Biochar amendments could enhance retention of nutrients such as ammonium (NH4+), nitrate (NO3-), and phosphate (PO43-) in soils. However, the situation for sulphate (SO42-), which is an indispensable nutrient element for crop growth, is unclear. In this paper, the effects of biochar derived from rape (Brassica campesstris L.) straw at 600°C on the sorption and leaching of SO42- in light sierozem (Calcids) was studied in columns, where biochar amendment rate, column soil height, solution pH value and initial sulphate concentration were selected as factors. It is shown that the transport of sulphate was a significant non-equilibrium process and the sorption and leaching curves (SLCs) of sulphate were asymmetrical. The breakthrough time would be increased by increasing biochar amendment and soil column height, and by decreasing solution pH value and initial sulphate concentration. The SLCs of bromide trace were fitted to determine dispersion coefficient (D) using equilibrium convection dispersion equation (CDEeq). The non-equilibrium (two-site) model (CDEnon-eq) with the results from CDEeq was used to simulate the transport processes of sulphate in the soil column, with good fitness, using software CXTFIT 2.1 fitting. The results could supply an implication for biochar application in loess areas.

The essential issues solved by geoenvironmental engineers relate to the assurance of uncontaminated regions of the subsurface just as the remediation of locales of the subsurface that have been sullied by releasing waste materials, spilling over the ground and underground stockpiling tanks and penetration of pesticides. In city areas, garbage and waste materials are generally dumped into landfills. A landfill site, which is otherwise called a trash dump, is used for the disposal of waste materials by burial. A safe landfill is a deliberately built sorrow in the ground into which wastes are put. The principal objective is to stay away from any water driven association between the wastes and the surrounding environment especially groundwater. This paper discusses landfill, in terms of its construction, stability and failure. The analysis and modelling of the landfill failure occurred in different countries like Poland, Turkey, Israel, the Philippines, China and Sri Lanka which are discussed.