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Emerging organic contaminants in groundwater under a rapidly developing city (Patna) in northern India dominated by high concentrations of lifestyle chemicals
2021
Richards, Laura A. | Kumari, Rupa | White, Debbie | Parashar, Neha | Kumar, Arun | Ghosh, Ashok | Sumant Kumar, | Chakravorty, Biswajit | Lu, Chuanhe | Civil, Wayne | Lapworth, Dan J. | Krause, Stephan | Polya, David A. | Gooddy, Daren C.
Aquatic pollution from emerging organic contaminants (EOCs) is of key environmental importance in India and globally, particularly due to concerns of antimicrobial resistance, ecotoxicity and drinking water supply vulnerability. Here, using a broad screening approach, we characterize the composition and distribution of EOCs in groundwater in the Gangetic Plain around Patna (Bihar), as an exemplar of a rapidly developing urban area in northern India. A total of 73 EOCs were detected in 51 samples, typically at ng.L⁻¹ to low μg.L⁻¹ concentrations, relating to medical and veterinary, agrochemical, industrial and lifestyle usage. Concentrations were often dominated by the lifestyle chemical and artificial sweetener sucralose. Seventeen identified EOCs are flagged as priority compounds by the European Commission, World Health Organisation and/or World Organisation for Animal Health: namely, herbicides diuron and atrazine; insecticides imidacloprid, thiamethoxam, clothianidin and acetamiprid; the surfactant perfluorooctane sulfonate (and related perfluorobutane sulfonate, perfluorohexane sulfonate, perfluorooctanoic acid and perfluoropentane sulfonate); and medical/veterinary compounds sulfamethoxazole, sulfanilamide, dapson, sulfathiazole, sulfamethazine and diclofenac. The spatial distribution of EOCs varies widely, with concentrations declining with depth, consistent with a strong dominant vertical flow control. Groundwater EOC concentrations in Patna were found to peak within ∼10 km distance from the River Ganges, indicating mainly urban inputs with some local pollution hotspots. A heterogeneous relationship between EOCs and population density likely reflects confounding factors including varying input types and controls (e.g. spatial, temporal), wastewater treatment infrastructure and groundwater abstraction. Strong seasonal agreement in EOC concentrations was observed. Co-existence of limited transformation products with associated parent compounds indicate active microbial degradation processes. This study characterizes key controls on the distribution of groundwater EOCs across the urban to rural transition near Patna, as a rapidly developing Indian city, and contributes to the wider understanding of the vulnerability of shallow groundwater to surface-derived contamination in similar environments.
Show more [+] Less [-]Estimation of nitrate pollution sources and transformations in groundwater of an intensive livestock-agricultural area (Comarca Lagunera), combining major ions, stable isotopes and MixSIAR model
2021
Torres Martínez, Juan Antonio | Mora, Abrahan | Mahlknecht, Jürgen | Daesslé, Luis W. | Cervantes-Avilés, Pabel A. | Ledesma-Ruiz, Rogelio
The identification of nitrate (NO₃⁻) sources and biogeochemical transformations is critical for understanding the different nitrogen (N) pathways, and thus, for controlling diffuse pollution in groundwater affected by livestock and agricultural activities. This study combines chemical data, including environmental isotopes (δ²HH₂O, δ¹⁸OH₂O, δ¹⁵NNO₃, and δ¹⁸ONO₃), with land use/land cover data and a Bayesian isotope mixing model, with the aim of reducing the uncertainty when estimating the contributions of different pollution sources. Sampling was taken from 53 groundwater sites in Comarca Lagunera, northern Mexico, during 2018. The results revealed that the NO₃⁻ (as N) concentration ranged from 0.01 to 109 mg/L, with more than 32% of the sites exceeding the safe limit for drinking water quality established by the World Health Organization (10 mg/L). Moreover, according to the groundwater flow path, different biogeochemical transformations were observed throughout the study area: microbial nitrification was dominant in the groundwater recharge areas with elevated NO₃⁻ concentrations; in the transition zones a mixing of different transformations, such as nitrification, denitrification, and/or volatilization, were identified, associated to moderate NO₃⁻ concentrations; whereas in the discharge area the main process affecting NO₃⁻ concentrations was denitrification, resulting in low NO₃⁻ concentrations. The results of the MixSIAR isotope mixing model revealed that the application of manure from concentrated animal-feeding operations (∼48%) and urban sewage (∼43%) were the primary contributors of NO₃⁻ pollution, whereas synthetic fertilizers (∼5%), soil organic nitrogen (∼4%), and atmospheric deposition played a less important role. Finally, an estimation of an uncertainty index (UI90) of the isotope mixing results indicated that the uncertainties associated with atmospheric deposition and NO₃⁻−fertilizers were the lowest (0.05 and 0.07, respectively), while those associated with manure and sewage were the highest (0.24 and 0.20, respectively).
