We investigated how sulfur (S) application prior to wheat cultivation under wheat-rice rotation influences the uptake of cadmium (Cd) in rice grown in low- and high-Cd soils. A pot experiment was conducted with four S levels (0, 30, 60, 120 mg S kg⁻¹) and two Cd rates (low and high, 0.35 and 10.35 mg Cd kg⁻¹) supplied to wheat. Part of the wheat straw was returned to the soil before planting rice, which was cultivated for 132 days. To explore the key mechanisms by which S application controlled Cd accumulation in brown rice, (1) soil pore water at the key growth stages was sampled, and dissolved Cd and S species concentrations were determined; (2) rice plant tissues (including iron plaque on the root surface) were sampled at maturity for Cd and S analysis. With increasing S level, Cd accumulation in brown rice peaked at 60 mg S kg⁻¹, irrespective of soil Cd levels. For high-Cd soils, concentrations of Cd in brown rice increased by 57%, 228%, and 100% at 30, 60, and 120 mg S kg⁻¹, respectively, compared with no S treatment. The increase in brown rice Cd by low S levels (0–60 mg kg⁻¹) could be attributed to (1) the S-induced increase in soil pore water sulfate increasing the Cd influx into rice roots and (2) the S-induced increase in leaf S promoting Cd translocation into brown rice. However, brown rice Cd decreased at 120 mg S kg⁻¹ due to (1) low Cd solubility at 120 mg S kg⁻¹ and (2) root and leaf S uptake, which inhibited Cd uptake. Sulfur application to wheat crop increased the risk of Cd accumulation in brown rice. Thus, applying S-containing fertilizers to Cd-contaminated paddy soils is not recommended.

We investigated the fates of seven neonicotinoids (NNIs) in full-scale drinking water treatment plants and assessed human exposure to NNIs through consuming drinking water. The total NNI concentrations in raw water and treated water samples from the drinking water treatment plants were 20.4–166 ng/L (median 118 ng/L) and 1.11–94.7 ng/L (median 20.4 ng/L), respectively. The dinotefuran (DIN) concentrations in raw water collected in different seasons were different, and the highest DIN concentration was found in summer. The drinking water treatment processes removed >91% of the NNIs except DIN and thiamethoxam (THIAM), for which the mean removal rates were 70% and 74%, respectively. The removal rates for all of the NNIs were higher for the granular activated carbon filtration process (mean 83.5%) than the other drinking water treatment plant processes (coagulation/sedimentation 22.3%, ozonation 29.2%). However, the removal rates in the granular activated carbon process were lower for DIN and THIAM (61.0% and 59.2%, respectively) than the other NNIs. Significant correlations were found between the NNI removal rates and physicochemical properties (solubility in water and log (octanol–water partition coefficient)). The estimated mean human exposure to NNIs in drinking water was 0.528 ng/(kg body weight d).

Wetlands can improve water quality, but they are also recognized as important sources of greenhouse gases (GHG) such as nitrous oxide (N₂O) and methane (CH₄). Emissions of these gases from wetland ecosystems, especially those in headwaters, are poorly understood. Here, we determined monthly concentrations of dissolved N₂O and CH₄ in a headwater stream of the Taihu Lake basin of China that contains both wetland and non-wetland reaches. Daily GHG dynamics in the wetland reach were also investigated. Riverine N₂O and CH₄ concentrations generally varied within 10–30 nmol L⁻¹ and 0.1–1.5 μmol L⁻¹, respectively. CH₄ saturation levels in the wetland reach were about seven times higher than those in the non-wetland reach, but there was no difference in N₂O saturation. In the wetland reach, saturation levels of CH₄ peaked in July, coincident with a dip in N₂O saturation to levels below its saturated solubility. This underscores that hotspots of CH₄ production and sinks for N₂O can occur occasionally in wetlands in mid-summer, when vegetative growth and microbial activities are high. Diurnal measurements indicated that CH₄ saturation in water flows passing through the wetlands from midnight through the early morning can surge to levels 10 times higher than those detected at other times of the day. Simultaneously, saturation levels of N₂O decreased by 75%, indicating a net consumption of N₂O. Changes in nutrient supply determined by upstream inflows, as well as dissolved oxygen, pH, and other environmental factors mediated by the wetlands, correlate with the differentiated behavior of N₂O and CH₄ production in wetlands. Additional work will be necessary to confirm the roles of these factors in regulating GHG emissions in riverine wetlands.

