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Status and evaluation of the selected soil nutrients irrigated by unconventional water (Case study: Qom) Full text
2016
Arast, Mina | Zehtabian, Gholamreza | Jafari, Mohammad | Khosravi, Hassan | Jabalbarezi, Bahareh
Population’s exponential growth along with drought has increased water resources limitation, especially in arid and semi-arid area. Therefore, the use of non-conventional water is an important tool for water resource management. If unconventional water has no negative impact on soil properties and water, it can be used for irrigation coupled with desertification projects. So, this paper tries to present the effect of irrigation with municipal wastewater, salt water, brackish water, and combination of salty water and wastewater on some soil properties including nitrogen, phosphorus, and potassium in Qom plain. Soil samples were taken from agricultural land treated by wastewater, saline water, brackish water, combination of salty water, and wastewater and range land as control in five treatments from depths of 0-30 and 60-90 centimeter. The results showed that wastewater has increased the amount of N, P, and K to other treatments and control area. The concentration of potassium in surface layer of area treated by combination of salty water and wastewater with amount of 459.39 ppm has the most significant difference to control and other treatments. Also, the maximum amount of nitrogen was observed in sub layer of saline and brackish water treatment with amount of 0.08 percent.
Show more [+] Less [-]Evaluation of Faryab spring hydrochemistry in Hormozgan Province, Southern Iran Full text
2017
Asadpour, Gholamabbas
With a mean precipitation rate, much lower than that of the world, Iran is among the countries that face severe water challenges. The present study has dealt with the evaluation of hydrochemistry of Faryab spring water in Hormozgan Province, Iran. Four different composite water samples have been analyzed to detect major anions, cations, total dissolved solids, electrical conductivity, pH, and sodium absorption ratio. The dominant water type was detected as sodium-chloride, with remarkable high concentration of sodium and chloride ions that makes it unfit for drinking purposes. Regarding irrigation use, high values of electrical conductivity (29989 to 31983 µS/cm) and sodium absorption ratio (SAR) (58.1 to 61) indicate a very high risk level for salinity and sodium alkali hazards, respectively. Abundance of secondary minerals such as halite and gypsum is considered to be the main reason for remarkably-high TDS values. Intensity of salt domes within the area would also facilitate solution/dissolution process of Na+ and Cl- into water column.
Show more [+] Less [-]A double pre-selection method for natural background levels assessment in coastal groundwater bodies Full text
2022
Parrone, D. | Frollini, E. | Masciale, R. | Melita, M. | Passarella, G. | Preziosi, E. | Ghergo, S.
To evaluate the chemical status of groundwater bodies (GWB) according to the European Groundwater Directive, EU Member States are required to take into account natural background levels (NBLs) where needed. Assessing the NBLs in coastal GWBs is complicated by seawater intrusion which can be amplified by groundwater withdrawals increasing the salinization of such groundwater systems. This paper proposes a new method for the NBLs assessment in coastal areas based on a double pre-selection (PS) with fixed/dynamic limits. A case study in the Apulia region, located in southeastern Italy, is proposed, where we investigated four adjacent GWBs which form the complex karst, fractured Murgia aquifer, hosted in the Jurassic-Cretaceous carbonate platform, bounded by two seas and sustained by saltwater of marine intrusion in the coastal areas. Data related to 139 monitoring stations (MSs) of the regional groundwater monitoring network were used. The first PS, “static”, based on a fixed limit of anthropogenic contamination markers (NO₃ and NH₄), allows for the elimination of MSs impacted by human activities. On these, the second PS, “dynamic”, based on the identification of Cl anomalous values, allows for the identification of additional MSs affected by saline contamination. The residual dataset of MSs was used for the definition of NBLs of Cl, SO₄, F and B. A statistical comparison with historical Cl observations finally allowed us to verify if the salinity of current groundwater is representative of pristine conditions. The calculated NBLs of salinity parameters are higher for the two coastal GWBs, with chloride values between 0.8 and 2 mg/L. Conversely, fluorides always show very low NBLs. The double PS approach seems more effective for NBLs calculation in coastal aquifers affected by saline contamination, where the use of a fixed Cl limit fails. It may respond to the international needs for a standardized procedure for NBL assessment.
