Increasing the pollution rate of water sources is one of the most severe issues that the world faces. This issue has stimulated researchers to investigate different treatment methods such as adsorption, chemical precipitation, membrane filtration, flocculation, ion exchange, flotation, and electrochemical methods. Among them, adsorption has gained broad interest due to its ease of operation, low cost, and high efficiency. The critical factor of the successful adsorption treatment process is finding attractive adsorbents with attractive criteria such as low cost and high adsorption capacity. In the last few decades, nanotechnology has attracted much attention, and numerous nanomaterials have been synthesized for water and wastewater treatment. This work provides a quick overview of nanomaterials, which have been investigated for water remediation as adsorbent and photocatalyst. This work reviewed more than 100 articles to provide a critical review that would determine the limitation of using nanomaterials in water treatment at the commercial scale.

Incessant release of a large spectrum of agro-industrial pollutants into environmental matrices remains a serious concern due to their potential health risks to humans and aquatic animals. Existing remediation techniques are unable to remove these pollutants, necessitating the development of novel treatment approaches. Due to its unique structure, physicochemical properties, and broad application potential, graphene has attracted a lot of attention as a new type of two-dimensional nanostructure. Given its chemical stability, large surface area, electron mobility, superior thermal conductivity, and two-dimensional structure, tremendous research has been conducted on graphene and its derived composites for environmental remediation and pollution mitigation. Various methods for graphene functionalization have facilitated the development of different graphene derivatives such as graphene oxide (GO), functional reduced graphene oxide (frGO), and reduced graphene oxide (rGO) with novel attributes for multiple applications. This review provides a comprehensive read on the recent progress of multifunctional graphene-based nanocomposites and nanohybrids as a promising way of removing emerging contaminants from aqueous environments. First, a succinct overview of the fundamental structure, fabrication techniques, and features of graphene-based composites is presented. Following that, graphene and GO functionalization, i.e., covalent bonding, non-covalent, and elemental doping, are discussed. Finally, the environmental potentials of a plethora of graphene-based hybrid nanocomposites for the abatement of organic and inorganic contaminants are thoroughly covered.

Numerous applications exist for graphene-based materials, such as graphene oxide (GO) nanosheets. Increased concentrations of GO nanosheets in the environment have the potential to have a large negative effect on the aquatic environment, with consequences for benthic organisms, such as polychaetes. The polychaete Hediste diversicolor mobilises the sediments, hence altering the availability of contaminants and the nutrients biogeochemical cycle. As such, this study proposes to assess the effects of different GO nanosheet concentrations on the behaviour, feeding activity, mucus production, regenerative capacity, antioxidant status, biochemical damage and metabolism of H. diversicolor. This study evidenced that H. diversicolor exposed to GO nanosheets had a significantly lower ability to regenerate their bodies, took longer to feed and burrow into the sediment and produced more mucus. Membrane oxidative damage (lipid peroxidation) increased in exposed specimens. The increased metabolic rate (ETS) evidenced a higher energy expenditure in exposed organisms (high use of ready energy sources – soluble sugars) to fight the toxicity induced by GO nanosheets, such as SOD activity. The increase in SOD activity was enough to reduce reactive oxygen species (ROS) induced by GO on cytosol at the lowest concentrations, avoiding the damage on proteins (lower PC levels), but not on membranes (LPO increase). This study revealed that the presence of GO nanosheets, even at the lower levels tested, impaired behavioural, physiological, and biochemical traits in polychaetes, suggesting that the increase of this engineered nanomaterial in the environment can disturb these benthic organisms, affecting the H. diversicolor population. Moreover, given the important role of this group of organisms in coastal and estuarine food webs, the biogeochemical cycle of nutrients, and sediment oxygenation, there is a real possibility for repercussions into the estuarine community.

