Biomagnification of persistent toxic substances (PTSs) in food chains is of environmental concern, but studies on biotransport of PTSs across aquatic and riparian food chains are still incomplete. In this study, biomagnification of several PTSs including methylmercury (MeHg), polybrominated diphenyl ethers (PBDEs), and 1,2-bis (2,4,6-tribromophenoxy) ethane (BTBPE) was investigated in adjacent aquatic and riparian food webs. Concentrations of MeHg and PBDEs ranged from 2.37 to 353 ng/g dry weight (dw) and not detected (Nd) to 65.1 ng/g lipid weight (lw) in riparian samples, respectively, and ranged from Nd to 705 ng/g dw and Nd to 187 ng/g lw in aquatic samples, respectively. Concentrations of MeHg were significantly correlated with δ¹³C (p < 0.01) rather than δ¹⁵N (p > 0.05) values in riparian organisms, while a significant correlation was observed between concentrations of MeHg and δ¹⁵N (p < 0.01) in aquatic organisms. Biomagnification factors (BMFs) and trophic magnification factors (TMFs) of PBDE congeners were similar in riparian and aquatic food webs, while BMFs and TMFs of MeHg were much higher in aquatic food web than those in riparian food web. The results indicate the biotransport of MeHg from aquatic insects to terrestrial birds, and δ¹³C can be a promising ecological indicator for biotransport of pollutants across ecosystems.

Inorganic particulate nitrate (p-NO3−), gaseous nitric acid (HNO₃₍g₎) and nitrogen oxides (NOₓ = NO + NO₂), as main atmospheric pollutants, have detrimental effects on human health and aquatic/terrestrial ecosystems. Referred to as the ‘Third Pole’ and the ‘Water Tower of Asia’, the Tibetan Plateau (TP) has attracted wide attention on its environmental changes. Here, we evaluated the oxidation processes of atmospheric nitrate as well as traced its potential sources by analyzing the isotopic compositions of nitrate (δ¹⁵N, δ¹⁸O, and Δ¹⁷O) in the aerosols collected from the Mt. Everest region during April to September 2018. Over the entire sampling campaigns, the average of δ¹⁵N(NO3−), δ¹⁸O(NO3−), and Δ¹⁷O(NO3−) was −5.1 ± 2.3‰, 66.7 ± 10.2‰, and 24.1 ± 3.9‰, respectively. The seasonal variation in Δ¹⁷O(NO3−) indicates the relative importance of O₃ and HO₂/RO₂/OH in NOₓ oxidation processes among different seasons. A significant correlation between NO3− and Ca²⁺ and frequent dust storms in the Mt. Everest region indicate that initially, the atmospheric nitrate in this region might have undergone a process of settling; subsequently, it got re-suspended in the dust. Compared with the Δ¹⁷O(NO3−) values in the northern TP, our observed significantly higher values suggest that spatial variations in atmospheric Δ¹⁷O(NO3−) exist within the TP, and this might result from the spatial variations of the atmospheric O₃ levels, especially the stratospheric O₃, over the TP. The observed δ¹⁵N(NO3−) values predicted remarkably low δ¹⁵N values in the NOₓ of the sources and the N isotopic fractionation plays a crucial role in the seasonal changes of δ¹⁵N(NO3−). Combined with the results from the backward trajectory analysis of air mass, we suggest that the vehicle exhausts and agricultural activities in South Asia play a dominant role in determining the nitrate levels in the Mt. Everest region.

