Modification of biochar by low-cost iron sources has gained increasing attention to improve pollutants removal performance and reduce production costs compared to conventional chemical modifications. While such iron sources generally have complex compositions, their effects on properties of the iron-biochar composite are not well investigated. This study produced an iron-biochar (RBC) composite from co-pyrolysis of incinerated sewage sludge ash (ISSA) and peanut shell, and examined the role of silica with widespread existence in ISSA and other low-cost iron sources on properties of the iron-biochar composite relevant to As(III)/As(V) removal. Silica was found to react with iron during the pyrolysis process at 850 °C and formed iron silicon at the expense of producing zero valent iron and Fe₃O₄ which resulted in a poorer removal efficacy for As(III) and As(V) compared to the iron-biochar (FBC) made from pure Fe₂O₃ and peanut shell. Moreover, a high leaching of reactive silica from RBC was observed which affected the formation of corrosion products of ZVI and competed with arsenic for active adsorption sites. Despite this, RBC still exhibited a maximum adsorption capacity of 17.44 and 57.56 mg/g towards As(III) and As(V) respectively at pH 3.0. Overall, this study provides an interesting insight into upcycling ISSA into useful media for sorptive removal of arsenic from aqueous solutions.

In recent years, pollution of antibiotics and heavy metal has often been reported in organic wastes. Saprophytic insects have been recorded as biological control agents in organic waste management. During organic waste conversion, the intestinal bacteria of the saprophytic insects play an important role in digestion, physiology, immunity and prevention of pathogen colonization. Black soldier fly (BSF) Hermetia illucens has been widely used as saprophytic insects and showed tolerance to sulfonamides (SAs) and cadmium (Cd). Diversity and changes in gut microbiota of black soldier fly larvae (BSFL) were evaluated through 16S rRNA high-throughput sequencing, and a decrease in diversity of gut microbiota along with an increase in SAs stress was recorded. Major members identified were Actinomycetaceae, Enterobacteriaceae, and Enterococcaceae. And fourteen multi-resistance Klebsiella pneumoniae strains were isolated. Two strains BSFL7-B-5 (from middle midgut of 7-day BSFL) and BSFL11-C-1 (from posterior midgut of 11-day BSFL) were found to be low-toxic and multi-resistance. The adsorption rate of SAs in 5 mg/kg solutions by these two strains reached 65.2% and 61.6%, respectively. Adsorption rate of Cd in 20 mg/L solutions was 77.2% for BSFL7-B-5. The strain BSFL11-C-1 showed higher than 70% adsorption rates of Cd in 20, 30 and 40 mg/L solutions. This study revealed that the presence of multi-resistance bacterial strains in the gut of BSFL helped the larvae against SAs or Cd stress. After determining how and where they are used, selected BSFL gut bacterial strains might be utilized in managing SAs or Cd contamination at suitable concentrations in the future.

While the increasing accumulation of anthropogenic litter in the marine environment has received considerable attention over the last decade, litter occurrence and distribution in rivers, the main source of marine litter, have been comparatively less investigated. Moreover, little information is available about the amount and typology of Riverine Anthropogenic Macro-litter (RAM) entering marine environments from intermittent rivers in low populated areas of the Mediterranean basin. To provide insights on this issue, we investigated density and composition of RAM accumulated over a total of 133 riverbanks, belonging to 37 river basins in the Sardinia Island (Mediterranean Sea). We report here that plastics, especially single-use items, represent the most frequent and abundant RAM category in all investigated basins. Statistical modelling revealed that occurrence of lightweight RAM (especially plastic) is mostly explained by levels of urban (12.3% of the relative contribution) and agricultural (12%) land use of the territory, whereas the proximity of bridges to the sampling point (21%) and the local population density (19.8%) are best predictors of heavy weighted RAM items (i.e., large metal items, appliances) occurrence. Our results confirm that plastics represent an important component of RAM and pinpoint that, beside plastic reduction policies and better waste management, actions aimed at abating and monitoring litter contamination should be localized on the proximity of bridges, whatever the local population density. Finally, to fill existing knowledge gaps in understanding the severity of litter discharge and accumulation in the Mediterranean Sea, land-to-sea systematic monitoring campaigns at appropriate spatial and temporal scales should be put in place.