Show more [+] Less [-]Microplastisphere may induce the enrichment of antibiotic resistance genes on microplastics in aquatic environments: A review Full text
2022
Yu, Xue | Zhang, Ying | Tan, Lu | Han, Chenglong | Li, Haixiao | Zhai, Lifang | Ma, Weiqi | Li, Chengtao | Lu, Xueqiang
Microplastics have been proven to be hotspots of bacterial pathogens and antibiotic resistance genes (ARGs). The enrichment of ARGs in microplastisphere, the specific niche for diverse microbial communities attached to the surface of microplastic, has attracted worldwide attention. By collecting 477 pairs of ARG abundance data belonging to 26 ARG types, based on the standardized mean difference (SMD) under the random effect model, we have performed the first meta-analysis of the ARG enrichment on microplastics in aquatic environments in order to quantitatively elucidate the enrichment effect, with comparison of non-microplastic materials. It was found that ARGs enriched on the microplastics were more abundant than that on the inorganic substrates (SMD = 0.26) and natural water environments (SMD = 0.10), but lower abundant than that on the natural organic substrates (SMD = −0.52). Furthermore, microplastics in freshwater tended to have a higher degree of ARG enrichment than those in saline water and sewage. The biofilm formation stage, structure, and component of microplastisphere may play a significant role in the enrichment of ARGs.
Show more [+] Less [-]Distribution and partitioning of heavy metals in water and sediments of a typical estuary (Modaomen, South China): The effect of water density stratification associated with salinity Full text
2021
Jia, Zhenzhen | Li, Shiyu | Liu, Qiuxin | Jiang, Feng | Hu, Jiatang
Many estuaries have undergone severe saltwater intrusion in addition to simultaneously experiencing serious heavy metal pollution. To explore the effect of water density stratification associated with saltwater intrusion on the behaviour of heavy metals (Cr, Co, Ni, Cu, Zn, As, Pb, and Cd) in water and sediments, a field survey was conducted in a typical estuary (Modaomen). The content, distribution, and mobility of heavy metals were investigated, as well as the influence of environmental factors on their future. The results showed that Modaomen estuary was characterised by a notable variation in salinity along the estuary, presenting total freshwater upstream, high salinity stratification water in the mouth, and saltwater offshore. Dissolved metals presented a prominent gradient vertically, with 1.2–2.1 times higher in bottom water than in surface water and the highest contents in the highly–stratified bottom water. Elevated salinity and restricted mixing induced by water stratification were likely the causes of this outcome. The distribution of heavy metals in sediments was greatly governed by grain size, Fe/Mn (hydr)oxides, total organic carbon, salinity, and dissolved oxygen. Comprehensive evaluation, combined with total contents and chemical fractions of heavy metals, indicated that internal release from sediments contributed a considerable part to the higher levels of heavy metals in bottom water, particularly for Zn and Pb, which was fully consistent with their status in water body, and elevated salinity and lack of oxygen were likely the primary driving factors. During the phase-partition processes between bottom water and sediments, partitioning coefficients were markedly lower in the highly stratified zone, implying that saltwater intrusion facilitated the mobility and repartitioning processes of metals. Because of increased levels and toxicity of heavy metals in water and extended residence time during saltwater intrusion, the potential damage to the estuarine ecosystem should receive more attention.
Show more [+] Less [-]Toxicity of TiO2, in nanoparticle or bulk form to freshwater and marine microalgae under visible light and UV-A radiation Full text
2017
Sendra, M. | Moreno-Garrido, I. | Yeste, M.P. | Gatica, J.M. | Blasco, J.
Toxicity of TiO2, in nanoparticle or bulk form to freshwater and marine microalgae under visible light and UV-A radiation Full text
2017
Sendra, M. | Moreno-Garrido, I. | Yeste, M.P. | Gatica, J.M. | Blasco, J.
Use of titanium dioxide nanoparticles (TiO2 NPs) has become a part of our daily life and the high environmental concentrations predicted to accumulate in aquatic ecosystems are cause for concern. Although TiO2 has only limited reactivity, at the nanoscale level its physico-chemical properties and toxicity are different compared with bulk material. Phytoplankton is a key trophic level in fresh and marine ecosystems, and the toxicity provoked by these nanoparticles can affect the structure and functioning of ecosystems. Two microalgae species, one freshwater (Chlamydomonas reinhardtii) and the other marine (Phaeodactylum tricornutum), have been selected for testing the toxicity of TiO2 in NP and conventional bulk form and, given its photo-catalytic properties, the effect of UV-A was also checked. Growth inhibition, quantum yield reduction, increase of intracellular ROS production, membrane cell damage and production of exo-polymeric substances (EPS) were selected as variables to measure.TiO2 NPs and bulk TiO2 show a relationship between the size of agglomerates and time in freshwater and saltwater, but not in ultrapure water. Under two treatments, UV-A (6 h per day) and no UV-A exposure, NPs triggered stronger cytotoxic responses than bulk material. TiO2 NPs were also associated with greater production of reactive oxygen species and damage to membrane. However, microalgae exposed to TiO2 NPs and bulk TiO2 under UV-A were found to be more sensitive than in the visible light condition. The marine species (P. tricornutum) was more sensitive than the freshwater species, and higher Ti internalization was measured. Exopolymeric substances (EPS) were released from microalgae in the culture media, in the presence of TiO2 in both forms. This may be a possible defense mechanism by these cells, which would enhance processes of homoagglomeration and settling, and thus reduce bioavailability.