There is less research on the hydrological system and its destruction processes mechanism in the mining areas, especially combined application of isotope technology and chemical signals, which is a key scientific problem that need to be solved. This study takes Jinci spring area in Shanxi as a case study. It is based on the data of hydrology and mining condition from 1954 to 2015, combining monitoring experiments, O18, D, S34 and N15 tracing, chemical and model simulation. This study investigates the hydrological regularity and impacts of mining activities on water quantity and quality, and reveals the destruction process of hydrological system. The results show that: (1) Water chemical type shows an evolutionary trend of HCO3−-Ca2+-Mg2+→SO42--HCO3--Ca2+-Mg2+→SO42--Ca2+-Mg2+, due to the influence of exploitation and fault zones. Isotope tracer shows that mine pit water is formed by a mixture of pore water, karst water and surface water. (2) Although precipitation and seepage have a certain impact on the reducing of groundwater quantity, over-exploitation of water resource is still the main reason for reducing of groundwater quantity. Under the conditions of keeping the exploitation intensity at the current level or reducing it by 10%, groundwater level shows a declining trend. Under the condition of reducing it by 30%, groundwater level starts to rise up. When reducing by 50%, groundwater level reaches its highest point. Coalmining changes the runoff, recharge and discharge paths. (3) From 1985 to 2015, Water quality in the mining area is worsening. Ca2+ increases by 35.30%, SO42− increases by 52.80%, and TDS (Total Dissolved Solid) increases by 67.50%. Nitrates come from the industrial and domestic wastewater, which is generated by mining. The percentage of groundwater coming from gypsum dissolusion is 67.51%, and the percentage from coal measure strata water is 34.49%. The water qualities of river branches are generally deteriorated.

The use of zero-valent iron nanoparticles (nZVI) has been advocated for the remediation of both soils and groundwater. A key parameter affecting nZVI remediation efficacy is the mobility of the particles as this influences the reaction zone where remediation can occur. However, by engineering nZVI particles with increased stability and mobility we may also inadvertently facilitate nZVI-mediated contaminant transport away from the zone of treatment. Previous nZVI mobility studies have often been limited to model systems as the presence of background Fe makes detection and tracking of nZVI in real systems difficult. We overcame this problem by synthesising Fe-59 radiolabelled nZVI. This enabled us to detect and quantify the leaching of nZVI-derived Fe-59 in intact soil cores, including a soil contaminated by Chromated-Copper-Arsenate. Mobility of a commercially available nZVI was also tested. The results showed limited mobility of both nanomaterials; <1% of the injected mass was eluted from the columns and most of the radiolabelled nZVI remained in the surface soil layers (the primary treatment zone in this contaminated soil). Nevertheless, the observed breakthrough of contaminants and nZVI occurred simultaneously, indicating that although the quantity transported was low in this case, nZVI does have the potential to co-transport contaminants. These results show that direct injection of nZVI into the surface layers of contaminated soils may be a viable remediation option for soils such as this one, in which the mobility of nZVI below the injection/remediation zone was very limited. This Fe-59 experimental approach can be further extended to test nZVI transport in a wider range of contaminated soil types and textures and using different application methods and rates. The resulting database could then be used to develop and validate modelling of nZVI-facilitated contaminant transport on an individual soil basis suitable for site specific risk assessment prior to nZVI remediation.

The increasing salinization of groundwater renders it challenging to maintain the water quality. Moreover, knowledge regarding the characteristics and mechanism of groundwater salinization in mining areas remains limited. This study represents the first attempt of combining the hydrochemical, isotope (δD, δ¹⁸O, δ³⁷Cl, and ⁸⁷Sr/⁸⁶Sr) and multivariate statistical analysis methods to explore the origin, control, and influence of fluoride enrichment in mining cities. The TDS content of groundwater ranged from 275.9 mg/L to 2452.0 mg/L, and 54% of the groundwater samples were classified as class IV water according to China's groundwater quality standards (GB/T 14848–2017), indicating a decline in the water quality of the study area. The results of the groundwater ion ratio and isotope discrimination analysis showed that dissolution and evaporation involving water-rock interactions and halite were the main driving processes for groundwater salinization in the study area. In addition to the hydrogeological and climatic conditions, mine drainage inputs exacerbated the increasing salinity of the groundwater in local areas. The mineral dissolution, cation exchange, and evaporation promoted the F⁻ enrichment, while excessive evaporation and salinity inhibited the F⁻ enrichment. Gangue accumulation and infiltration likely led to considerable F⁻ enrichment in individual groundwater regions. Extensive changes in the groundwater salinity indicated differences in the geochemical processes that controlled the groundwater salinization. Given the particularity of the study area, the enrichment of salinization and fluoride triggered by mining activities cannot be ignored.