This study aimed to evaluate the impact factors and effectiveness of management policies on the presence of polybrominated diphenyl ethers (PBDEs) in sediment samples in Taiwan from the last 10 years. Twenty-four PBDE congeners were detected in 838 sediment samples collected from 4 stages (2006–2019) in 30 principal rivers, based on the national project for background monitoring of the environmental distribution of chemical substances. The ΣPBDE concentrations in the 4 stages ranged from 30.00 to 147.10 ng/g dw, 6.03–15.30 ng/g dw, 4.99–7.00 ng/g dw, and 1.20–2.10 ng/g dw in the northern, southern, central, and eastern areas, respectively. The concentrations of PBDEs (e.g., penta-BDE and octa-BDE) in sediment samples notably decreased (−6 to −73%) as the Taiwan Environmental Protection Administration implemented policies banning PBDEs (except deca-BDE). The PBDEs levels of the sediment samples collected in the dry season were higher than those collected in the wet season. The levels of ΣPBDEs in sediment samples were affected by season, the amount of general waste present, and nearby PBDE-related factories and e-waste recycling facilities. Reducing the release of PBDEs, especially deca-BDE, through sound waste management and recycling practices is still needed to improve environmental sustainability in Taiwan.

Soil contamination is perhaps the most hazardous issue all over the world; these emerging pollutants ought to be treated to confirm the safety of our living environment. Fast industrialization and anthropogenic exercises have resulted in different ecological contamination and caused serious dangerous health effects to humans and animals. Agro wastes are exceptionally directed because of their high biodegradability. Effluents from the agro-industry are a possibly high environmental risk that requires suitable, low-cost, and extensive treatment. Soil treatment using a bioremediation method is considered an eco-accommodating and reasonable strategy for removing toxic pollutants from agricultural fields. The present review was led to survey bioremediation treatability of agro soil by microbes, decide functional consequences for microbial performance and assess potential systems to diminish over potentials. The presence of hazardous pollutants in agricultural soil and sources, and toxic health effects on humans has been addressed in this review. The present review emphasizes an outline of bioremediation for the effective removal of toxic contaminants in the agro field. In addition, factors influencing recent advancements in the bioremediation process have been discussed. The review further highlights the roles and mechanisms of micro-organisms in the bioremediation of agricultural fields.

The rapid growth of plastic wastes exceeds efforts to eliminate plastic pollution owing to the outbreak of COVID-19 in 2020 and then aggravates inherent environmental threats to the ecosystem. The paper provided a short introduction relating to the hazards of plastic wastes on environment and a detailed statement about plastic toxicity on human. The article stated on plastic how to enter the body and cause harm for us step by step. Given the toxicity and harm of plastic wastes on human, the degradation of plastic wastes via the physical, chemical and biotic methodologies is looked back. The advanced physical techniques are introduced briefly at firstly. Additionally, evaluate on chemical method for plastic decomposition and review on biotic degradation of plastic. The reactive oxygen species and the enzymes play a crucial role in chemical and biotic degradation processes, respectively. The reactive oxygen species are derived from the activated state of oxides, and the enzymes that aid the microorganism to ingest plastic through its metabolic mechanism are secreted by the microorganism. Subsequently, the potential possibility of upcycling plastic is analyzed from two aspects of the technology and application. The innovative technology utilizes sunlight as driver-power of plastic upcycling. And the carbon capture, utilization and sequestration and the growth substrate provided the novel guided directions for plastic recycle. Lastly, the three suggestions on plastic waste management are expected to establish an economy and efficient plastic sorting system, and two engineering solutions on plastic recycle are to make a contribution for sustainable upcycling of plastic.

