In the present investigation, 41 soil samples were subjected to single step chemical partitioning to assess the lithogenic and non-lithogenic portions of metals in Tehran's soils. The share of various studied metals in the anthropogenic portion ranges from as low as 0.2% to as high as 85% of bulk concentration. Geo-accumulation index (Igeo) showed that Cd falls within "heavily contaminated" soils. It might be inferred that Ni, Cu, Cr, Zn, Co and Ca fall within "Deficient to minimal" class in accordance with enrichment factor (EF) classification.. Enrichment factor values (to some extents) match with the chemical partition studies results (except for Ni and Cr). The very low Ca content of soil samples could be indicative of low biological productivity in the Tehran's soil. Also the very low concentrations of Mn could be indicative of reducing environment in soils of Tehran.

Solid-solution partitioning of Rare Earth Elements in mine-tailings and soils in China: experimental results and multi-surface modelling. Interfaces Against Pollution

Permeable reactive barriers (PRBs) remove nitrogen from groundwater by enhancing microbial denitrification. The PRBs consist of woodchips that provide carbon for denitrifiers, but these woodchips also support other anaerobic microbes, including sulfate-reducing bacteria. Some of these anaerobes have the ability to methylate inorganic mercury present in groundwater. Methylmercury is hazardous to human health, so it is essential to understand whether PRBs promote mercury methylation. We examined microbial communities and geochemistry in fresh water and sulfate-enriched PRB flow-through columns by spiking replicates of both treatments with mercuric chloride. We hypothesized that mercury addition could alter bacterial community composition to favor higher abundances of genera containing known methylating taxa and that the sulfate-rich columns would produce more methylmercury after mercury addition, due mainly to an increase in abundance of sulfate reducing bacteria (SRB). However, methylmercury output at the end of the experiment was not different from output at the beginning, due in part to coupled Hg methylation and demethylation. There was a transient reduction in nitrate removal after mercury addition in the sulfate enriched columns, but nitrate removal returned to initial rates after two weeks, demonstrating resilience of the denitrifying community. Since methylmercury output did not increase and nitrate removal was not permanently affected, PRBs could be a low cost approach to combat eutrophication.

Thallium (Tl) and its compounds are non-essential and highly toxic for living organisms, even at low concentrations. In this paper, we analyzed the presence and geochemical distribution of Tl in different mining-metallurgical and sediment samples collected from several mining zones of Mexico. A modified BCR sequential extraction procedure was also applied to the samples to investigate the geochemical behavior and potential environmental risk of Tl according to types of ore deposit and mineral processing method applied. Results revealed the presence of Tl in the majority of the mining-metallurgical samples, with labile concentrations reaching up to values of 184.4 mg kg⁻¹, well above the environmental standards. A comparison of Tl partitioning in different samples showed that Tl was usually found associated with labile fractions instead of entrapped in the environmentally-passive residual fraction. Specifically, high levels of Tl were extracted from the exchangeable/acid-extractable and poorly-crystalline reducible fractions, suggesting its association with both soluble and amorphous Fe-Mn oxyhydroxides, respectively. Besides, Tl was also frequently found associated with the crystalline reducible fraction, presumably bonded to manganese oxides and jarosite-like minerals. Lastly, little amounts of Tl were extracted from the oxidizable fraction. Considering the fractionation of Tl in these mining-metallurgical samples, they may pose a significant environmental hazard. This study provides useful insights into the potential sources of Tl pollution in Mexico and emphasizes the need for further research to determine the extent of its impact and to develop effective remediation protocols to protect the environment from Tl toxicity.

Investigating the nature of PM₁₀ is crucial to differentiate sources and their relative contributions. In this study we compared the levels, and the chemical and mineralogical properties of PM₁₀ particles sampled in different seasons at monitoring stations representative of urban background, urban traffic and suburban traffic areas of Naples city. The aims were to relate the PM₁₀ load and characteristics to the location of the monitoring stations, to investigate the different sources contributing to PM₁₀ and to highlight PM₁₀ seasonal variability. Bulk analyses of chemical species in the PM₁₀ fraction included total carbon and nitrogen, δ¹³C and other 20 elements. Both natural and anthropogenic sources were found to contribute to the exceedances of the EU PM₁₀ limit values. The natural contribution was mainly related to marine aerosols and soil dust, as highlighted by X-ray diffractometry and SEM-EDS microscopy. The percentage of total carbon suggested a higher contribution of biogenic components to PM₁₀ in spring. However, this result was not supported by the δ¹³C values which were seasonally homogeneous and not sufficient to extract single emission sources. No significant differences, in terms of PM₁₀ load and chemistry, were observed between monitoring stations with different locations, suggesting a homogeneous distribution of PM₁₀ on the studied area in all seasons. The anthropogenic contribution to PM₁₀ seemed to dominate in all sites and seasons with vehicular traffic acting as a main source mostly by generation of non-exhaust emissions Our findings reinforce the need to focus more on the analysis of PM₁₀ in terms of quality than of load, to reconsider the criteria for the classification and the spatial distribution of the monitoring stations within urban and suburban areas, with a special attention to the background location, and to emphasize all the policies promoting sustainable mobility and reduction of both exhaust and not-exhaust traffic-related emissions.