Hooghly River (HR), the other name used for the lower stretch of River Ganga, is a prime freshwater source in the eastern part of India. However HR has been evidenced with a variety of emerging organic pollutants (EOPs) in the recent past. Given the extensive use of plasticizers and additive in plastic products, we have investigated seven plasticizers and bisphenol A (BPA) in the surface and storm-water of HR up to the tip of the Bay of Bengal. Further using a previously published sediment data we have estimated the fluxes for the aforementioned EOPs. Surface water and storm-water concentrations of seven plasticizers varied between 92.62 and 770 ng/L (176.1 ± 104.8; Avg ± SD) and 120.9–781.5 ng/L (355.2 ± 232.5), respectively. BPA varied between 43 and 8800 ng/L (658.3 ng/L ± 1760) and 117.9–2147 ng/L (459.3 ± 620.2) in surface and storm-water, respectively. With the increase in salinity, a decreasing trend for bis-(2-ethylhexyl) phthalate (DEHP) was evidenced. However, concentration of BPA increased with the increase in salinity. Significant and strong correlation between DEHP and BPA (R² = 0.6; p < 0.01) in the suburban corridor might have resulted from sludge disposal of the scrap recycling activities. Using site-specific principal component analysis, unregulated disposal of plastic waste, particularly from such industrial belts and tourist spots were identified as the possible point sources for plasticizers and BPA in this region. Net diffusive flux based on fugacity fraction showed a trend depending on the pollutant’s aqueous solubility and partition coefficient. However, transfer tendency from water to sediment was noticed in the sites having point source. Estimated ecotoxicological risk posed by BPA was higher for edible fishes and for lower order organisms, PAEs was the major contributor.

Liming is a safe and effective remediation practice for Cd contaminated acid paddy soil. The fate of Cd can also be strongly influenced by redox chemistry of sulfur. But it is unclear if, to what extent and how the combination of liming and sulfur mediation could further control Cd uptake by paddy rice. A rice cultivation pot experiment was conducted to evaluate the impact of different sulfur forms (S⁰ and SO₄²⁻ in K₂SO₄) on the solubility, uptake and accumulation of Cd in the soil-paddy rice system and how liming and reducing organic carbon mediate the process. Results showed that under neutral soil circumstances achieved by liming, co-application of K₂SO₄ and glucose significantly reduced brown rice Cd by 33%, compared to liming alone. They made it more readily for Cd²⁺ to be precipitated into CdS/CdS₂ or co-precipitate with newly formed FeS/FeS₂/iron oxides. The higher pH balancing capability of K₂SO₄ as well as liming kept the newly formed sulfide or iron containing minerals negatively charged to be more prone to adsorb Cd²⁺, that kept the porewater Cd²⁺ the lowest among all the treatments. Individual K₂SO₄ showed significant promoting effect on soil Cd solubility due to SO₄²⁻ chelation effect. Furthermore, K₂SO₄ had much weaker inhibiting effect on Cd translocation from root to grain, it showed no significant attenuating effect on brown rice Cd. S⁰ containing treatments displayed weaker or no attenuating effect on brown rice Cd due to its strong soil acidification effect. On the basis of liming, organic carbon induced sulfur (K₂SO₄) mediation showed great application potential for safe production on large areas of acid paddy soil contaminated by Cd.

Pyrogenic char (biochar) with a high sorption capacity (B-HSC) can sequester hazardous chemicals (e.g., phenanthrene). However, when sorption inhibits bioavailability of some functional chemicals (e.g., the herbicidal efficacy of diuron in soil), biochar with a low sorption capacity (B-LSC) is required to prevent sorption effects. The pyrolytic B-HSC generation has been reported, but information on B-LSC formation is scarce. How fast B-HSC and B-LSC could be generated is unknown until now. Here, biochars were rapidly prepared (the shortest heating time reached 5 min and the cooling time reached < 30 min) by a direct-pyrolysis method by directly exposing packaged rice straw and pine wood to 350 °C, 500 °C and 700 °C and out-of-furnace cooling at room temperature. The sorption of diuron, phenanthrene, and twelve other chemicals was investigated. B–HSCs were obtained within 30 min of rice straw pyrolysis, and the biochar Kd values quickly increased to 7-730-fold that of the raw biomass as –OH and C–O–C in (hemi)cellulose of rice straw rapidly degraded, increasing hydrophobic interactions between the char and chemicals (solubility ≤ 82.8 g/L). In contrast, B-LSCs were generated within 30 min of PW pyrolysis, and the Kd values of the biochars were 0.2–3.0-fold that of the raw biomass, as the surface area development and hydrophobicity-driven sorption were probably delayed by the late degradation of lignin aromatic C–O and phenolic –OH. Biochar amendment revealed an enhancement effect of B-HSC but not of B-LSC on soil sorption. The fast formation of B-LSC and B-HSC provides a guide to develop time- and cost-effective technique in pyrolytically producing weakly or strongly sorbing biochars for organic chemical management.

