We estimated the total inorganic fluxes of nitrogen (N), sulfur (S), chloride (Cl-, sodium (Na⁺, calcium (Ca²⁺, magnesium (Mg²⁺, potassium (K⁺ and hydronium (H⁺. The resistance deposition algorithm that is programmed as part of the CALMET/CALPUFF modeling system was used to generate spatially-distributed deposition velocities, which were then combined with measurements of urban and rural concentrations of gas and particle species to obtain dry deposition rates. Wet deposition rates for each species were determined from rainfall concentrations and amounts available from the National Acid Deposition Program (NADP) monitoring network databases. The estimated total inorganic nitrogen deposition to the Tampa Bay watershed (excluding Tampa Bay) was 17 kg-N ha-¹ yr-¹ or 9,700 metric tons yr-¹, and the ratio of dry to wet deposition rates was ~2.3 for inorganic nitrogen. The largest contributors to the total N flux were ammonia (NH₃ and nitrogen oxides (NO x at 4.6 kg-N ha-¹ yr-¹ and 5.1 kg-N ha-¹ yr-¹, respectively. Averaged wet deposition rates were 2.3 and 2.7 kg-N ha-¹ yr-¹ for NH₄ ⁺ and NO₃ -, respectively.

One of the methods to diminish the internal phosphorus (P) loading is inactivation of P by aluminum (Al). After addition of Al to lake water an Al(OH)₃ floc is formed, which settles to the bottom and initially form a lid on the sediment surface. The effects of Chironomus plumosus larvae on sediment nutrient fluxes and P binding-sites in the sediment after addition of Al were tested. C. plumosus larvae were added to sediment cores in which sediment-water fluxes of nutrients were measured four times. After one month, the sediment was sectioned with depth and P fractions were measured by sequential chemical extraction. The chironomids created burrows through the Al layer which caused a significantly increased efflux of P from the Al treated sediment, because the P had only limited contact to the added Al. The chironomids also affected the P fractions in the sediment by their bioturbating activity. Thus, they caused increased Al concentrations in the upper part of the Al treated sediment. This created an enhanced contact between Al and P in the upper 7 cm of the sediment and, as a result, an increased binding of P to Al and a lowered porewater P. The DIP efflux is therefore expected to be lowered after the initial phase. Al had no effects on the nitrogen fluxes, but the chironomids enhanced the [graphic removed] release, and decreased the [graphic removed] release or increased the [graphic removed] uptake by the sediments.