The sources of aerosol ammonium (NH4+) are of interest because of the potential of NH4+ to impact the Earth's radiative balance, as well as human health and biological diversity. Isotopic source apportionment of aerosol NH4+ is challenging in the urban atmosphere, which has excess ammonia (NH3) and where nitrogen isotopic fractionation commonly occurs. Based on year-round isotopic measurements in urban Beijing, we show the source dependence of the isotopic abundance of aerosol NH4+, with isotopically light (−33.8‰) and heavy (0 to +12.0‰) NH4+ associated with strong northerly winds and sustained southerly winds, respectively. On an annual basis, 37–52% of the initial NH3 concentrations in urban Beijing arises from fossil fuel emissions, which are episodically enhanced by air mass stagnation preceding the passage of cold fronts. These results provide strong evidence for the contribution of non-agricultural sources to NH3 in urban regions and suggest that priority should be given to controlling these emissions for haze regulation. This study presents a carefully executed application of existing stable nitrogen isotope measurement and mass-balance techniques to a very important problem: understanding source contributions to atmospheric NH3 in Beijing. This question is crucial to informing environmental policy on reducing particulate matter concentrations, which are some of the highest in the world. However, the isotopic source attribution results presented here still involve a number of uncertain assumptions and they are limited by the incomplete set of chemical and isotopic measurements of gas NH3 and aerosol NH4+. Further field work and lab experiments are required to adequately characterize endmember isotopic signatures and the subsequent isotopic fractionation process under different air pollution and meteorological conditions.

The hydrological and pollution processes are an important science problem for aquatic ecosystem. In this study, the samples of river water, reservoir water, shallow groundwater, deep groundwater, and precipitation in mining area are collected and analyzed. δD and δ¹⁸O are used to identify hydrological process. δ¹⁵N-NO₃⁻ and δ¹⁸O-NO₃⁻ are used to identify the sources and pollution process of NO₃⁻. The results show that the various water bodies in Fenhe River Basin are slightly alkaline water. The ions in the water mainly come from rock weathering. The concentration of SO₄²⁻ is high due to the impact of coal mining activity. Deep groundwater is significantly less affected by evaporation and human activity, which is recharged by archaic groundwater. There are recharge and discharge between reservoir water, river water, soil water, and shallow groundwater. NO₃⁻ is the main N species in the study area, and forty-six percent of NO₃⁻-N concentrations exceed the drinking water standard of China (NO₃⁻-N ≤ 10 mg/L content). Nitrification is the main forming process of NO₃⁻. Denitrification is also found in river water of some river branches. The sources of NO₃⁻ are mainly controlled by land use type along the riverbank. NO₃⁻ of river water in the upper reaches are come from nitrogen in precipitation and soil organic N. River water in the lower reaches is polluted by a mixture of soil organic N and fertilizers.

The dynamics of the coastal aquifers are well-expressed by geochemical and isotopic signatures. Coastal regions often exhibit complex groundwater recharge pattern due to the influence of depression in the Bay of Bengal, tidal variations on surface waters, saline water intrusion and agricultural return flows. In this research, groundwater recharge processes occurring in coastal Tamil Nadu, South India were evaluated using major ion chemistry and environmental isotopes. A total of 170 groundwater samples were collected from shallow and deep aquifers during both post-monsoon (POM) and pre-monsoon (PRM) seasons. The isotopic results showed a wide variation in the shallow groundwater, suggesting contribution from multiple recharge sources. But, the deeper groundwater recharge is mainly from precipitation. The northern part of the study area showed more depleted isotopic values, which rapidly changed towards south from −6.8 to −4.4‰. Alternatively, central and southern parts exhibited relatively enriched isotopic content with variation from −0.58 to −2.7‰. Groundwater was discerned to be brackish to saline with chloride content, 600–2060 mgL⁻¹ and δ¹⁸O ranging from −5.8 to −4.5‰, suggesting influence of the saline water sources. A minor influence of anthropogenic activities was also observed in the deeper groundwater during PRM, which was confirmed by tritium and Cl⁻ trends. The old groundwater with depleted isotopic content infer recharged by distant sources while modern groundwater with enriched isotopes points to the influence of evaporated recharge.