Show more [+] Less [-]Assessing the health impacts attributable to PM2.5 and ozone pollution in 338 Chinese cities from 2015 to 2020
2021
Guan, Yang | Xiao, Yang | Wang, Yameng | Zhang, Nannan | Chu, Chengjun
China has effectively reduced the fine particulate (PM₂.₅) pollution from 2015 to 2020. Ozone pollution and related health impacts have become severe contemporaneously. The coordinated control of PM₂.₅ and ozone is becoming a new issue for China's air pollution control. This study quantitatively assessed the health impacts attributed to PM₂.₅ and ozone pollution in 338 Chinese cities from 2015 to 2020 and estimated the possible health benefits from achieving dual concentration targets during 2021–2025. Results show PM₂.₅ caused a total health impact of 2.45 × 10⁷ disability-adjusted life years (DALYs) in 2020. All-cause and respiratory ozone-related health impact in 2020 was 1.04 × 10⁷ DALYs and 1.56 × 10⁶ DALYs. Between 2015 and 2020, the PM₂.₅-related health impacts decreased by 14.97%, while those ozone-related increased by 94.61% and 96.54% for all-cause and respiratory. Cities in the North China Plain have suffered higher health impacts attributable to PM₂.₅ and ozone pollution, indicating that the two-pollutant coordinated control is primarily needed. By achieving aggressive concentration target (decreasing 10%) between 2020 and 2025, China will reduce the PM₂.₅-related health impacts in 338 cities by 1.56 × 10⁶ DALYs (improving 6.37%). By achieving general target (decreasing 10% or within the Interim target-1 of World Health Organization), the PM₂.₅-related health benefit will be 7.98 × 10⁵ DALYs (improving 3.25%). The deteriorating ozone health risks will also be improved. Controlling air pollution in large cities and regional center cities can achieve remarkable health benefits. Due to the inter-region, inter-province, and inter-city difference of health impacts, targeted and differentiated pollution prevention and control need to be implemented.
Show more [+] Less [-]PCDD/Fs emissions from secondary copper production synergistically controlled by fabric filters and desulfurization
2021
Li, Haifeng | Liu, Wenbin | Lu, Anxiang | Li, Cheng | Die, Qingqi | Lei, Rongrong | Wu, Xiaolin
The effects of fabric filters and desulfurization systems during secondary copper smelting on polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) concentrations, emission coefficients, and profiles were studied in an oxygen-rich smelting furnace and an anode furnace. In the anode furnace, the toxic equivalent (TEQ) concentration ranges were 0.106–1.04 ng World Health Organization (WHO)-TEQ/m³ at the fabric filters inlet and 0.027–0.17 ng WHO-TEQ/m³ at the outlet. For the oxygen-rich smelting furnace, the TEQ concentration ranges were 1.21–1.93 and 0.010–0.019 ng WHO-TEQ/m³ at the desulfurization system inlet and outlet, respectively. The TEQs in the outlet stack gases of the desulfurization system from the anode furnace were 0.0041–0.016 ng WHO-TEQ/m³. It is likely that PCDD/Fs that were taken away from the stack gases were adsorbed by the fly ash and gypsum. Solid residues were the dominant release routes for PCDD/Fs. PCDD/Fs congener and homologue profiles of stack gases from different smelting stages were similar. The contributions of more chlorinated homologues from the anode furnace decreased observably after the stack gases passed through the fabric filters. However, the desulfurization process did not greatly change the PCDD/Fs homologue profiles. Overall, both the fabric filters and desulfurization systems showed excellent removal efficiencies for PCDD/Fs in the stack gases, which reduced the TEQ emissions to well below the 0.5 ng WHO-TEQ/m³ to achieve standard discharge.