Ocean acidification (OA) could become a serious threat for the Antarctic marine ecosystem over coming years, as the solubility of atmospheric CO₂ and CaCO₃ minerals increases at lower temperatures. We evaluated the effect of OA on the stress response of the limpet Nacella concinna by measuring gene expression levels. The experiment was performed with the two ecotypes (Littoral and Sublittoral) of the species during 54 days (IPCC, 2019 scenario RCP8.5; control, ~375 ppm; low-pH treatment, ~923 ppm). Exposure to low-pH treatment during 15 days triggered the down-regulation of two heat-shock protein genes (HSP70A, HSP70B) only in sublittoral individuals. Little variation in the relative expression values of all genes in both ecotypes was observed probably, due to a historical exposure to the substantial daily natural pH fluctuations recorded in the study area during the experiment. This study provides relevant baseline data for future OA experiments on coastal species in Antarctica.

During 2015–2020, 26 cruises were carried out in a bay scallop farming area, North Yellow Sea, to study the dissolved oxygen (DO) dynamics and its controlling factors. Significant DO depletion (deoxygenation) was observed in the summertime with the decrease rates of 0.31–0.55 and 0.96–2.10 μmol d⁻¹ in the surface and bottom waters, respectively, which were comprehensively forced by temperature, photosynthesis and microbial respiration. Seasonally, temperature was the main driver of the deoxygenation processes. In the surface water, DO dynamics were dominated by temperature-induced solubility changes, while the photosynthesis offset the effects of physical processes to a certain extent; in the bottom water, its dynamics were mainly attributed to the comprehensive control of temperature-induced solubility changes and biological respiration. Overall, the results suggested that the occurrence of hypoxia and acidification in the coastal waters were highly associated with the formation of temperature-induced stratification under complex hydrodynamic processes.

This study obtained the first dataset on the solubilities and partitioning of metals and metalloids (MMs), including Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cs, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Rb, Sb, Sc, Se, Sn, Sr, Th, Ti, Tl, U, V, W, Y, Zn, and Zr, during spring rains in Moscow. MM concentrations were determined using inductively coupled plasma mass spectrometry and atomic emission spectroscopy. The metals Ti, Zr, Al, Sn, Fe, W, Th, Li, V, Cs, Bi, and Y were predominant in the insoluble fraction of the rainwater, whilst Sb, Zn, Ca, Cd were prevalent in the soluble fraction. The end of the winter heating season, together with a weaker dilution effect due to lower precipitation in April, caused higher soluble and insoluble MM concentrations in rainwater than those in May. MM solubilities increased with decreasing pH and longer periods of precipitation, and declined with an increase in precipitation intensity, the length of the antecedent dry period, and the content of solid particles in the rainwater. A 20%–50% increase in solubility in acid rains compared to non-acid rains was observed for Y, Pb, U, Be, Na, Ni, Th, Cu, W, Fe, Mg, Cr, Tl, and Ba. Anthropogenic sources contributed significantly to the concentration of soluble MMs (>90% for Sb, Pb, Se, Cd, Zn, Cu, Bi, Ca, Mo, Sc, Ba, As, W, Sr, Mn, Sn, Co, Tl, Ni, and Be). For the insoluble MM, crustal materials were the important contributors. During public holidays in Russia in the first decade of May, an increase in the proportion of insoluble MMs was observed.

Environmental pollution has brought adverse socio-economic consequences. Organic pollutants and heavy metals are the main culprits of environmental pollution. It is of great importance to develop novel, simple, rapid, sensitive, and low-cost detection approaches for sensing trace pollutants in environmental samples. A lot of detection strategies which are based on varieties of nanomaterials have been developed for environmental analysis in past decades. In this review, we retrospect a variety of nanomaterials decorated with cyclodextrins (CDs), including carbon nanomaterials decorated with CDs, noble metal nanomaterials decorated with CDs and other nanomaterials decorated with CDs, and their application in environmental analysis. CDs is a type of ideal modifying molecules which could recognize targets, improve the solubility and dispersibility of corresponding functionalized materials, and enhance the detecting performance of designed sensors. CDs have been widely immobilized to carbon nanomaterials, noble metal nanomaterials, phosphorene (BP) nanocomposites, metal organic framework (MOF), and magnetic nanomaterials, and these nanocomposites have been utilized as the sensing elements for different target analytes. Immobilizing CDs on different nanomaterials could extremely expand the development of new sensing systems for environmental analysis based on these materials, greatly broaden the species of sensing targets, and apparently improve their sensing performance. Herein, the nanomaterials decorated with CDs, as sensing elements for environmental analysis, were reviewed including the types of nanomaterials decorated with CDs and their applications in various sensing strategies for environmental analysis. Finally, the perspectives of the nanomaterials decorated with CDs used as sensing elements were also discussed.