Open waste burning emissions constitute a significant source of air pollution affecting human health in India. In regions where cleaner fuels have displaced solid biofuel usage, open waste burning is rapidly becoming one of the largest sources of airborne human class-I-carcinogens and particulate matter. As the establishment of waste management infrastructure in rural India is likely to take years, we explore whether health-relevant emissions can be reduced by legalizing the burning of dry non-biodegradable waste in improved devices. We measure the emission factors of 76 VOCs, CH₄, CO, and CO₂ from different types of waste burned in two different improved devices, a burn basket and a local water heater. Based on our experiments, we create four “what-if” intervention scenarios to assess the improvement of air quality due to the emission reductions that can be accomplished by four management strategies. We find that substituting the traditional, more polluting water heating fuels with dry plastic waste across rural India can reduce primary emissions (e.g., −29 Ggy⁻¹ for benzene) and ozone formation potential (−2960 Ggy⁻¹) from open waste burning. When dry waste is used in lieu of more polluting fuels, and its burning serves a purpose, the net class-I-carcinogen benzene emissions, would be halved compared to the present. The change in emissions for the class-I carcinogen 1,3-butadiene would become net negative. This happens because the emissions avoided when part of the solid biofuel currently used in rural India is replaced by plastic waste (4.1 (1.2–4.1) Ggy⁻¹) exceed the waste burning emissions of this compound (3 (1.2–3.7) Ggy⁻¹) by so much, that residential sector emission reductions offset all waste burning emissions including those of landfill fires. Our study demonstrates that India's air quality can be improved by permitting and promoting the use of dry packaging waste in lieu of traditional biofuels and by promoting improved burning devices.

Baseline marine litter abundance and distribution on Saint Martin Island, Bay of Bengal, were assessed. Seventy-two transects (100–150 m) along 12 km of coastline were surveyed for litter items every two weeks for two months. The most abundant items were polythene bags, food wrappers, plastic bottles/caps, straws, styrofoam, plastic cups, plastic fragments, fishing nets, clothes, and rubber buoys. Tourism, local markets, hotels, domestic waste, and fishing activities were primary sources of marine litter. According to the mean clean coast index (CCI), all transects were clean, of which 11.3 % and 14.1 % of sandy beaches and rocky shores with sandy beaches were reported dirty, respectively. Northern Saint Martin Island comprised sandy beaches (2.8 %) and was extremely dirty. In addition, plastic abundance index (PAI) analysis showed that 24 % of sites, out of 72 sites, were under “very high abundance”, 33 % were “high abundance”, 33 % showed “moderate abundance”, and 4 % were classified as “low abundance”. Establishing baseline results of marine litter abundance and distribution on Saint Martin Island may help improve island conservation and mitigation strategies (e.g., improved waste management, beach cleaning activities to raise public awareness, local government litter reduction policies, and increase local pro-environmental behavioral change).

Contributions of Pacific Islands countries to marine plastic debris are disproportionate to the effects on people's connections to the ocean. Plastic waste management initiatives face challenges in containing waste and consequently plastics plague coastal environments. The Seabin, a floating trash skimmer, presents a novel and replicable approach to collecting and cataloguing marine plastics. The objectives of the study were to conduct an audit of marine plastic debris within the breakwaters of the University of the South Pacific, Marine Campus at Laucala Bay while simultaneously gauging the effectiveness of the Seabin and providing recommendations to enhance its utility. Inorganic debris was comprised entirely of plastics while the majority of debris collected was organic. This study provides the first assessment of floating marine plastic debris in an inshore environment of a Pacific Island country. Plastic debris assessments have the potential to inform policy and pivot management efforts to mitigate plastic waste pollution.

This study was a baseline with quantitative data of marine litter along the Gulf of Nicoya, Costa Rica. The objective of the study was to quantify marine litter and its association with human activities in this estuarine gulf. A total of fourteen sandy beaches were cataloged by the degree of urbanization, tourism intensity, beach cleaning programs, and tributary rivers as possible drivers of marine litter presence. The items of the marine litter were separated and weighted by type. Analysis by the clean coastal index (CCI) and multivariate statistics were applied to find spatial patterns in marine litter in the gulf. On beaches with the highest touristic activity, cigarette butts and straws were the main components. Locations with river plume influence, less frequent cleanup, or waste cans showed more bottles, plastic parts, and sanitary waste than beaches in other conditions. A beach in a fisherman town had recently utilized plastic bags, household goods, and boat parts in the marine litter. A wildlife refuge beach showed only small plastic and coffee foam cup fragments that came with currents from other points in the estuary. River basin management, solid waste disposal programs, and environmental education to avoid single-use items combined with correct waste disposal are needed to reduce marine litter in tropical countries focused on ecological tourism.