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Assessment of Spatial and Temporal Variations in Water Quality Dynamics of River Ganga in Varanasi
2018
Singh, Abaidya Nath | Shrivastava, Reshu | Mohan, Devendra | Kumar, Pankaj
River Ganga is one of the prime sacred National Rivers of India, closely associated with economic, social, and cultural heritage of Indian people. Recently, it has been subjected to immense degradation and pollution as a result of receiving huge amounts of domestic and industrial wastewater as well as religious ritual activities and surface runoff. The present study attempts to study spatial and temporal changes in water quality of River Ganga while calculating its Water Quality Index (WQI) by analyzing 9 physico-chemical, 7 trace metal, and 4 microbiological parameters at eleven sampling stations, on the basis of River Ganga index of Ved Prakash. Thus it can assess water’s suitability for drinking and irrigation purposes along with other human uses. The study is directed towards the use of WQI to describe pollution level in the river for a period of 1 year (from January to December 2014). It has been shown that index values as per CPCB class range between medium to good, while the ones as per NSF Index range from bad to good water quality. The study also identifies critical pollutants, affecting the river water quality within its course through the city. Finally, pH, DO, BOD, DO, EC, and FC have been found to be critical parameters for the stretch in each season of this research.
Show more [+] Less [-]Characteristics and Health Risk of BTEX at Selected Different Microenvironments in an Industrial-Urban Area, Iran
2019
Tarassoli, A. | Esmaili Sari, A. | Bahramifar, N.
The present study monitors BTEX concentration in outdoor and indoor air of eight different microenvironments during summer 2017 and winter 2018 at Asaloyeh city, Iran's energy capital. It samples BTEX compounds by charcoal tubes, analyzing the samples by means of a gas chromatograph with a flame ionization detector. According to the obtained results, outdoor concentrations of BTEX have been higher than the indoor ones, for both seasons, with the highest outdoor and indoor BTEX being 21.70 and 18.59 μg/m3, respectively. Toluene has been the most abundant substance, among the investigated BTEX in all sampling points. Based on the MIR scale, m, p-xylene is the most dominant contributor to ozone formation potential among BTEX species. Indoor to outdoor (I/O) ratios of BTEX compounds range from 0.53 to 0.88 and 0.41 to 0.77 in winter and summer, respectively. The cumulative hazard index (HI) is within an acceptable range. The LTCR value of benzene concentration, obtained, exceeds the value of 1.0E-06, recommended by USEPA. Sensitivity analysis shows that benzene concentration, exposure duration, and inhalation rate have a greater impact on health risk assessment.
Show more [+] Less [-]Assessment of Pb and Ni contamination in the topsoil of ring roads' green spaces in the city of Hamadan
2018
Sobhan Ardakani, Soheil
Due to rapid industrialization and urbanization, environmental pollution has become a major concern in developing countries; therefore, the main objective of the current study is to determine heavy metal contents of Pb, and Ni for 42 topsoil samples, collected from 14 green spaces along the 1st and 2nd ring roads in Hamedan City in 2016. For this purpose, after determining some chemical properties as well as acid digestion of soil samples, Pb and Ni concentrations have been found in the soil samples with ICP-OES. All statistical analyses have been conducted, using SPSS 18.0 statistical package, with the results showing that the metal levels in soil samples, collected from green space of 1st and 2nd ring road, have been 34.86±10.28 and 41.57±10.08 mg/kg for Pb and 14.0-20.33 and 14.0-20.0 mg/kgfor Ni, respectively. Also the mean concentration of Pb and Ni have been lower than MPL. According to heavy metal concentration maps, the spatial distribution patterns of Pb, and Ni contents in the soil samples are generally similar along the 1st and 2nd ring road. Due to the fact that traffic volume in the 2nd ring was higher than the 1st one, there has been a significant difference in the mean contents of Pb between the topsoil samples, collected from the 1st and 2nd ring roads; therefore, it is recommended to keep environmental health in order to control the anthropogenic sources, causing the pollutants discharge into the environment is recommended.
