To reduce the losses caused by the atmospheric corrosion of carbon steels, it is important to establish a prediction model to determine the corrosion rate of carbon steels in natural environments. In this study, a prediction model of atmospheric corrosion of Q235 carbon steel (PMACC-Q235) in China was established by coupling the mean impact value algorithm and back propagation artificial neural network. Tempo-spatial patterns of corrosion rates in five long-exposure time categories across China were analyzed. Ten main factors affecting the atmospheric corrosion of Q235 were identified. The corrosion rates in a single year were similar (approximately 30 μm/a) and larger than those for 2 (25.30 μm/a) and 3 years (21.66 μm/a). The spatial corrosion rates in the northwestern areas were primarily lower than those in southeastern coastal areas. This could be influenced by climatic factors, such as temperature, humidity, and precipitation. All corrosion rates reached the C2 level (>1.3 μm/a), and there was some possibility that they reached higher corrosion levels. The largest probability for the C3 level in all periods was an average of 0.91, and that for the C4 level was 0.83. Spatially, higher probabilities were mainly located in the southern area, especially in Hainan, located in the south and surrounded by sea. Corrosion rates largely varied among climatic zones, and mean corrosion rates in the tropical monsoon climate zone were the largest (average of three periods 33.39 μm/a). SO₂ and soluble-dust fall had the largest impact on the variations in the corrosion rates among different climatic zones.

The outbreak of novel coronavirus (COVID-19) has become a global concern that is deteriorating environmental quality and damaging human health. Though some researchers have investigated the linkage between temperature and COVID-19 transmissibility across different geographical locations and over time, yet these studies are scarce. This study aims to bridge this gap using daily temperature and COVID-19 cases (transmissibility) by employing grey incidence analysis (GIA) models (i.e., Deng’s grey incidence analysis (DGIA), the absolute degree GIA (ADGIA), the second synthetic degree GIA (SSDGIA), the conservative (maximin) model) and correlation analysis. Data on temperature are accessed from the NASA database, while the data on COVID-19 cases are collected from the official website of the government of Pakistan. Empirical results reveal the existence of linkages between temperature and COVID-19 in all Pakistani provinces. These linkages vary from a relatively stronger to a relatively weaker linkage. Based on calculated weights, the strength of linkages is ranked across provinces as follows: Gilgit Baltistan (0.715301) > Baluchistan (0.675091) > Khyber Pakhtunkhwa (0.619893) > Punjab (0.619286) > Sindh (0.601736). The disparity in the strength of linkage among provinces is explained by the discrepancy in the intensity of temperature. Besides, the diagrammatic correlation analysis shows that temperature is inversely linked to COVID-19 cases (per million persons) over time, implying that low temperatures are associated with high COVID-19 transmissibility and vice versa. This study is among the first of its kind to consider the linkages between temperature and COVID-19 transmissibility for a tropical climate country (Pakistan) using the advanced GIA models. Research findings provide an up-to-date glimpse of the outbreak and emphasize the need to raise public awareness about the devastating impacts of the COVID-19. The educational syllabus should provide information on the causes, signs, and precautions of the pandemic. Additionally, individuals should practice handwashing, social distancing, personal hygiene, mask-wearing, and the use of hand sanitizers to ensure a secure and supportive atmosphere for preventing and controlling the current pandemic.

This work investigated the impact of a clay mineral on toxic waste. The Ivorian Anti-pollution Center discovered the toxic waste from Probo Koala boat on 21 August 2006. This boat had been used to refine oil named naphtha of cokéfaction by Trafigura firm in the sea. The process of refining consists of caustic sodium carbonate washing and produced toxic waste. These toxic wastes have been unloading in 13 zones of the Abidjan district: Akouédo, Abobo, Abobo Alépé road (Djibi village), civile prison road (MACA), industrial zone of Koumassi, Port-Bouët - Vridi CAP Logistic (Rue Saint-Sylvestre)… This situation caused a socio-political crisis and generated the death of many people. To solve this problem, one first part has been excavated and sent to France to be incinerated. A second part is used to be a biopile for bioremediation. After these two processes, the rest of toxic waste remained in the place where they have been unloaded. The analyses of these toxic wastes show that polycyclic aromatic hydrocarbons (PAHs), oxygenated polycyclic aromatic compounds (O-PACs), volatile aromatic compound (VAC), mercaptan and sulfur molecules, and also heavy metal and organometallic are the principal polluters of these contaminated soils. From a mineralogical viewpoint, the tropical climate soils of Ivory Coast in general and district of Abidjan in particular constituted of about 50% of kaolinite, 30 to 40% of smectite, and 10 to 20% of illite (OSTROM 1993). In this study, we want to show the impact of this local clay on toxic waste.