Show more [+] Less [-]Responses of fine particulate matter and ozone to local emission reductions in the Sichuan Basin, southwestern China
2021
Qiao, Xue | Liu, Lu | Yang, Chun | Yuan, Yanping | Zhang, Mengyuan | Guo, Hao | Tang, Ya | Ying, Qi | Zhu, Shengqiang | Zhang, Hongliang
The Sichuan Basin (SCB) in southwestern China is largely affected by air pollution. Understanding the responses of air pollutant concentrations to emission changes is critical for designing and evaluating effective control strategies. Thus, this study used the Community Multi-scale Air Quality (CMAQ) model to simulate PM₂.₅ (i.e., particulate matter with an aerodynamic diameter ≤ 2.5 μm) in winter (January 2015) and ozone (O₃) in summer (July 2015) under nine emission reduction scenarios. For each scenario, the anthropogenic emissions of each air pollutant in each SCB grid cell were reduced by the same percentage, ranging from 10% to 90%. We found that approximately 30–70% emission reductions are required to reduce the January mean PM₂.₅ concentrations in all the SCB urban centers to a value that is less than the Chinese standard for daily mean PM₂.₅ (24-h PM₂.₅: 75 μg m⁻³). However, the January mean PM₂.₅ concentrations under 90% emission reduction still exceeded the World Health Organization (WHO) guideline (25 μg m⁻³) in 16 SCB urban centers. Moreover, reducing both SCB and non-SCB emissions were critical for achieving the PM₂.₅ level recommended by WHO. An 80% emission reduction was required to prevent the occurrence of 8-h O₃ (i.e., daily maximum 8-h mean O₃) non-attainment days in all SCB urban centers. Under 90% emission reduction, July mean 8-h O₃ concentrations still exceeded the WHO guideline of 47 ppb in approximately 35% of the SCB areas. In conclusion, this study suggests that (1) compared with the governmental emission reduction targets for 2015–2020 (2–27%), more significant emission reductions are required to meet the Chinese and WHO pollution standards; and (2) both SCB and non-SCB emissions must significantly reduce to achieve the desired pollution targets.
Show more [+] Less [-]The association of urinary metabolites of polycyclic aromatic hydrocarbons with obstructive coronary artery disease: A red alert for action
2021
Hajir, Salwa | Al Aaraj, Lamis | Zgheib, Nathalie | Badr, Kamal | Ismaeel, Hussain | Abchee, Antoine | Tamim, Hani | Saliba, Najat A.
In Lebanon, previous studies have indicated an onset of cardiovascular diseases 12 years earlier than in other parts of the world, suggesting the presence of additional risk factors specific to Lebanon. Measurements of airborne particles in Lebanon surpass the recommendations of the World Health Organization by over 150%. This study examined the association between obstructive coronary artery disease (CAD), assessed by a novel marker calculated from coronary catheterization, and markers of air pollution, specifically polycyclic aromatic hydrocarbons (PAHs), in a cohort of 258 patients seen at the American University of Beirut Medical Center since 2014. The concentrations of four types of hydroxylated polycyclic aromatic hydrocarbons (OHPAHs), 2-OHNAP, 2-OHFLU, 3-OHPHE, and 1-OHPYR, were measured in the urine samples of these patients using high performance liquid chromatography coupled with fluorescence detector. Results showed that the OHPAH concentrations were higher than what was reported in high-income countries and, most notably, the levels for non-smokers in this study were higher than those of smokers and some occupational workers in other countries. This implies that patients were exposed to high levels of PAHs, which originate from combustion sources. In particular, 1-OHPYR showed a significant association with presence of obstructive CAD, even after adjusting for covariates like age, sex, and diabetes. Smokers or not, this association has implications for public health and calls for urgent need to pass regulations to reduce the emissions of PAH sources, such as cars, diesel generators, and incinerators.