Volatile organic compounds (VOCs) represent a considerable threat to humans and ecosystems. Strategic remediation techniques for the abatement of VOCs are immensely important and immediately needed. Given a unique set of optical, mechanical, electrical, and thermal characteristics, inimitable surface functionalities, porous structure, and substantial specific surface area, graphene and derived nanohybrid composites have emerged as exciting candidates for abating environmental pollutants through photocatalytic degradation and adsorptive removal. Graphene oxide (GO) and reduced graphene oxide (rGO) containing oxygenated function entities, i.e., carbonyl, hydroxyl, and carboxylic groups, provide anchor and dispersibility of their surface photocatalytic nanoscale particles and adsorptive sites for VOCs. Therefore, it is meaningful to recapitulate current state-of-the-art research advancements in graphene-derived nanostructures as prospective platforms for VOCs degradation. Considering this necessity, this work provides a comprehensive and valuable insight into research progress on applying graphene-based nanohybrid composites for adsorptive and photocatalytic abatement of VOCs in the aqueous media. First, we present a portrayal of graphene-based nanohybrid based on their structural attributes (i.e., pore size, specific surface area, and other surface features to adsorb VOCs) and structure-assisted performance for VOCs abatement by graphene-based nanocomposites. The adsorptive and photocatalytic potentialities of graphene-based nanohybrids for VOCs are discussed with suitable examples. In addition to regeneration, reusability, and environmental toxicity aspects, the challenges and possible future directions of graphene-based nanostructures are also outlined towards the end of the review to promote large-scale applications of this fascinating technology.

In agricultural fields, pesticides are widely used, but their residual presence in the environment poses a threat to humans, animals, insects, and ecosystems. The overuse of pesticides for pest control, enhancement of crop yield, etc. leaves behind a significant residual amount in the environment. Various robust, reliable, and reusable methods using a wide class of composites have been developed for the monitoring and controlling of pesticides. Researchers have discovered that carbon nanomaterials have a wide range of characteristics such as high porosity, conductivity and easy electron transfer that can be successfully used to detect pesticide residues from food. This review emphasizes the role of carbon nanomaterials in the field of pesticide residue analysis in different food matrices. The carbon nanomaterials including carbon nanotubes, carbon dots, carbon nanofibers, graphene/graphene oxides, and activated carbon fibres are discussed in the review. In addition, the review examines future prospects in this research area to help improve detection techniques for pesticides analysis.

Graphene oxide can be used to store energy, as electrodes and purify industrial and domestic wastewater as photocatalysts and adsorbents because of its remarkable thermal, electrical, and chemical capabilities. Toward understanding graphene oxide (GO) based nanomaterials considering the background factors, the present review study investigated their characteristics, preparation methods, and characterization processes. The removal of contaminants from wastewater has recently been a focus of attention for materials based on GO. Progress in GO synthesis and surface modification has shown that they can be used to immobilize enzymes. It is possible to immobilize enzymes with varying characteristics on graphene-oxide-based substrates without sacrificing their functioning, thus developing a new environmental remediation platform utilizing nano biocatalysts. GO doping and co-doping with a variety of heterogeneous semiconductor-based metal oxides were included in a brief strategy for boosting GO efficiency. A high band-gap material was also explored as a possibility for immobilization, which shifts the absorption threshold to the visible range and increases photoactivity. For water treatment applications, graphene-based nanomaterials were used in Fenton reactions, photocatalysis, ozonation, photo electrocatalysis, photo-Fenton, and a combination of photon-Fenton and photocatalysis. Nanoparticles made from GO improved the efficiency of composite materials when used for their intended applications. As a result of the analysis, prospects and improvements are clear, especially when it comes to scaling up GO-based wastewater treatment technologies.