The safe recycling of organic wastes such as the nutrients obtained from agriculture activities is a relevant aspect of the “One Health” strategy, a worldwide initiative including all aspects of health care for humans and animals, as well as aspects related to the conservation and development of the environment. It represents an important opportunity to mitigate the potential impact of microbial pathogens likely present in nutrient natural sources, as digestate, when applied to land as fertilizers. The objectives of the current study were to determine the inactivation of enteric microorganisms in swine digestate (effluent and sludge) during storage in anaerobic conditions and at different ambient temperatures of tropical zones (16, 22, and 37 °C). Human adenovirus 2 (HAdV-2), bacteriophage PhiX-174, and Salmonella enterica serovar typhimurium (S. typhimurium) were used as enteric microbial models to determine the minimum storage time required to reduce at least 3log of enteric microorganisms load in both matrices at the mentioned temperatures. The minimum storage time required for S. typhimurium was shorter than those observed for viruses at 37 °C, while reduction of at least 3log for S. typhimurium was observed after just 1 day; 20 and 90 days were needed for similar reductions for HAdV-2 and PhiX-174, respectively. Similar results were also observed at lower temperatures: 30 and 45 days were needed for S. typhimurium at 22 and 16 °C, respectively, but 30 and 90 days were needed at 22 °C for HAdV-2 PhiX-174, respectively, or 90 and 120 days at 16 °C for HAdV-2 PhiX-174, respectively. This is a pioneering study on the evaluation of inactivation of enteric viruses in swine digestate in usual tropical ambient temperatures; it demonstrates that the time for a considerable inactivation is longer than that observed for a enteric microorganisms (S. typhimurium), and shows that the storage of swine digestate at the referred temperatures can be used as a low-cost post-treatment to inactivate enteric microorganisms, allowing a further use as safer fertilizer.

Evaluation of a field scale agricultural nonpoint source simulation model against field experiment data is an important step that must be considered before a model can be used as a management tool. Field soil water content and metribuzin residue adsorbed in soil profile were intensively monitored and measured by the gravimetric method and the LC-MS/MS method, respectively, for a soybean field plot located at the Asian Institute of Technology, Thailand. The Root Zone Water Quality Model (RZWQM) was evaluated based on laboratory-measured soil hydraulic properties and pesticide residue in Bangkok clay soil. Reasonable agreement exists between the soil water content measured and predicted by RZWQM for 10–20 and 30–40 cm soil depths. The model slightly overestimated the pesticide residue at 0–10 cm soil depth 1 day after application at surface, whereas pesticide residue at 10–20 and 30–40 cm soil depths was in agreement with model acceptance. These results indicate that RZWQM can be used when properly calibrated to predict the movement of water and metribuzin through the soil profile in the tropical zone.

The Tubarão River rises in Santa Catarina, Brazil, and has been historically affected by coal mining activities around its springhead. To evaluate its water conditions, an investigation regarding a possible decontamination gradient associated with the increased river flow toward the estuary, as well as the influence of seasonality over this gradient was performed through a series of biomarkers (vitellogenin, comet assay, lipid peroxidation, protein carbonylation, gluthatione, gluthatione S-transferase, acetylcholinesterase, light microscopy in liver, and scanning electron microscopy in gills) and chemical analysis (polycyclic aromatic hydrocarbons (PAHs) in bile and metal analysis in sediment) in the cichlid Geophagus brasiliensis. Two collections (summer and winter) were made in four distinct sites along the river, while sediments were sampled between those seasons. As expected, the contamination linked exclusively to mining activities was not observed, possibly due to punctual inputs of contaminants. The decontamination gradient was not observed, although seasonality seemed to have a critical role in the responses of biomarkers and availability of contaminants. In the summer, the fish presented higher histopathological damages and lower concentrations of PAHs, while in the winter they showed both higher genetic damage and accumulation of PAHs. The Tubarão suffers impacts from diverse activities, representing health risks for wild and human populations.

