A study was carried out recently to determine the pollution level of waters in the Karachi harbour and adjoining backwaters. Nine locations were selected, four in the backwaters, two on the seaside, and three in the main navigable channel. Four of these locations were deliberately selected to coincide with those of a previous study conducted in 1982 by Pakistan Council of Scientific and Industrial Research (PCSIR) so that the values for the concentration of different pollutants could be compared. Analysis was conducted for pH, bicarbonates, Total Solids, Volatile matter in Total Solids, Chlorides, Sulphates, Calcium, Magnesium, Sodium and Potassium.The results indicate that the composition of sea water as far as the concentration of above constituents is concerned has not changed much since the time of the PCSIR study, viz 1982, except that the organic matter concentration has increased. The reasons for this increase in organic loading and its possible impact are discussed in this paper.

The arboreal mites and epiphytes in young Scots pine forests (plant association Leucobryo-Pinetum) polluted by a copper smelting works at Głogów, were investigated. The concentration of heavy metals in Scots pine bark and epiphytes increased towards the pollution source. Copper was accumulated mainly by algae, but lead was accumulated mainly by lichens; these epiphytes accumulated more heavy metals than tree bark. A high concentration of heavy metals was harmful to mites, especially to Oribatida, and to lichens, but algae tolerated these pollutants. The number of oribatid species decreased towards the pollution source, along with the increasing concentrations of heavy metals in tree bark and epiphytes. Among mites, the following categories were distinguished: a) sensitive to heavy metals, b) sensitive to a high concentration but tolerant of small concentrations and c) tolerant of these metals. The mites inhabited mainly the lower section of trees.

In the late 1980s, citrus plantations in the area of Villarreal (Spain) showed injuries similar to those previously reported for boron and fluorine toxicity. The area was affected by the disposal of industrial wastewater, mainly from ceramic industries. Conjunctive uses of surface water, groundwater and wastewater for irrigation had taken place. A survey was conducted at 25 orchards to assess leaves and soil for their boron, fluorine, lead, nickel and zinc contents. Wastewater and groundwater were also analyzed to corroborate the presence of these pollutants. The results showed that both boron and fluorine contents were greater than those reported as excess at the most part of the orchards included in the study. Heavy metals toxicity effects were not confirmed. Boron pollution was attributed to industrial wastewater spills and fluorine contamination from atmospheric pollution.

Combined effects of organic or inorganic pollutants on soil microbial activities were investigated in field plots grown with four types of covering plants. It was derived from this study that combined effects were dependent not only on the type and dose of pollutants, addition of soda lime, plant type and season variation, but also on test parameters. When jointly added, higher doses of Cd, Cu, Pb, Zn and As caused significant inhibition. Addition of soda lime could even enhance inhibition. Joint effects of phenanthrene, MET (active ingredient: paclobutrazol) and 1,2,4-trichlorobenzene were not significant, and may be covered by other biotic or abiotic factors. Compared with other two parameters (respiration and microbial biomass), dehydrogenase activity appeared to be more sensitive for evaluating the toxicity of anthropogenic pollutants in soil. Soil samples collected in summer often had higher microbial activities than those in fall. The microbial activity in soil decreased with covering vegetation in the order alfalfa > pine > poplar and maize, albeit some exceptions were observed.

A study was carried out recently to determine the pollution level of waters in the Karachi harbour and adjoining backwaters. Nine locations were selected, four in the backwaters, two on the seaside, and three in the main navigable channel. Four of these locations were deliberately selected to coincide with those of a previous study conducted in 1982 by Pakistan Council of Scientific and Industrial Research (PCSIR) so that the values for the concentration of different pollutants could be compared. Analysis was conducted for pH, bicarbonates, Total Solids, Volatile matter in Total Solids, Chlorides, Sulphates, Calcium, Magnesium, Sodium and Potassium.The results indicate that the composition of sea water as far as the concentration of above constituents is concerned has not changed much since the time of the PCSIR study, viz 1982, except that the organic matter concentration has increased. The reasons for this increase in organic loading and its possible impact are discussed in this paper.

The combined influence of high phenol concentrations and low temperatures on aerobic and anaerobic phenol degradation kinetics was investigated in microbial enrichment cultures to evaluate temperature-inhibition relationships with respect to the ambient conditions in polluted habitats. The inhibition of microbial phenol degradation by excess substrate was found to be temperature-dependent. Substrate inhibition was intensified when temperatures were lower. This results in an elevated temperature sensitivity of phenol degradation at inhibitory substrate concentrations.The synergistic amplification of substrate inhibition at low temperatures may help to explain the limited self-purification potential of contaminated habitats such as soils, sediments and groundwater aquifers where high pollutant concentrations and low temperatures prevail.

A few case studies will be presented involving both radioactive and chemical pollution at small, medium, and large space-time scales. Reported are recent advances in the field of environmental pollution involving the use of fractals and multifractals. The mathematical tools proposed here may offer new perspectives for investigating many of the problems of nonlinear variability which commonly arise when dealing with pollutants, such as the presence of outliers and the sparseness of the sampling networks. They may also lead to a simplification of the models adopted for studying natural phenomena, thanks to a scaling approach. Finally, they may provide parameters whose values are directly related to the nonlinear dynamics involved in the pollutant distribution in the environment which, in turn, may be relevant for computer simulation and epidemiological or risk assessment purposes.

A two-step analytical method is developed for the isolation and characterization of polycyclic aromatic hydrocarbons (PAHs) in crude oil contaminated soil. In the first step, those crude oil components were isolated which are easily mobilized with water from the contaminated soil (determination of groundwater pollution potential). In the second step, the fraction containing the remaining crude oil compounds was extracted using toluene. After the cleanup of the fractions, both fractions were analyzed using high-performance liquid chromatography (HPLC).The HPLC of the toluene extracted fraction shows that along with the sixteen priority pollutants from the US-EPA list, many other polycyclic aromatic hydrocarbons (PAHs) are present as well. It is evident from the chromatograms that a significant amount of PAHs are present as is also the case in the fractions eluted by water.The described method allows the determination of total organic pollutants from crude oil, some of them being potential groundwater contaminants. The major part of the total pollutants could not be mobilized by water and therefore remains in the soil, which was extracted in the second step.