The project aims to remove reactive blue dye from the effluent of textile industries by utilizing coal-associated soil as an adsorbent, as it possesses effective physical properties and distinguishing characteristics. In comparison to other separation techniques, the adsorption method is the most effective, cost-effective, and straightforward. A batch adsorption investigation was carried out to examine the various adsorption-influencing factors, including solution pH, adsorbent dosage, contact time, temperature, and dye concentration. Contact time of 30 min, an adsorbent dosage of 10g.100 mL-1, a solution pH of 7, a temperature of 30°C, and an initial dye concentration of 100 mg.L-1 were found to be optimal for dye adsorption. Using two distinct kinetic models, the evaluation of kinetic studies revealed that the pseudo-second-order provided the greatest fit, with a higher R2 value than the pseudo-first-order. The thermodynamic parameters Gibbs free energy (ΔG°), entropy (ΔS°), and enthalpy (ΔH°) indicated that the current adsorption system was exothermic and spontaneous. Further study of the adsorption isotherm revealed that the Langmuir isotherm model provided the best fit, with an R2 value of 0.977%.

The occurrence of heavy metals in soil and selected edible plants (Manihot esculenta, Dioscorea rotundata, Ipomoea batatas, Telfairia occidentalis, and Chromolaena odorata) in the vicinity of major Lead-Zinc mining sites in Ebonyi State, Nigeria was investigated. The concentrations of the detected heavy metals in soil from the study sites ranged from 0.38-77830.99 (mg.kg-1). The limit values for all detected metals in soil from the mining sites were exceeded in most instances. The results showed that the plant species accumulated heavy metals near the mining sites to varying levels in their shoots and roots. The limit values for all detected heavy metals in the edible plants were not exceeded except in a few instances. The plant species demonstrated varying effectiveness for phytoextraction, indicating their appropriateness in the phytoremediation of heavy metal-contaminated soil. Therefore, examining the environmental consequences of uncontrolled mining activity in the vicinity of the mining sites with a scientific approach has helped to increase our knowledge of the pollution problem in the mining sites, reveal the ferocity of the situation, and contribute to the techniques presently in use for monitoring chemical pollution in a mining-impacted ecosystem.