A comprehensive study was conducted to determine the soil to plant transfer factor (TFS-P) of K-40, Cs-137, Th-232 and U-238 in perennial plants from accessible areas of Mumbai, using high-resolution γ spectrometry. A total of 50 soil and 150 plants samples were collected from all over the Mumbai region where lithology is dominated by basaltic rocks. The mean concentration values for K-40, Cs-137, Th-232 and U-238 in soil was 170.06 ± 65.36, 5.19 ± 1.20, 25.72 ± 6.262 and 10.21 ± 2.82 Bq kg⁻¹ respectively, whereas in case of plants the mean concentration values were determined to be 181.82 ± 18.50, 0.44 ± 0.14, 0.84 ± 0.19 and 0.79 ± 0.22 Bq kg⁻¹ respectively. The mean activity ratio of Th-232/U-238 in plants is 1.06 while in soil the ratio is 2.5. The soil to plant transfer factor (TFS-P) calculated for K-40, Cs-137, U-238 and Th-232 are 1.05, 0.076, 0.071 and 0.031 respectively. Higher value of TFS-P for K-40, which is an integral part of stable potassium clearly indicates the physiological need of stable potassium, for maintaining the different biological mechanisms of perennial plants under tropical conditions.

Many national exposure programmes have been performed in tropical and subtropical climates during the last 50 years. However, ambitious programmes involving more than a few countries are scarce. In this paper a recently formed network of test sites is described involving 12 test sites in Asia (India, Vietnam, Thailand, Malaysia and China including Hong Kong) and four test sites in Africa (South Africa, Zambia and Zimbabwe). This effort is part of the 2001-2004 Swedish International Development Agency (SIDA) funded Programme on Regional Air Pollution in Developing Countries (RAPIDC). Corrosion attack after one (2002-2003) year of exposure (carbon steel, zinc, copper, limestone and paint coated steel) are presented together with environmental data (SO₂, NO₂, HNO₃, O₃, particles, amount and pH of precipitation, temperature and relative humidity) for all the test sites. The obtained corrosion values are substantially higher than expected for limestone, higher than expected for carbon steel and lower than expected for zinc compared to values calculated using the best available dose-response functions.

Anaerobic reactors have been spreading in places with tropical climate and in developing countries. Their association with aerobic reactors provides great removal of carbonaceous matter with lower energy consumption and sludge production, although it does not allow the reduction in the concentration of total nitrogen. An alternative that could provide nitrogen removal without the construction of new reactors would be the nitrified effluent recirculation to the anaerobic reactor, in which denitrification would take place. Therefore, in this study, we sought to perform the nitrified effluent recirculation to the packed bed reactor (PBR) and UASB and concluded the following: (a) due to the presence of filling material, PBR tended to present a better performance in denitrification and removal of organic matter and suspended solids than the UASB reactor; (b) when performing the nitrified effluent recirculation to anaerobic reactors, the COD/NO₃⁻-N ratio must not be less than 6; (c) the concentration of N₂O in the biogas of both reactors remained below the detection limit, minimizing the production of greenhouse gases; and (d) the limitation of organic matter promoted partial denitrification, creating conditions for the emergence of anammox bacteria in the sludge.

The Nevado de Toluca Natural Protected Area (Zona de Protección de Flora y Fauna Nevado de Toluca, ZPFFNT), Central Mexico, encompasses one of the four highest (> 4000 m a.s.l.) volcanoes in Mexico, Nevado de Toluca; an extended area of woodland surrounds this volcano. Although identified as a remote area based on its high altitude, the ZPFFNT is not far from the urban and industrial zones of Toluca (~20 km) and Mexico (~72 km) cities, which potentially threatens the environmental health of the ZPFFNT by emitting SO₂ and NOX. Acid precipitation falling on areas with low alkaline reserve leads to environmental acidification and land degradation. To provide reliable data on the air pollution reaching the ZPFFNT and the related potential risks, our study analyzed the bulk atmospheric deposition chemistry and its temporal dynamics throughout an annual cycle. There are two well-defined seasons: (a) cold/dry with SW–NE wind direction and (b) warm/rainy with NE–SW wind direction. The pH, electric conductivity (K₂₅), cations, Cl⁻, and HCO₃⁻ were statistically higher in the cold/dry period. Differently, NO₃⁻ and SO₄²⁻ showed steadier behavior. Bulk deposition pH remained acidic at all times but reached extreme low values from July to September during the warm/rainy season. In the cold/dry season, alkaline cations were important in partially neutralizing the acidic compounds from the urban and industrial zones of Toluca and Mexico cities. Previously assumed to be safe based on its remoteness, the ZPFFNT is threatened by acid precipitation, which demand the implementation of preventative and mitigating actions as part of a management plan to avoid environmental deterioration.