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Landfill Leachate Treatment through Electro-Fenton Oxidation
2019
Mohajeri, S. | Hamidi, A. A. | Isa, M. H. | Zahed, M. A.
Advanced Oxidation Processes (AOPs) have been employed to degrade biorefractory organic matters. This study investigates the combination of classical Fenton reaction with electrochemical oxidation, the electro-Fenton process, for the treatment of semi aerobic landfill leachate, collected from Pulau Burung Landfill Site (PBLS), Penang, Malaysia. The investigation has been carried out in batch reactors with aluminum electrodes to establish the optimal treatment conditions. The effects of applied current, pH, reaction time, electrodes separation distance, H2O2/Fe2+ molar ratio, and H2O2 and Fe2+ concentrations, significant process parameters by themselves, have also been investigated. According to the obtained results, electro-Fenton process is very efficient for the treatment of landfill leachate. Optimum oxidation efficiency has been achieved when neither H2O2 nor Fe2+ are overdosed, so that the maximum amount of OH radicals is available for the oxidation of organic compounds. The highest COD and color removals have been 92% and 93%, respectively; obtained at initial pH=3, H2O2/Fe2+ molar ratio=1, applied current= 2A, treatment duration= 30 min, and electrodes separation distance= 3 cm. The current efficiency declines from 94% to 38% when the current rises from 0.5A to 2A.
Show more [+] Less [-]Uptake of Some Elements with Aquatic Plants Exposed to the Effluent of Wastewater Treatment Plant
2019
Tatar, S. | Obek, E. | Arslan Topal, E. I. | Topal, M.
In this study, in the removal of macro (P, S, Na, K, Ca, Mg) and micro (Sb, Ba, Co, Cu, Fe, Pb, Mn, Hg, Mo, Se, Ag, Zn) elements in the effluent of Elazig Wastewater Treatment Plant, the efficiency of Lemna minor L. and Lemna gibba L. has been studied comparatively. For this aim, fronds of these plants have been adapted to the effluent of the treatment plant that feeds pilot scale reactors. The concentrations of elements in fronds harvested during the working period were analyzed by ICP/MS. The analytical results show that Lemna minor L. has a high accumulation potential for P, Sb, Ba, Co, Fe, Pb, Mn, Hg, Ag and Zn while Lemna gibba L. has a high accumulation potential for S, Na, Ca, Mg, Cu, Mo and Se. The results show that Lemna minor L. and Lemna gibba L. can be used as phytoremediators of wastewater.
Show more [+] Less [-]Model for the Treatment of Refinery Wastewater and expression of catabolic genes in Fluidized Bed Bioreactor using mixed bacterial consortium
2019
Ajao, A. T. | Mustapha, M. O. | Yakubu, S. E.
This study was undertaken to evaluate a novel aerobic wastewater treatment model for the remediation of refinery effluents and to assess the removal efficiency of Bulkholderia cepacia strain AJI and Corynebacterium kutscheri strain AJ2 to clean oil waste from petrochemical company. Wastewater quality parameters including pH, BOD5, COD, TDS, OIL & GREASE, PHENOL concentration, TPH and THC were monitored at 5, 10 and 15 days of treatment and the removal efficiencies were calculated. Results indicated that the raw oily wastewater effluents used during this study had extremely high levels of all the tested parameters. The mean values of all physicochemical parameters of the wastewater from primary tank at different treatment period were statistically different (P˂0.001) After 15 days of biological treatment, BOD5 ,COD, TDS, Phenol, TPH, Oil & grease level of the refinery wastewater were reduced by 95.60 %, 98.40 % , 66.34 % , 100 %, 97.60 % and 96.20 % respectively. The detection of the catabolic genes in the bacterial isolates recovered from primary tank using polymerase chain reaction revealed that both Bulkholderia cepacia strain AJ1 and Corynebacterium kutsheri strain AJ2 carried alk B and C23O but C12O was not detected in both isolates. Naphthalene dioxygenase was detected in Bulkholderia cepacia strain AJ1 but not found in Corynebacterium kutscheri strain AJ2. After treatment the waste water was filtered in the secondary tank. The results of physicochemical parameters in the outlet vessel essentially confirmed that the mixed culture in the two column model successfully carry out bioremediation of refinery wastewater. Therefore, aerobic treatment model for the bioremediation of refinery Petroleum refineries generate great amounts of wastewaters that may become seriously dangerous, leading to the accumulation of toxic products in the receiving water bodies with potentially serious long term effects to aquatic biota. Due to extreme toxicity of contaminants in refinery wastewater, there is a need to develop an economical technique to remove the pollutants from the wastewater is highly recommended owing its environmental friendliness.
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