The desorption rate is an important factor determining cadmium (Cd) ecotoxicity and pollution remediation in soils. The pedotransfer functions (PTFs) of desorption rate coefficients of fresh Cd in soils have been developed in literature. We hypothesized that the aging of Cd pollution would alter Cd desorption process. Taking historically polluted soils as the object, this study aimed at testing the hypothesis and developing new PTFs of desorption rate coefficients for historical Cd. 15 d batch extraction experiments and 13 kinetic models were employed to define Cd desorption rate coefficients in 27 historically polluted soil samples. Compared with fresh Cd, the desorption rate coefficients of historical Cd were lower, and the break time of biphasic desorption processes was retarded to 3 d (4320 min). Different with the usual models for fresh Cd desorption (e.g. parabolic diffusion and two constant rate models), the best models to mimic the historical Cd desorption processes were the pseudo first order, logarithmic, Elovich, and simple Elovich models. The rate-limiting step controlling Cd desorption was changed from the intraparticle diffusion to the interface reaction with aging of pollution. New PTFs of desorption rate coefficients of historical Cd were established (R² ≥ 0.71). Cd desorption rate coefficients increased with organic matter and clay contents, but decreased with oxalate extractable Fe content, solution pH, cation exchange capacity, and silt content. The key soil properties influencing desorption rate coefficients were not altered by the aging of pollution. The developed PTFs could guide us to adjusting the ecotoxicity and pollution remediation of Cd in historically polluted field soils.

Selenium (Se) is an essential micronutrient for animals with a narrow margin between essentiality and toxicity. Se toxicity is largely related to inorganic forms of Se in soil, i.e., selenite and selenate that enter food chains through plant uptake, threatening higher trophic level organisms. This experiment investigated effects of earthworm activity on Se bioavailability in soil and the subsequent plant uptake, using earthworm Eisenia fetida and bean plant Phaseolus vulgaris L, both exposed to either selenite or selenate at 1 or 4 mg Se kg⁻¹ for 16 weeks. Plants took up selenate (up to 221-fold) faster than selenite, with up to 84% of the Se rapidly transported to shoots. In the presence of earthworms, Se accumulation obviously increased for selenate-supplied plants, leading to an up to 4% increase in Se translocation factor for all treatments except for 1 mg kg⁻¹ selenite treatment. Earthworms also concentrated Se faster in tissues (up to 274 mg kg⁻¹ DW) at exposure to selenate. For Se toxicity, Se speciation analysis was conducted on the plants and earthworms using XAS. Compared to worm-free treatments, the percentage of organo-Se, i.e., SeMet and CysSeSeCys, increased in beans (up to 34%) in the presence of earthworms for selenate, while the elemental Se portion was significantly reduced or absent, opposite to the results for selenite. Surprisingly, elemental Se (up to 65%) dominated earthworms, regardless of the form of Se supplied. In conclusion, earthworms clearly enhanced Se uptake and translocation in plants, leading to elevated Se levels in shoots. To prevent resulting hazards to humans and other animals, caution should be taken while consuming the shoots, particularly beans, harvested from the Se contaminated soil where earthworm activity is high. Finally, the significant reduction in soil Se suggests phytoextraction of Se from the soil could be improved using earthworms as an aid to plants.

The remediation of cadmium (Cd) contaminated soil has become a global problem due to its toxicity to living organisms. In this study, earthworm (Eisenia fetida) alone or combined with EDTA or bean dregs were used for Cd removal from soils. The total and available Cd in soils, soil physicochemical and biological (soil enzyme) properties, Cd accumulation in the earthworm and its antioxidant responses towards Cd, were determined during the 35 days of soil incubation experiment. Our results showed that earthworms were capable of removing Cd from soils, and the remediation process was accelerated by both EDTA and bean dregs. By translocation of Cd from soils, the content of Cd in earthworm steadily increased with the exposure time to 8.11, 12.80, and 9.26 mg kg⁻¹ on day 35 for T2 (earthworm alone), T3 (EDTA enhancement), and T4 (bean dregs enhancement), respectively. Consequently, a great reduction in the Cd contents in soils was achieved in T3 (36.53%) and T4 (30.8%) compared with T2 (28.95%). The concentrations of water/DTPA extractable Cd were also reduced, indicating the low Cd mobility after amendment. Finally, the soil became more fertile and active after wermi-remediation. The soil pH, EC, NO₃⁻-N, available P, and K contents increased, while soil SOM, DOC, and NH₄⁺-N contents were decreased. There were higher soil enzyme activities (including acid phosphatase activity, β-glucosidase activity, and urease activity) among treatments with earthworms. Additionally, the operational taxonomic units (OTUs) increased by 100–150 units, and the higher chao1 and Shannon indexes indicated the enhanced microbial community after wermi-remediation, especially among treatment with EDTA and bean dregs. Therefore, we concluded that earthworms, alone or combined with EDTA and bean dregs, are feasible for the remediation of Cd-contaminated soil.