Antimicrobial nanomaterials provide numerous opportunities for the synthesis of next-generation sustainable water disinfectants. Using the keywords graphene and water disinfection and graphene antibacterial activity, a detailed search of the Scopus database yielded 198 and 1433 studies on using graphene for water disinfection applications and graphene antibacterial activity in the last ten years, respectively. Graphene family nanomaterials (GFNs) have emerged as effective antibacterial agents. The current innovations in graphene-, graphene oxide (GO)-, reduced graphene oxide (rGO)-, and graphene quantum dot (GQD)-based nanocomposites for water disinfection, including their functionalization with semiconductor photocatalysts and metal and metal oxide nanoparticles, have been thoroughly discussed in this review. Furthermore, their novel application in the fabrication of 3D porous hydrogels, thin films, and membranes has been emphasized. The physicochemical and structural properties affecting their antibacterial efficiency, such as sheet size, layer number, shape, edges, smoothness/roughness, arrangement mode, aggregation, dispersibility, and surface functionalization have been highlighted. The various mechanisms involved in GFN antibacterial action have been reviewed, including the mechanisms of membrane stress, ROS-dependent and -independent oxidative stress, cell wrapping/trapping, charge transfer, and interaction with cellular components. For safe applications, the potential biosafety and biocompatibility of GFNs in aquatic environments are emphasized. Finally, the current limitations and future perspectives are discussed. This review may provide ideas for developing efficient and practical solutions using graphene-, GO-, rGO-, and GQD-based nanocomposites in water disinfection by rationally employing their unique properties.

Photocatalytic technology has been widely studied by researchers in the field of environmental purification. This technology can not only completely convert organic pollutants into small molecules of CO₂ and H₂O through redox reactions but also remove metal ions and other inorganic substances from water. This article reviews the research progress of graphene-based photocatalytic nanocomposites in the treatment of wastewater. First, we elucidate the basic principles of photocatalysis, the types of graphene-based nanocomposites, and the role of graphene in photocatalysis (e.g., graphene can accelerate the separation of photon-hole pairs and increase the intensity and range of light absorption). Second, the preparation, characterization, and application of composites in wastewater are introduced. We also discuss the kinetic model of the photocatalytic degradation of pollutants. Finally, the enhancement mechanism of graphene in terms of photocatalysis is not completely clear, and graphene-based photocatalysts with high catalytic efficiency, low cost, and large-scale production have not yet appeared, so there is an urgent need for more extensive and in-depth research.

Graphene photocatalysis is a new method for harmful algae and water pollution control. However, microbial communities undergoing graphene photocatalysis treatment in freshwater lakes have been poorly studied. Here, using 16S rRNA and 18S rRNA gene high-throughput sequencing, the responses of microbial communities to graphene photocatalysis were analyzed in the eutrophic lake, Lake Xinyun, southwestern China. For microeukaryotes, we found that Arthropoda was dominant in summer, while its abundant level declined in spring under natural conditions. The evident reduction of Arthropods was observed after graphene photocatalysis treatment in summer and then reached a relatively stable level. For bacteria, Cyanobacteria decreased in summer due to the graphene photocatalysis-mediated inactivation. However, Cyanobacteria was higher in the treated group in spring with a genera group-shift. Functional analysis revealed that microeukaryotes showed higher potential for fatty acid oxidation and TCA cycle in the treated group in summer, but they were more abundant in control in spring. Pathways of starch and sucrose metabolism and galactose metabolism were more abundant in control in summer, while they were enriched in the treated group in spring for bacteria. This study offers insights into the effects of graphene photocatalysis on microbial communities and their functional potential in eutrophic lake.

A simple electrochemical method is proposed for recovering iron from steel pickling waste liquor with graphite plates as electrodes. In this study, response surface methodology (RSM) was used to optimize the experimental conditions and assess the effect of the process variables, including initial pH, reaction temperature (T), current density (J), and reaction time (t), on total iron (TFe) removal. The model obtained by analyzing data with Design Expert 8.0.6 was very significant, and pH had the most significant effect on TFe removal. The optimum reaction conditions were pH = 9, T = 35 °C, J = 20.07 mA/cm², and t = 30 min, under which conditions the removal rate was more than 99.99%, the residual TFe = 0.28 mg/L at the initial TFe of 10 g/L, and the obtained product had strong magnetism. Therefore, the method of electrochemical synthesis of Fe₃O₄ is promising in the treatment and recycling of steel pickling waste liquor.