The Cananéia-Iguape system is located in a coastal region of southeastern Brazil, recognized by UNESCO as an Atlantic Forest Biosphere Reserve. This system has suffered substantial environmental impacts due to the opening of an artificial channel and by past intensive mining activities. In this paper was performed the sequential chemical extraction of Cu, Pb, and Zn, on previously described sediment cores, and the statistical treatment of the data, allowing to estimate the remobilization geochemical behavior, the available content and the trend of accumulation between 1926 and 2008. The maximum available level (sum of all mobile fraction) were, in mgkg⁻¹, 18.74 for Cu, 177.55 for Pb and 123.03 for Zn. Considering its environmental availability, Pb remains a concern in the system. It was possible to recognize the anthropic contribution of Pb, being the mining activities considered the only potential source of this metal in the region.

The purpose of this article is to study, result of metal concentration in two-sediment cores from Persian Gulf. Age of sediment is determined by C14 isotope method and bulk concentration is determined by ICP. This research output shows that, age of BandareAbbas core back to 9660 and Bushehr core to 15,600 years ago. Also,concentration in BandareAbbas and Bushehr cores respectively change as, As (1.08–11.76 Vs 5.2–13.09), Ba (15.03–129.5 Vs 73.9–120.4), Cd (0.09–0.46 Vs 0.09–0.18), Li (5.66–58.5 Vs 15.3–33.4), Mo (0.3–0.75 Vs 0.3–0.8), Mg (7928.4–15,503.9 Vs 13,102.8–17,227.8), Mn (110.6–566.4 Vs 279.3–429.1), Na (8905.47–27,993.3 Vs 9357.7–27,541.4), Ni (13.3–110.3 Vs 37.1–88.4), Pb (0.5–42.5 Vs 2.5–13.6), Sr (407.5–1773.2 Vs 440.3–1596.9), Zn (13.05–71.2Vs22.4–50.5), Fe (0.46–4.07 Vs 1.7–3.18), Ca (9.25–23.3 Vs 13.8–19.2) and Al (0.62–8.15 Vs 2.48–4.65). Moreover different pollution index investigation represent that except Ca, the rest of the metal elements do not show pollution.

Lagoon Burullus is located in the North West quadrant of the Nile Delta. It receives drainage water through several drains around the lagoon. Understanding the mobility and bioavailability of zinc metal in bottom sediments of Lagoon Burullus is essential for the design of remediation processes and the institution of environmental recommendation for zinc pollution.Single extractions used to fractionate zinc into five fractions. The chemical analyses preceded using atomic absorption spectrometry after using the digestion technique. Zinc concentrates in the residual fraction (167.5μg/g) followed by the organic (14.6μg/g), exchangeable (3.2μg/g), carbonate (2.4μg/g) and then the Fe-Mn hydroxides (1μg/g) fractions. The average content of zinc (189μg/g) is about three fold the average earth's crust.Ecological pollution index show that the metal has a low-risk assessment to surrounding ecosystem. The anthropogenic activities considered as the main source of pollution.

Gold mining operations in the northern Black Hills of South Dakota resulted in the discharge of arsenopyrite-bearing mine tailings into Whitewood Creek from 1876 to 1977. Those tailings were transported further downstream along the Belle Fourche River, the Cheyenne River, and the Missouri River. An estimated 110 million metric tons of tailings remain stored in alluvial deposits of the Belle Fourche and Cheyenne Rivers. Pore-water dialysis samplers were deployed in the channel and backwaters of the Belle Fourche and Cheyenne Rivers to determine temporal and seasonal changes in the geochemistry of groundwater in alluvial sediments. Alluvial sediment adjacent to the dialysis samplers were cored for geochemical analysis. In comparison to US Environmental Protection Agency drinking water standards and reference concentrations of alluvial sediment not containing mine tailings, the Belle Fourche River sites had elevated concentrations of arsenic in pore water (2570 μg/L compared to 10 μg/L) and sediment (1010 ppm compared to < 34 ppm), respectively. Pore water arsenic concentration was affected by dissolution of iron oxyhydroxides under reducing conditions. Sequential extraction of iron and arsenic from sediment cores indicates that substantial quantities of soluble metals were present. Dissolution of arsenic sorbed to alluvial sediment particles appears to be affected by changing groundwater levels that cause shifts in redox conditions. Bioreductive processes did not appear to be a substantial transport pathway but could affect speciation of arsenic, especially at the Cheyenne River sampling sites where microbial activity was determined to be greater than at Belle Fourche sampling sites.

Century old mine tailings in the Cobalt and Silver Center areas are widely dispersed throughout the terrestrial and aquatic environments and contain high concentrations of arsenic. Arsenic concentrations were found to be as high as 972 μg/L in surface waters and 10,800 mg/kg in lake sediment. The mean values for arsenic in surface waters and sediment from 9 lakes directly influenced by mining activity were 431 μg/L and 1704 mg/kg, respectively, whereas in the 12 control lakes with no mining activity in their catchment had mean values of 2.2 μg/L and 11 mg/kg in their water and sediment, respectively. Lakes impacted by downstream tailing migration (n = 4) were also assessed and had intermediate concentrations of arsenic. Principal component analysis identified contaminated lakes as having different geochemical signatures than control lakes but lake sediment that was sampled below tailings in contaminated lakes, deposited pre-mining, can resemble the geochemistry of those found in control lakes. Arsenic concentrations in these samples ranged from 4.4 to 185 mg/kg, which can be considered reasonable background as these areas contained abundant mineral deposits that could naturally elevate background concentrations. Even though background concentrations are naturally elevated, the presence of arsenic-rich tailings in these lakes has prevented any natural recovery from occurring. Fe-Mn oxides at the water-sediment interface perpetually scavenge arsenic from buried tailings below and from contaminated surface waters that cause arsenic concentrations to remain enriched in the upper sediments even after tailings have been buried by lake sediment. This process has prevented recovery of the lake ecosystems even after nearly a century without mining.