Show more [+] Less [-]How human mega-events influence urban airborne PM2.5 pollution: A systematic review and meta-analysis
2021
Li, Shaoning | Lu, Shaowei | Xu, Xiaotian | Zhao, Na | Li, Ai | Xu, Lan
Air pollution caused by PM₂.₅ particles is a critical issue for public health that adversely affects people living in urban cities. Short-term Mega-events such as international meetings, sports tournaments, and traditional festivals can profoundly influence the local air quality. However, the extent of these influences and their role in improving or deteriorating the local air quality is still unclear. By collecting relative research from 75 publications based on more than 37 cities worldwide, we conducted a systematic review and meta-analysis. We calculated the log response ratio (RR) of the treatment (during) and control periods (before and after) of the Mega-events. The short-term policy control measures enacted during the Mega-Events consisting of meetings caused a significant decline (by −44.06%) in the ambient PM₂.₅ concentration. The mean daily PM₂.₅ concentration reduced from more than 100.00 μg/m³ before the events to 60.39 μg/m³, which is below the WHO (World Health Organization) interim target – 1 (75 μg/m³). On the contrary, setting off fireworks during the festival increased the ambient PM₂.₅ concentrations by 89.57% on average, with a mean daily value of 254.22 μg/m³. The variations in the effects of all event types on the air quality were primarily influenced by the background PM₂.₅ concentrations, with a negative correlation throughout. Moreover, the impact of events with policy control measures was also influenced by the year of the event, level of control, and location (suburban/urban) of the monitoring sites. Our findings provide evidence of the potential of human intervention on PM₂.₅ pollution reduction. We further highlight the crucial role of background pollution level in implementing policies during the Mega-events, which can benefit the environmental governance of developing countries.
Show more [+] Less [-]Are greenspace quantity and quality associated with mental health through different mechanisms in Guangzhou, China: A comparison study using street view data
2021
Wang, Ruoyu | Feng, Zhiqiang | Pearce, Jamie | Liu, Ye | Dong, Guanghui
Residential greenspace quality may be more important for people's mental health than the quantity of greenspace. Existing literature mainly focuses on greenspace quantity and is limited to exposure metrics based on an over-head perspective (i.e., remote sensing data). Thus, whether greenspace quantity and quality influence mental health through different mechanisms remains unclear. To compare the mechanisms through which greenspace quantity and quality influence mental health, we used both remote sensing and street view data. Questionnaire data from 1003 participants in Guangzhou, China were analysed cross-sectionally. Mental health was assessed through the World Health Organization Well-Being Index (WHO-5). Greenspace quantity was measured by both remote sensing-based Normalized Difference Vegetation Index (NDVI) and Street View Greenness-quantity (SVG-quantity). Greenspace quality was measured by both Street View Greenness-quality (SVG-quality) and questionnaire-based self-reported greenspace quality. Structural equation models were used to assess mechanisms through which neighbourhood greenspace exposure has an influence on mental health. Stress, social cohesion, physical activity and life satisfaction were found to mediate both SVG-quality - WHO-5 scores and self-reported greenspace quality - WHO-5 scores associations. However, only NO₂ (nitrogen dioxide) mediated the association between NDVI and WHO-5 scores, while NO₂, perceived pollution and social cohesion mediated the association between SVG-quantity and WHO-5 scores. The mechanisms through which neighbourhood greenspace exposure influences mental health may vary across different exposure assessment strategies. Greenspace quantity influences mental health through reducing harm from pollution, while greenspace quality influences mental health through restoring and building capacities.