Show more [+] Less [-]Toxicity of TiO2, in nanoparticle or bulk form to freshwater and marine microalgae under visible light and UV-A radiation Full text
2017
Sendra, Marta | Moreno-Garrido, Ignacio | Yeste, María Pilar | Gatica, José Manuel | Blasco, Julián | Junta de Andalucía | Ministerio de Economía y Competitividad (España) | European Commission
Use of titanium dioxide nanoparticles (TiO2 NPs) has become a part of our daily life and the high environmental concentrations predicted to accumulate in aquatic ecosystems are cause for concern. Although TiO2 has only limited reactivity, at the nanoscale level its physico-chemical properties and toxicity are different compared with bulk material. Phytoplankton is a key trophic level in fresh and marine ecosystems, and the toxicity provoked by these nanoparticles can affect the structure and functioning of ecosystems. Two microalgae species, one freshwater (Chlamydomonas reinhardtii) and the other marine (Phaeodactylum tricornutum), have been selected for testing the toxicity of TiO2 in NP and conventional bulk form and, given its photo-catalytic properties, the effect of UV-A was also checked. Growth inhibition, quantum yield reduction, increase of intracellular ROS production, membrane cell damage and production of exo-polymeric substances (EPS) were selected as variables to measure. TiO2 NPs and bulk TiO2 show a relationship between the size of agglomerates and time in freshwater and saltwater, but not in ultrapure water. Under two treatments, UV-A (6 h per day) and no UV-A exposure, NPs triggered stronger cytotoxic responses than bulk material. TiO2 NPs were also associated with greater production of reactive oxygen species and damage to membrane. However, microalgae exposed to TiO2 NPs and bulk TiO2 under UV-A were found to be more sensitive than in the visible light condition. The marine species (P. tricornutum) was more sensitive than the freshwater species, and higher Ti internalization was measured. Exopolymeric substances (EPS) were released from microalgae in the culture media, in the presence of TiO2 in both forms. This may be a possible defense mechanism by these cells, which would enhance processes of homoagglomeration and settling, and thus reduce bioavailability. | This research has been funded by the Junta de Andalucía (PE2011-RNM-7812 project and FQM-110 group) and the Spanish National Research Plan (CTM2012-38720-C03-03) and FEDER fundings (MAT2013-40823-R). | Peer reviewed
Show more [+] Less [-]Effects of a brine discharge over soft bottom Polychaeta assemblage Full text
2008
Del-Pilar-Ruso, Yoana | De-la-Ossa-Carretero, Jose Antonio | Giménez-Casalduero, Francisca | Sánchez Lizaso, José Luis
Effects of a brine discharge over soft bottom Polychaeta assemblage Full text
2008
Del-Pilar-Ruso, Yoana | De-la-Ossa-Carretero, Jose Antonio | Giménez-Casalduero, Francisca | Sánchez Lizaso, José Luis
Desalination is a growing activity that has introduced a new impact, brine discharge, which may affect benthic communities. Although the role of polychaetes as indicators to assess organic pollution is well known, their tolerance to salinity changes has not been examined to such a great extent. The aim of this study was to examine the effect of brine discharge over soft bottom polychaete assemblage along the Alicante coast (Southeast Spain) over a two year period. Changes in the polychaete assemblage was analysed using univariate and multivariate techniques. We compared a transect in front of the discharge with two controls. At each transect we sampled at three depths (4, 10 and 15 m) during winter and summer. We have observed different sensitivity of polychaete families to brine discharges, Ampharetidae being the most sensitive, followed by Nephtyidae and Spionidae. Syllidae and Capitellidae showed some resistance initially, while Paraonidae proved to be a tolerant family. The Polychaete assemblage is affected by the brine discharge of the Alicante desalination plant and we detect different sensitivity levels in polychaete families to brine impact.