Show more [+] Less [-]Spatial distribution of microplastics in Chinese freshwater ecosystem and impacts on food webs
2022
Over the past two decades, there has been a lot of discussion about the rapid increase of microplastics (MPs) due to their persistence, ubiquity, and toxicity. The widespread distribution of MPs in various freshwater ecosystems makes them available for different trophic levels biota. The ingestion and trophic transfer of MPs may induce potential impacts on freshwater food webs. Therefore, this systematic review is an in-depth review of 51 recent studies to confirm the spatial distribution of MPs in the Chinese freshwater ecosystem including water, sediment and biota, exposure pathways, and impacts on freshwater food webs. The result suggested the white, transparent and colored, Polypropylene (PP) and Polyethylene (PE) of <1 mm fibers were dominant in Chinese freshwaters. The uptake of MPs by various freshwater organisms as well as physiological, biological and chemical impacts on food webs were also elucidated. At last, some limitations were discussed for future studies to better understand the effects of MPs on food webs.
Show more [+] Less [-]Heterologous spatial distribution of soil polycyclic aromatic hydrocarbons and the primary influencing factors in three industrial parks
2022
Ren, Helong | Su, Peixin | Kang, Wei | Ge, Xiang | Ma, Shengtao | Shen, Guofeng | Chen, Qiang | Yu, Yingxin | An, Taicheng
Soil polycyclic aromatic hydrocarbons (PAHs) generated from industrial processes are highly spatially heterologous, with limited quantitative studies on their main influencing factors. The present study evaluated the soil PAHs in three types of industrial parks (a petrochemical industrial park, a brominated flame retardant manufacturing park, and an e-waste dismantling park) and their surroundings. The total concentrations of 16 PAHs in the parks were 340–2.43 × 10³, 26.2–2.63 × 10³, and 394–2.01 × 10⁴ ng/g, which were significantly higher than those in the surrounding areas by 1–2 orders of magnitude, respectively. The highest soil PAH contamination was observed in the e-waste dismantling park. Nap can be considered as characteristic pollutant in the petrochemical industrial park, while Phe in the flame retardant manufacturing park and e-waste dismantling park. Low molecular weight PAHs (2–3 rings) predominated in the petrochemical industrial park (73.0%) and the surrounding area of brominated flame retardant manufacturing park (80.3%). However, high molecular weight PAHs (4–6 rings) were enriched in the other sampling sites, indicating distinct sources and determinants of soil PAHs. Source apportionment results suggested that PAHs in the parks were mainly derived from the leakage of petroleum products in the petroleum manufacturing process and pyrolysis or combustion of fossil fuels. Contrarily, the PAHs in the surrounding areas could have been derived from the historical coal combustion and traffic emissions. Source emissions, wind direction, and local topography influenced the PAH spatial distributions.
Show more [+] Less [-]Spatial distribution, homologue patterns and ecological risks of chlorinated paraffins in mangrove sediments along the South China Coast
2022
Chen, Hui | Han, Xu | Liang, Bowen | Deng, Man | Du, Bibai | Zeng, Lixi
The spatial distribution, homologue patterns, and ecological risks of chlorinated paraffins (CPs) were investigated in sediments from sixteen mangrove wetlands along the South China Coast (SCS). The total concentrations of CPs in mangrove sediments from Guangdong, Fujian, Guangxi, and Hainan were in the range of 933–4760, 619–2300, 375–1550, and 271–658 ng/g dry weight, respectively. The contamination levels and spatial distribution of short-chain and medium-chain CPs (SCCPs and MCCPs, respectively) in mangrove sediments were mainly affected by local population scale and CP industries. The dominant CP patterns in sediments were C₁₀–₁₁Cl₆₋₈ and C₁₄Cl₇₋₉ for SCCPs and MCCPs, respectively. Redundancy analysis, based on CP levels and several potential influencing factors showed that MCCPs/SCCPs ratio was the main factor affecting the accumulation of CPs in mangrove sediments. Additionally, MCCP concentrations were significantly correlated with total organic carbon (TOC), indicating that TOC might affect MCCP accumulation in mangrove sediments. Risk assessments indicated that CPs would pose medium ecological risks to sediment dwelling organisms in nearly one-third of the sampling sites. This is the first comprehensive report of the sedimentary SCCPs and MCCPs in mangrove wetlands along the SCS and highlights the need for more sediment toxicity data for CPs.
