The debate on sludge recycling and disposal has been recently a target of growing interest due to the expressed concern about the potential risks of its agricultural use on human health and the environment. This fact has led to revisions in government policy and regulations and many novel treatment processes have been proposed in order to make the recycling and reuse of sewage sludge sustainable. In this work, the use of some pretreatments (alkaline, thermal, and ozonation) combined with conventional anaerobic digestion has been assessed on digested sludge quality in terms of pathogens, dewatering properties, heavy metals, and organic pollutants. All pretreatments proved to be efficient to reach the requirements proposed in the Working Document on Sludge prepared by the European Commission (CEC, Council Directive of 27 April 2000 on Working Document on Sludge--third draft. Brussels: European Commission DG Environment. Retrieved from http://ec.europa.eu/environment/waste/sludge/pdf/sludge_en.pdf, 2000a) and also those established by the U.S. Environmental Protection Agency (EPA, Standards for the disposal and utilization of sewage sludge, part 503. Retrieved from http://www.epa.state.il.us/public-notices/2004/lincoln-trails-mhp/draft-permit.pdf, 1993).

The main purpose of this work was to conduct a kinetic study on cell growth and hexavalent chromium [Cr(VI)] removal by Candida sp. FGSFEP in a concentric draft-tube airlift bioreactor. The yeast was batch-cultivated in a 5.2-l airlift bioreactor containing culture medium with an initial Cr(VI) concentration of 1.5 mM. The maximum specific growth rate of Candida sp. FGSFEP in the airlift bioreactor was 0.0244 h⁻¹, which was 71.83% higher than that obtained in flasks. The yeast strain was capable of reducing 1.5 mM Cr(VI) completely and exhibited a high volumetric rate [1.64 mg Cr(VI) l⁻¹ h⁻¹], specific rate [0.95 mg Cr(VI) g⁻¹ biomass h⁻¹] and capacity [44.38 mg Cr(VI) g⁻¹ biomass] of Cr(VI) reduction in the airlift bioreactor, with values higher than those obtained in flasks. Therefore, culture of Candida sp. FGSFEP in a concentric draft-tube airlift bioreactor could be a promising technological alternative for the aerobic treatment of Cr(VI)-contaminated industrial effluents.

This work investigates the solar heterogeneous photocatalytic degradation of three commercial acid dyes: Blue 9 (C.I. 42090), Red 51 (C.I. 45430), and Yellow 23 (C.I. 19140). TiO₂ P25 from Degussa was used as the photocatalyst. The dyes were completely degraded within 120 min of treatment in the following increasing order of removal rate: Blue 9 < Yellow 23 < Red 51. The photocatalytic color removal process was well described by a two-first-order in-series reaction, followed by another first-order reaction. Photolytic experiments showed that this process is quite inefficient and highly selective towards Red 51 only. The dyes' solution was completely decolorized and organic matter removals up to 99% were achieved with photocatalysis. The lack of selectivity and the possibility of using solar light to excite the photocatalyst are promising results regarding the feasibility of this technology.