Show more [+] Less [-]Spatio-temporal characteristics of air pollutants over Xinjiang, northwestern China
2021
Rupakheti, Dipesh | Yin, Xiufeng | Rupakheti, Maheswar | Zhang, Qianggong | Li, Ping | Rai, Mukesh | Kang, Shichang
To understand the characteristics of particulate matter (PM) and other air pollutants in Xinjiang, a region with one of the largest sand-shifting deserts in the world and significant natural dust emissions, the concentrations of six air pollutants monitored in 16 cities were analyzed for the period January 2013–June 2019. The annual mean PM₂.₅, PM₁₀, SO₂, NO₂, CO, and O₃ concentrations ranged from 51.44 to 59.54 μg m⁻³, 128.43–155.28 μg m⁻³, 10.99–17.99 μg m⁻³, 26.27–31.71 μg m⁻³, 1.04–1.32 mg m⁻³, and 55.27–65.26 μg m⁻³, respectively. The highest PM concentrations were recorded in cities surrounding the Taklimakan Desert during the spring season and caused by higher amounts of wind-blown dust from the desert. Coarse PM (PM₁₀₋₂.₅) was predominant, particularly during the spring and summer seasons. The highest PM₂.₅/PM₁₀ ratio was recorded in most cities during the winter months, indicating the influence of anthropogenic emissions in winters. The annual mean PM₂.₅ (PM₁₀) concentrations in the study area exceeded the annual mean guidelines recommended by the World Health Organization (WHO) by a factor of ca. ∼5–6 (∼7–8). Very high ambient PM concentrations were recorded during March 19–22, 2019, that gradually influenced the air quality across four different cities, with daily mean PM₂.₅ (PM₁₀) concentrations ∼8–54 (∼26–115) times higher than the WHO guidelines for daily mean concentrations, and the daily mean coarse PM concentration reaching 4.4 mg m⁻³. Such high PM₂.₅ and PM₁₀ concentrations pose a significant risk to public health. These findings call for the formulation of various policies and action plans, including controlling the land degradation and desertification and reducing the concentrations of PM and other air pollutants in the region.
Show more [+] Less [-]Health Effects of Occupational Noise
2021
Pretzsch, Anna | Seidler, Andreas | Hegewald, Janice
PURPOSE OF REVIEW: Workplace noise negatively impacts health, and noise-induced hearing loss is the most common work-related disease in many countries. Occupational noise may also cause cardiovascular disease, and there is epidemiologic evidence on the non-auditory effects of noise. This paper aims to briefly present and summarize the latest evidence on the auditory and non-auditory health effects of occupational noise exposure from the last 5 years. RECENT FINDINGS: Two systematic reviews assessing the cardiovascular effects of occupational noise exposure were published in the last year. Our own recent review found convincing evidence of an association between occupational noise exposure > 80 dB(A) and hypertension and a dose-response relationship between noise exposure and hypertension risk. Another review of cardiovascular disease conducted by the World Health Organization (WHO) and the International Labour Organization (ILO) found an increased risk of incident ischemic heart disease at noise exposures ≥ 85 dB(A). Recent reviews on work-related injuries, diabetes, acoustic neuroma, and pregnancy outcomes also find noise-related associations. Evidence of an association between occupational noise and cardiovascular outcomes was recently evaluated. We found the risk of hypertension increases with a clear dose-response relationship at noise levels > 80 dB(A). The WHO/ILO review highlights the lack of quality research including women. Additional high-quality research on epigenetic effects, oxidative stress, work-related injuries, diabetes, acoustic neuroma, and pregnancy outcomes is also needed. Urgently needed (increased) measures of workplace noise reduction will reduce the incidence of noise-induced hearing loss and help prevent cardiovascular diseases, especially hypertension.
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