Show more [+] Less [-]Source apportionment of potentially toxic elements in soils of the Yellow River Delta Nature Reserve, China: The application of three receptor models and geostatistical independent simulation
2021
Zhang, Mengna | Lv, Jianshu
The Yellow River Delta (YRD) wetland, the most important estuary wetland in eastern China, has an important ecosystem service function. Rapid and intensive development has inevitably led to the accumulation of potentially toxic elements (PTEs) in soils. Therefore, identifying quantitative sources and spatial distributions of PTEs is essential for soil environmental protection in the YRD. A total of 240 topsoil samples (0–20 cm) were collected in the Yellow River Delta Nature Reserve (YRDNR) and analyzed the PTE contents. To avoid the biases of the single receptor model, positive matrix factorization, factor analysis with nonnegative constraints, and maximum likelihood principal component analysis-multivariate curve resolution-alternating least squares were used for source apportionment of soil PTEs. To promote the efficiency of multivariate geostatistical simulation, a minimum/maximum autocorrelation factor-sequential Gaussian simulation was built to map the spatial patterns of PTEs. Three factors were derived by the three receptor models, and their contributions to the source explanation were similar. As, Cr, Cu, Mn, Ni, and Zn originated from natural sources, with contributions of 85.6%–96.4 %. A total of 61.5 % of Hg was associated with atmospheric deposition of coal combustion and wastewater from upstream. Agricultural activities and oil exploitation contributed 33.5 % and 15.9 % of the Cd and Pb concentrations. Spatial distributions of soil PTEs were controlled by sedimentary grain size. A total of 47.2 % of the total study area was identified as hazardous area for Cd, 10.3 % for As, and 5.4 % for Hg. This work is expected to provide references for soil pollution assessment and management of YRDNR.
Show more [+] Less [-]Vertical profile of aerosols in the Himalayas revealed by lidar: New insights into their seasonal/diurnal patterns, sources, and transport
2021
Xiang, Yan | Zhang, Tianshu | Liu, Jianguo | Wan, Xin | Loewen, Mark | Chen, Xintong | Kang, Shichang | Fu, Yibin | Lv, Lihui | Liu, Wenqing | Cong, Zhiyuan
Atmospheric aerosols play a crucial role in climate change, especially in the Himalayas and Tibetan Plateau. Here, we present the seasonal and diurnal characteristics of aerosol vertical profiles measured using a Mie lidar, along with surface black carbon (BC) measurements, at Mt. Qomolangma (QOMS), in the central Himalayas, in 2018–2019. Lidar-retrieved profiles of aerosols showed a distinct seasonal pattern of aerosol loading (aerosol extinction coefficient, AEC), with a maximum in the pre-monsoon (19.8 ± 22.7 Mm⁻¹ of AEC) and minimum in the summer monsoon (7.0 ± 11.2 Mm⁻¹ of AEC) seasons. The diurnal variation characteristics of AEC and BC were quite different in the non-monsoon seasons with enriched aerosols being maintained from 00:00 to 10:00 in the pre-monsoon season. The major aerosol types at QOMS were identified as background, pollution, and dust aerosols, especially during the pre-monsoon season. The occurrence of pollution events influenced the vertical distribution, seasonal/diurnal patterns, and types of aerosols. Source contribution of BC based on the weather research and forecasting chemical model showed that approximately 64.2% ± 17.0% of BC at the QOMS originated from India and Nepal in South Asia during the non-monsoon seasons, whereas approximately 47.7% was from local emission sources in monsoon season. In particular, the high abundance of BC at the QOMS in the pre-monsoon season was attributed to biomass burning, whereas anthropogenic emissions were the likely sources during the other seasons. The maximum aerosol concentration appeared in the near-surface layer (approximately 4.3 km ASL), and high concentrations of transported aerosols were mainly found at 4.98, 4.58, 4.74, and 4.88 km ASL in the pre-monsoon, monsoon, post-monsoon, and winter seasons, respectively. The investigation of the vertical profiles of aerosols at the QOMS can help verify the representation of aerosols in the air quality model and satellite products and regulate the anthropogenic disturbance over the Tibetan Plateau.
