Pyrolysis is a promising thermochemical conversion process that transforms biomass into biochar, a carbon-rich solid material, in an oxygen-limited environment. This study focuses on the utilization of rice byproducts, namely rice straw and rice husk as feedstock for biochar production through low-temperature pyrolysis. The aim is to explore the potential of these biochars as cost-effective adsorbents for removing metal contaminants from aqueous solutions, with a particular emphasis on Pb(II) removal. Physicochemical properties of the biochars produced at a low temperature of 300 °C were thoroughly investigated, including surface morphology and their adsorption capacity for Pb(II). Remarkably, the rice straw biochar (RSB) produced at 300 °C exhibited exceptional Pb(II) adsorption capacity, with a value of 390.10±0.30 mg/g, and demonstrated a high Pb(II) removal efficiency of 96.10±0.30% when modified with 30% w/w H2O2. A crucial aspect of this study lies in the evaluation of the cost-effectiveness of the biochar production process, particularly when compared to commercially available adsorbents. By demonstrating the potential of rice byproduct-derived biochar as an efficient Pb(II) biosorbent in aqueous environments, this work not only provides new insights into the preparation of biochar using low-temperature pyrolysis but also offers a viable and economical solution for metal-contaminated water treatment. The findings of this research contribute to the field of sustainable waste utilization and highlight the significant potential of rice byproduct-based biochar as an environmentally friendly adsorbent for heavy metal removal.