Iron nanoparticles (Fe NPs) have often been used for in situ remediation of both groundwater and soil. However, the impact of Fe NPs on the distribution and transformation of As species in contaminated soil is still largely unknown. In this study, green iron oxide nanoparticles synthesized using a euphorbia cochinchinensis leaf extract (GION) were used to stabilize As in a contaminated soil. GION exhibited excellent As stabilization effects, where As in non-specifically-bound and specifically-bound fractions decreased by 27.1% and 67.3% after 120 days incubation. While both arsenate (As (V)) and arsenite (As (III)) decreased after GION application, As (V) remained the dominant species in soil. X-ray photoelectron spectroscopy (XPS) confirmed that As (V) was the dominant species in specifically-bound fractions, while As (III) was the dominant species in amorphous and poorly-crystalline hydrous oxides of Fe and Al. Correlation analysis showed that while highly available As fractions were negatively correlated to oxalate and DCB extractable Fe, they were positively correlated to Fe²⁺ content, which indicated that Fe cycling was the main process influencing changes in As availability. X-ray fluorescence (XRF) spectroscopy also showed that the Fe₂O₃ content increased by 47.9% following GION soil treatments. Overall, this work indicated that As would be transformed to more stable fractions during the cycling of Fe following GION application and that the application of GION, even in small doses, provides a low-cost and ecofriendly method for the stabilization of As in soil.

Soils have the ability to modify contaminant bioavailability and toxicity. Prediction the modifying effect of soil on arsenic phytoaccumulation and phytoavailability using either soil property data or soil chemical extraction data in risk assessment of contaminated soil is highly desirable. In this study, plant bioassays important to ecological receptors, were conducted with 20 soils with a wide range in chemical and physical soil properties to determine the relationships between As measured by soil chemical extraction (soil pore water, Bray-1, sodium phosphate solution, hydroxylamine hydrochloride, and acid ammonium oxalate) or soil physico/chemical properties on arsenic phytotoxicity and phytoaccumulation. Soil pore water As and Bray-1 extracted As were significantly (P < 0.01) correlated with lettuce tissue As and those extractants and sodium phosphate were correlated with ryegrass tissue As. Hydroxylamine and acid ammonium oxalate extractions did not correlate with plant bioassay endpoints. Simple regression results showed that lettuce tissue relative dry matter growth (RDMG) was inversely related to tissue As concentration (r² = 0.85, P < 0.01), with no significant relationship for ryegrass. Soil clay exhibited strong adsorption for As and significantly reduce tissue As for lettuce and ryegrass. In addition to clay content, reactive aluminum oxide (AlOx), reactive Fe oxide (FeOx) and eCEC was inversely related to ryegrass tissue As. Multiple regression equation was strongly predictive (r² = 0.83) for ryegrass tissue As (log transformed) using soil AlOx, organic matter, pH, and eCEC as variables. Soil properties can greatly reduce contaminant phytoavailability, plant exposure and risk, which should be considered when assessing contaminant exposure and site-specific risk in As-contaminated soils.

Pollution by antimony (Sb) and arsenic (As) in soil can pose a great threat to human health. Straw-returning is widely applied to paddy fields for improving and remediating soil. A pot experiment was conducted to investigate the effect of straw-returning on Sb and As transformation and translocation in a soil–rice system. In this study, Sb and As co-contaminated soil was thoroughly mixed with different proportions (0, 0.5, 1, and 2%) of straw and used for growing rice plants through the entire growing stage in a pot experiment and 4 weeks in a microcosm experiment. The straw application significantly increased Sb and As mobility. The concentrations of total Sb and As in soil-pore water increased after the application of straw in most growing stages. The Sb volatilization in the pot and microcosm experiments was also stimulated by straw application. With the high dose of straw application (2%), the concentration of Sb in brown grain was reduced by 72% compared with the control, but As concentrations increased by around 77%. These findings provide a new perspective in that straw-returning could affect the behavior of both Sb and As in soil and reduce the Sb accumulation in brown grain and some guidance in the use of straw-returning in Sb-contaminated paddy soil.

Biochar has a wide range of feedstocks, and different feedstocks often resulted in different properties, such as element distribution and heavy metal immobilization performance. In this work, batch experiments were conducted to assess the effectiveness of biochar pyrolyzed from kitchen waste (KWB), corn straw (CSB), and peanut hulls (PHB) on immobilization of Cd and Pb in contaminated soil by planting swamp cabbage (Ipomoea aquatica Forsk.) with a combination of toxicological and physiological tests. The results showed that biochar could all enhance the soil pH, and reduce extractable Pb and Cd in soil by 22.61%–71.01% (KWB), 18.54%–64.35% (CSB), and 3.28%–60.25% (PHB), respectively. The biochar led to a drop in Cd and Pb accumulation in roots, stems, and leaves by 45.43%–97.68%, 59.13%–96.64%, and 63.90%–99.28% at the dosage of 60.00 mg/kg, respectively. The root length and fresh weight of swamp cabbage were promoted, while superoxide dismutase (SOD) and peroxidase (POD) decreased after biochar treatment. The distribution of heavy metal fractions before and after biochar treatment indicated that biochar could transform Cd and Pb into a state of lower bioavailability, thus inhibiting Cd and Pb uptake by swamp cabbage. Biochar with different feedstocks could be ranked by the following order according to immobilization performance: KWB > CSB > PHB.