Show more [+] Less [-]Effects of a brine discharge over soft bottom Polychaeta assemblage Full text
2007 | 2008
Del-Pilar-Ruso, Yoana | de-la-Ossa-Carretero, Jose Antonio | Gimenez-Casalduero, Francisca | Sánchez-Lizaso, José Luis | Universidad de Alicante. Departamento de Ciencias del Mar y Biología Aplicada | Biología Marina
Desalination is a growing activity that has introduced a new impact, brine discharge, which may affect benthic communities. Although the role of polychaetes as indicators to assess organic pollution is well known, their tolerance to salinity changes has not been examined to such a great extent. The aim of this study was to examine the effect of brine discharge over soft bottom polychaete assemblage along the Alicante coast (Southeast Spain) over a two year period. Changes in the polychaete assemblage was analysed using univariate and multivariate techniques. We compared a transect in front of the discharge with two controls. At each transect we sampled at three depths (4, 10 and 15 m) during winter and summer. We have observed different sensitivity of polychaete families to brine discharges, Ampharetidae being the most sensitive, followed by Nephtyidae and Spionidae. Syllidae and Capitellidae showed some resistance initially, while Paraonidae proved to be a tolerant family. | This work was funded by the Mancomunidad de los Canales de Taibilla.
Show more [+] Less [-]The adaptive mechanism of halophilic Brachybacterium muris in response to salt stress and its mitigation of copper toxicity in hydroponic plants Full text
2022
Liu, Siyu | Liu, Xiayu | Shi, Ying | Zhuang, Shulin | Chen, Qihe
Serious environmental pollution of heavy metals has attracted people's attention in recent years and halophiles seem to be potential bioremediation in the controlling of heavy metals contamination. In this study, the adaptive mechanism of halophilic Brachybacterium muris (B. muris) in response to salt stress and its mitigation of copper (Cu) toxicity in hydroponic plants were investigated. The cell morphology was observed using transmission electron microscopy. The cell membrane composition and fluidity were examined by the combination of gas chromatography, gas chromatography-mass spectrometry, ultra-high performance liquid chromatography-mass spectrometry, and fluorescence spectrophotometry. Moreover, the metabolic pathways of B. muris in response to salt stress were analyzed using the prokaryotic transcriptomics approach. A hydroponic co-culture model was further conducted to explore the effects of B. muris on wheat seedlings subjected to Cu toxicity. It was found that B. muris can respond to high osmotic pressure by improving the cell membrane fluidity, altering the cell morphology and cell membrane compositions. The proportion of unsaturated fatty acids, phosphatidylethanolamine, and phosphatidylinositol in B. muris cell membranes increased significantly, while zymosterol, fecosterol, and ergosterol contents decreased under a high salinity situation. Further transcriptomic analysis showed that genes encoding L-glutamate synthase, glutamate ABC transporter ATP-binding protein, and sodium cotransporter were up-regulated, indicating that both the synthesis and transport of glutamate were significantly enhanced under high osmotic pressure. Additionally, B. muris alleviated the inhibitory effect of Cu²⁺ on wheat seedlings' growth, causing a 30.14% decrease in H₂O₂ content and a significant increase of 83.86% and 45.96% in POD activity and GSH content in wheat roots, respectively. The findings of this study suggested that the salt-tolerant B. muris may serve as a promising strategy for improving the bioremediation of metal-contaminated saline water and soils.
Show more [+] Less [-]“Smart” nanosensors for early detection of corrosion: Environmental behavior and effects on marine organisms Full text
2022
Martins, Roberto Borges | Figueiredo, Joana | Sushkova, Alesia | Wilhelm, Manon | Tedim, João | Loureiro, Susana
“Smart” nanosensors for early detection of corrosion: Environmental behavior and effects on marine organisms Full text
2022
Martins, Roberto Borges | Figueiredo, Joana | Sushkova, Alesia | Wilhelm, Manon | Tedim, João | Loureiro, Susana
Corrosion is an environmental and economic global problem. “Smart” or stimuli-responsive colorimetric nanosensors for maritime coatings have been proposed as an asset to overcome the limitations of the current monitoring techniques by changing color in the presence of triggers associated with the early stages of corrosion. Layered double hydroxides (Zn–Al LDH; Mg–Al LDH) and silica mesoporous nanocapsules (SiNC) were used as precursor nanocarriers of active compounds: hexacyanoferrate ions ([Fe(CN)₆]³⁻) and phenolphthalein (PhPh), respectively. Additionally, the safer-by-design principles were employed to optimize the nanosensors in an eco-friendly perspective (e.g., regular vs. warm-washed SiNC-PhPh; immobilization using different carriers: Zn–Al LDH-[Fe(CN)₆]³⁻ vs. Mg–Al LDH-[Fe(CN)₆]³⁻). Therefore, the present study aims to assess the environmental behavior in saltwater and the toxic effects of the nanosensors, their nanocarriers, and the active compounds on the marine microalgae Tetraselmis chuii and the crustacean Artemia salina. Briefly, tested compounds exhibited no acute toxic effects towards A. salina (NOEC = 100 mg/L), apart from SiNC-PhPh (LC₅₀ = 2.96 mg/L) while tested active compounds and nanosensors caused significant growth inhibition on T. chuii (lowest IC₅₀ = 0.40 mg/L for SiNC-PhPh). The effects of [Fe(CN)₆]³⁻ were similar regardless of the nanocarrier choice. Regarding SiNC-PhPh, its toxicity can be decreased at least twice by simply reinforcing the nanocapsules washing, which contributes to the removal (at least partially) of the surfactants residues. Thus, implementing safe-by-design strategies in the early stages of research proved to be critical, although further progress is still needed towards the development of truly eco-friendly nanosensors.
