Pentachlorophenol (PCP) vertical transportation in soil column during its phototransformation on the soil surface was investigated using a new designed photoreactor. Three kinds of soils were used to study the effect of soil water and soil properties. In air-dried sandy loam, no obvious PCP transportation occurred in the soil profile when PCP was phototransformed on the soil surface. And the average removal of PCP in the whole soil column was close to zero after 48 h irradiation. In the moist sandy loam, PCP in the deeper soil could transport to the soil surface with water evaporation and then be transformed during UV irradiation, thus the average PCP removal in the whole soil column was improved. When the initial water contents are 9.3 and 19.2%, the average PCP removal in the sandy loam after 48 h irradiation accounted to 20.9 and 39.9%, respectively. The improving of PCP removal induced by soil water was limited in the clay and silt soils where PCP transportation was impeded because of their higher adsorption capacity. In the silt soil where the initial water content was 19.7%, not only PCP transportation in the deeper soil but also PCP phototransformation on the surface was inhibited seriously because of the high organic matter content of 18%.

Cementitious materials are commonly used to reinforce the bearing capacity of silty soils. However, there is very little data about how changes in arsenic (As) leaching from silty soils caused by the addition of cementitious materials. Therefore, batch leaching tests were conducted using As-bearing silty soil under different pH conditions. The pH was adjusted by changing the amount of slag cement added or the concentration of sodium hydroxide. This allows us to evaluate the effects of cement on As leaching. In addition, two different additives were applied to reduce As migration. The results show that high concentration of calcium ion (Ca²⁺) in leachates of soil-cement mixture has a significant effect in reducing the mobility of As even under hyperalkaline pH conditions. Arsenic immobilized by Ca²⁺ was observed in two patterns. The first mechanism was the help of Ca²⁺ to reduce the negative electrical potential on the surface of (hydr)oxide minerals under high pH conditions, thereby reducing the mobility of As by adsorption and coagulation of fresh precipitates of Fe and Al hydroxides. The second was the precipitation of calcium carbonate. This precipitate either directly adsorb/co-precipitate As or lower the concentration of strong competing ion, silica, both of which reduced the As mobility. When Ca- or Mg-based additive was added to the silty soil-cement mixture, As concentration in the leachate decreased. These findings are useful in developing sustainable soil-cement reinforcement techniques to avoid contamination.

Bioremediation strategies, including biostimulation, exogenous bioaugmentation and autochthonous bioaugmentation, were evaluated to determine their ability to degrade petroleum hydrocarbons in two recently polluted agricultural soils, one with a clayey texture and a silty loam soil. It was hypothesized in this work that the bioavailability of the pollutant may depend on the soil type, which would determine the biodegradation rate and the correct methodology to be used. The soils were artificially contaminated with diesel fuel, and several soil–water suspension batch microcosm experiments were conducted to observe the bioremediation process. The inocula used in the experiments included an autochthonous soil consortium and an exogenous consortium that had been acclimated to diesel consumption. The clayey soil desorbed diesel quickly, while the silty soil, with a higher organic content, did not. Hydrocarbon availability was limited in the latter case. After 48 h of treatment, the diesel removal efficiency in the clayey soil was clearly higher than that in the silty soil. However, after 11 days, the efficiencies were similar, and more than 95% of the diesel was biodegraded in most experiments. According to the efficiency and bioavailability analyses, the best methodology to bioremediate the silty soil was biostimulation with the native consortium. In contrast, bioaugmentation with a combination of native and exogenous consortia was chosen to treat the clayey soil. The results of this study suggest that when pollutants are easily available, bioaugmentation can successfully remediate the pollution. However, when availability is limited, biostimulation can be more efficient.

Stabilisation/solidification (S/S) of heavy metals and a parallel biodegradation of an organic contaminant using magnesium phosphate cements (MPC) was investigated under laboratory conditions. The study was aimed at improving the robustness of S/S technology by encouraging biodegradation in order to bring about some form of contaminant attenuation over time. A silty sand soil, amended with compost was spiked with an organic contaminant, 2-chlorobenzoic acid (2CBA), and two heavy metal compounds, lead nitrate and zinc chloride. Two formulations of the MPC grouts based on different proportions of the cement constituents, with paste pH of approximately 6.5 and 10, were utilised for S/S treatment. The study involved treating the organic contaminant present in the soil with and without the heavy metals by employing the low and high pH MPC grout mixes, and using 10% and 25% compost content. Microbial activity was monitored using dehydrogenase assay, whilst the tests pertaining to the performance criteria such as contaminant concentration, unconfined compressive strength, elastic stiffness, permeability and batch leaching tests were evaluated at set periods. Contaminant recovery analysis after 140 days indicated a similar reduction in 2CBA concentration to approximately 56% in the different grout mixes. The cement constituents exhibited stimulatory and inhibitory effects on soil dehydrogenase activity. Heavy metal leachability as well as the engineering behaviour of the treated soils conformed to acceptable standards. The results of the investigations show considerable promise for the application of MPC in contaminated land remediation.

The aim of the present study was the influence of various methods of long-term soil utilisation on the content of polycyclic aromatic hydrocarbons (PAH) in selected silty soils. Four soils were selected for the present studies, i.e.: Eutric Fluvisol originating from silty formations, Haplic Phaeozem developed from loess, Haplic Luvisol (non-uniform) developed from silt, Haplic Luvisol developed from loess. Five study sites were chosen, i.e.: apple orchards, hop gardens, fields, grasslands and natural woodland ecosystems. Samples were collected from the depth of 0-10 cm. In the samples the content of 16 PAHs was determined by means of the HPLC-UV method. The total PAHs content was at a low level. Depending on the soil and object type, the total PAHs content ranged from 72.5 to 764.0 μg·kg-¹. The pollutant level determined together with composition of individual PAHs suggested a limited anthropogenic influence relating mainly to pyrolytic processes. The total PAH content as well as the content of individual PAHs depended on agricultural land use and management. It has been shown that PAH level was influenced by environmental conditions specific for a given type of land use. In the soils in which organic carbon content differed only slightly among locations, a higher influence of the soil utilisation method on the content of individual PAHs was observed.

In recent years, with the frequent occurrences of heavy metal (HM) pollution in agriculture, the problem of HM pollution in farmland soil, especially in the areas irrigation by the Yellow River, has been attracted increasing attention because of the complex sources of pollution. Qualitative identification of pollution sources and quantification of their contributions to HMs in soil are the key links in the prevention and control of HM pollution. The contents of 11 heavy metals (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sn, V, and Zn) in the rhizosphere soil of the Ningxia irrigation area were determined by inductively coupled plasma mass spectrometry (ICP-MS). Multiple methods were used for source identification, including positive matrix factorization (PMF) analysis combined with multiple other analyses (single factor index method (Pi), coefficient of variation(CV), correlation analysis(CA), enrichment factor(EF), and principal component analysis(PCA)). The results showed that (1) the over-standard rates of As, Cd, Cr, Mn, Pb, Sn, and Zn in the study area were 100%, of which Cd was seriously polluted, while As, Zn, and Sn were moderately polluted. (2) The HM contributions from irrigation and silt soil formed by the Yellow River sediment were the highest (42.45%), followed by the smelting industry and traffic pollution (16.06%). (3) The contribution of agricultural pollution to HMs in the region was 15.54%, in which As was mainly from pesticides and Cd was mainly from fertilizers.