As a result of metal mining activities in Pakistan, toxic heavy metals (HMs) such as chromium (Cr) and lead (Pb) often enter the soil ecosystem, accumulate in food crops and cause serious human health and environmental issues. Therefore, this study examined the efficacy of biochar for contaminated soil remediation. Poplar wood biochar (PWB) and sugarcane bagasse biochar (SCBB) were amended to mine-contaminated agricultural soil at 3% and 7% (wt/wt) application rates. Lactuca sativa (Lettuce) was cultivated in these soils in a greenhouse, and uptake of HMs (Cr and Pb) as well as biomass produced were measured. Subsequently, health risks were estimated from uptake data. When amended at 7%, both biochars significantly (P<0.01) reduced plant uptake of Cr and Pb in amended soil with significant (P<0.01) increase in biomass of lettuce as compared to the control. Risk assessment results showed that both biochars decreased the daily intake of metals (DIM) and associated health risk due to consumption of lettuce as compared to the control. The Pb human health risk index (HRI) for adults and children significantly (P<0.01) decreased with sugarcane bagasse biochar applied at 7% rate relative to other treatments (including the control). Relative to controls, the SCBB and PWB reduced Cr and Pb uptake in lettuce by 69%, 73.7%, respectively, and Pb by 57% and 47.4%, respectively. For both amendments, HRI values for Cr were within safe limits for adults and children. HRI values for Pb were not within safe limits except for the sugarcane bagasse biochar applied at 7%. Results of the study indicated that application of SCBB at 7% rate to mine impacted agricultural soil effectively increased plant biomass and reduced bioaccumulation, DIM and associated HRI of Cr and Pb as compared to other treatments and the control.

Cadmium (Cd) as a highly toxic heavy metal can cause seriously harmful to human health. Rice consumption is a major source of Cd intake by Chinese. Reduce the Cd accumulation by rice is the key for reducing Cd hazard. Therefore, fly ash (FA) was used as raw material in this study, after the process of simplifying hydrothermal synthesis the zeolite (ZE), which was named as low-temperature-alkali roasting, a new intermediate materials (IP) was got. And the three mentioned materials (FA, IP and ZE) were used for a two-year field experiment. The study demonstrated that, application of IP and ZE could promote rice growth, as well as increase soil pH, and improve available Si content. The rice production increased by 36.1% and 29.8% in 2017 by IP and ZE applied, enhanced 35.9% and 31.7% in 2018, respectively. Meanwhile, the bio-available Cd decreased by 26.9% and 26% in 2017, reduced by 22.9% and 28% in 2018, respectively. Generally, the passivators could promote the conversion of acid-exchangeable fraction Cd to reducible fraction Cd. It can be conclude that, IP and ZE have good remediation effect on contaminated soil, and alleviated effects on Cd accumulation by rice, even though no significant difference was detected between IP and ZE. The synthesis process of IP of is simpler than ZE. The impact of IP on contaminated soil needs further exploration.

Oil-contaminated soils resulted from drilling activities can cause significant damages to the environment, especially for living organisms. Treatment and management of these soils are the necessity for environmental protection. The present study investigates the field study of seven oil-contaminated soils treated by different stabilization/solidification (S/S) methods, and the selection of the best treated site and treatment method. In this study, first, the ratios of consumed binders to the contaminated soils (w/w) and the treatment times for each unit of treated soils were evaluated. The ratios of consumed binders to the contaminated soils were between 6 and 10% and the treatment times for each unit of treated soils were between 4.1 and 18.5 min/m³. Physicochemical characteristics of treated soils were also determined. Although S/S methods didn’t change the water content of treated soils, they increased the porosity of soils. Unexpectedly, the cement-based S/S methods didn’t increase the pH of the treated soils. The highest and the lowest leaching of petroleum hydrocarbons was belonging to S/S using diatomaceous earth (DE) and the combination of Portland cement, sodium silicate and DE (CS-DE), respectively. The best acid neutralization capacity was obtained for soils treated using the combination of Portland cement and sodium silicate (CS). Based on the best-worst multi-criteria decision-making method (BWM-MCDM), the soils treated using CS-DE was select as the best. The BWM-MCDM can be used as an effective tool for the selection of the best alternative in all areas of environmental decontamination.