Show more [+] Less [-]“Smart” nanosensors for early detection of corrosion: environmental behavior and effects on marine organisms Full text
2022 | 2024
Martins, Roberto | Figueiredo, Joana | Sushkova, Alesia | Wilhelm, Manon | Tedim, João | Loureiro, Susana
Corrosion is an environmental and economic global problem. “Smart” or stimuli-responsive colorimetric nanosensors for maritime coatings have been proposed as an asset to overcome the limitations of the current monitoring techniques by changing color in the presence of triggers associated with the early stages of corrosion. Layered double hydroxides (Zn–Al LDH; Mg–Al LDH) and silica mesoporous nanocapsules (SiNC) were used as precursor nanocarriers of active compounds: hexacyanoferrate ions ([Fe(CN)6] 3-) and phenolphthalein (PhPh), respectively. Additionally, the safer-by-design principles were employed to optimize the nanosensors in an ecofriendly perspective (e.g., regular vs. warm-washed SiNC-PhPh; immobilization using different carriers: Zn–Al LDH-[Fe(CN)6] 3- vs. Mg–Al LDH-[Fe(CN)6] 3-). Therefore, the present study aims to assess the environmental behavior in saltwater and the toxic effects of the nanosensors, their nanocarriers, and the active compounds on the marine microalgae Tetraselmis chuii and the crustacean Artemia salina. Briefly, tested compounds exhibited no acute toxic effects towards A. salina (NOEC = 100 mg/L), apart from SiNC-PhPh (LC50 = 2.96 mg/L) while tested active compounds and nanosensors caused significant growth inhibition on T. chuii (lowest IC50 = 0.40 mg/L for SiNC-PhPh). The effects of [Fe(CN)6] 3- were similar regardless of the nanocarrier choice. Regarding SiNC-PhPh, its toxicity can be decreased at least twice by simply reinforcing the nanocapsules washing, which contributes to the removal (at least partially) of the surfactants residues. Thus, implementing safe-by-design strategies in the early stages of research proved to be critical, although further progress is still needed towards the development of truly eco-friendly nanosensors. | published
Show more [+] Less [-]Optimized parameters of the electrocoagulation process using a novel reactor with rotating anode for saline water treatment Full text
2020
Al-Raad, Abbas A. | Hanafiah, Marlia M. | Naje, Ahmed Samir | Ajeel, Mohammed A.
In this study, a novel rotating anode-based reactor (RAR) was designed to investigate its effectiveness in removing dissolved salts (i.e., Br⁻, Cl⁻, TDS, and SO₄²⁻) from saline water samples. Two configurations of an impeller’s rotating anode with various operation factors, such as operating time (min), rotating speed (rpm), current density (mA/cm²), temperature (°C), pH, and inter-electrode space (cm), were used in the desalination process. The total cost consumed was calculated on the basis of the energy consumption and aluminum (Al) used in the desalination. In this respect, operating costs were calculated using optimal operating conditions. Salinity was removed electrochemically from saline water through electrocoagulation (EC). Results showed that the optimal adjustments for treating saline water were carried out at the following conditions: 150 and 75 rpm rotating speeds for the impeller’s rod anode and plate anode designs, respectively; 2 mA/cm² current density (I), 1 cm² inter-electrode space, 25 °C temperature, 10 min operation time, and pH 8. The results indicated that EC technology with impeller plates of rotating anode can be considered a very cost-effective technique for treating saline water.
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