Show more [+] Less [-]Occurrence and spatial distribution of legacy and novel brominated flame retardants in seawater and sediment of the South China sea
2021
Feng, Hongru | Cheng, Yixue | Ruan, Yuefei | Tsui, Mirabelle M.P. | Wang, Qi | Jin, Jing | Wu, Rongben | Zhang, Haiyan | Lam, Paul K.S.
The occurrence and spatial distribution of polybrominated diphenyl ethers (PBDEs) and novel brominated flame retardants (NBFRs) in seawater and surficial sediment samples (N = 19 and 45, respectively) from the South China Sea (SCS) in 2018 were investigated, and the correlation between BFRs and site parameters (total organic carbon, depth, etc.) were assessed by principal component analysis. The concentration ranges of ΣPBDEs in seawater and sediments were 0.90–4.40 ng/L and 0.52–22.67 ng/g dry weight (dw), respectively, while those of ΣNBFRs were 0.49–37.42 ng/L and 0.78–82.29 ng/g dw, respectively. BDE-209 and decabromodiphenyl ethane were the predominant BFRs, accounting for 38.65% and 36.94% in seawater and 26.71% and 68.42% in sediments, respectively. Notably, tris(2,3-dibromopropyl)isocyanurate and 2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine, seldomly detected in aquatic matrices worldwide, were detected for the first time in the study area, and their relatively high levels and detection frequencies indicate the ubiquitous application of these NBFRs in the Pearl River Delta. Zhuhai and Jiangmen are the main sources of NBFRs in the SCS. Preliminary risk assessment on NBFRs using hazard quotient indicates low to medium risks to marine organisms at some sites. The occurrence of NBFRs in the SCS highlights the prioritization of more toxicological information on these compounds.
Show more [+] Less [-]Influence of a weak typhoon on the vertical distribution of air pollution in Hong Kong: A perspective from a Doppler LiDAR network
2021
Huang, Tao | Yang, Yuanjian | O’Connor, Ewan James | Lolli, Simone | Haywood, Jim | Osborne, M. (Martin) | Cheng, Jack Chin-Ho | Guo, Jianping | Yim, Steve Hung-Lam
High particulate matter (PM) and ozone (O₃) concentration in Hong Kong are frequently observed during the summertime typhoon season. Despite the critical effect of a typhoon on air pollution, contributions of vertical wind profile and cloud movement during transboundary air pollution (TAP) on surface PM and O₃ concentration have yet to be fully understood. This work is the first study to apply a network of Doppler light detection and ranging (LiDAR) as well as back trajectory analysis to comprehensively analyze the effect of a weak Typhoon (Danas) occurring during 16–19 July 2019 on different variations in PM and O₃ concentration. During the typhoon Danas, three types of surface air pollution with five episodes were identified: (1) low PM and high O₃ concentration; (2) co-occurring high PM and O₃ concentration and (3) high PM and low O₃ concentration. Employing our 3D Real-Time Atmospheric Monitoring System (3DREAMs) along with surface observations, we found the important role of TAP in the increases in surface PM and O₃ concentration with significant vertical wind shear that transported air pollutants at upper levels, and strong vertical mixing that brought air pollutants to the ground level. Cloud movement related to typhoon periphery, as well as high solar radiation due to sinking motion and remote transport by continental wind, have an impact on local O₃ concentration. For the substantial difference in O₃ concentration between two air quality measurement sites, the similar vertical aerosol distributions and wind profiles suggest the comparable TAP contributions at the two sites and thus infer the critical role of local O₃ photochemical process in the O₃ difference. This work comprehensively reveals the influences of a weak typhoon on variations in PM and O₃ during the five episodes, providing important references for air quality monitoring and forecast in regions under the influence of typhoon.
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