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Antifouling paint booster biocides (Irgarol 1051 and diuron) in marinas and ports of Bushehr, Persian Gulf Full text
2016
Saleh, Abolfazl | Molaei, Saeideh | Sheijooni Fumani, Neda | Abedi, Ehsan
In the present study, antifouling paint booster biocides, Irgarol 1051 and diuron were measured in ports and marinas of Bushehr, Iran. Results showed that in seawater samples taken from ports and marinas, Irgarol was found at the range of less than LOD to 63.4ngL−1 and diuron was found to be at the range of less than LOD to 29.1ngL−1 (in Jalali marina). 3,4-dichloroaniline (3,4-DCA), as a degradation product of diuron, was also analyzed and its maximum concentration was 390ngL−1. Results for analysis of Irgarol 1051 in sediments showed a maximum concentration of 35.4ngg−1 dry weight in Bandargah marina. A comparison between the results of this study and those of other published works showed that Irgarol and diuron pollutions in ports and marinas of Bushehr located in the Persian Gulf were less than the average of reports from other parts of the world.
Show more [+] Less [-]Damage and recovery assessment of the Philippines' mangroves following Super Typhoon Haiyan Full text
2016
Long, Jordan | Giri, Chandra | Primavera, Jurgenne | Trivedi, Mandar
We quantified mangrove disturbance resulting from Super Typhoon Haiyan using a remote sensing approach. Mangrove areas were mapped prior to Haiyan using 30m Landsat imagery and a supervised decision-tree classification. A time sequence of 250m eMODIS data was used to monitor mangrove condition prior to, and following, Haiyan. Based on differences in eMODIS NDVI observations before and after the storm, we classified mangrove into three damage level categories: minimal, moderate, or severe. Mangrove damage in terms of extent and severity was greatest where Haiyan first made landfall on Eastern Samar and Western Samar provinces and lessened westward corresponding with decreasing storm intensity as Haiyan tracked from east to west across the Visayas region of the Philippines. However, within 18months following Haiyan, mangrove areas classified as severely, moderately, and minimally damaged decreased by 90%, 81%, and 57%, respectively, indicating mangroves resilience to powerful typhoons.
Show more [+] Less [-]Offshore produced water management: A review of current practice and challenges in harsh/Arctic environments Full text
2016
Zheng, Jisi | Chen, Bing | Thanyamanta, Worakanok | Hawboldt, Kelly | Zhang, Baiyu | Liu, Bo
Increasing offshore oil and gas exploration and development in harsh/Arctic environments require more effective offshore produced water management, as these environments are much more sensitive to changes in water quality than more temperate climates. However, the number and scope of studies of offshore produced water management in harsh/Arctic environments are limited. This paper reviews the current state of offshore produced water management, impacts, and policies, as well as the vulnerability, implications and operational challenges in harsh/Arctic environments. The findings show that the primary contaminant(s) of concern are contained in both the dissolved oil and the dispersed oil. The application of emerging technologies that can tackle this issue is significantly limited by the challenges of offshore operations in harsh/Arctic environments. Therefore, there is a need to develop more efficient and suitable management systems since more stringent policies are being implemented due to the increased vulnerability of harsh/Arctic environments.
Show more [+] Less [-]Geogenic metal mobility in a coastal inlet impacted by cannery discharge, Magdalena Bay, Baja California Sur, Mexico Full text
2016
O'Shea, Beth | Capistrano, Christian | Lee, William
Magdalena Bay is an important habitat for marine organisms, some of which have been the subject of metal bioaccumulation studies. Cannery waste is discharged into the bay providing a plausible source of contamination but this study finds that some metals occur geogenically. Bay sediments and rocks (n=59) were analyzed for total metals and clustered (HCA) into two distinct groups with PCA indicating concentrations of Cr, Cu, Mn, and Ni influenced samples near ophiolite outcrops, which reported some metal concentrations exceeding averages in the crust by an order of magnitude (up to 4450ppm Cr and 1269ppm Ni). Metals at the cannery are rarely elevated above crustal averages except Zn (max. 160ppm), however, acid-extracted Zn was below recommended sediment quality guidelines in contrast to 80% of ophiolitic samples reporting Ni extractability exceeding such guidelines. This study raises awareness of geogenic metals when considering sources of contamination in marine environments.
Show more [+] Less [-]Evaluation of an urban modelling system against three measurement campaigns in London and Birmingham Full text
2016
Srimath, Srinivas T.G. | Sokhi, Ranjeet | Karppinen, Ari | Singh, Vikas | Kukkonen, Jaakko
The results of three measurement campaigns are presented in this study. The campaigns have been undertaken at an urban roadside site in London, for more than a year and three months in 2003–2004 and for a year in 2008, and at an urban background site in Birmingham, U.K, for about four months in 2002. The concentrations of PM2.5, PM10, NOx and NO2 were predicted using the roadside dispersion model CAR-FMI, combined with a national U.K. emission model, a meteorological pre-processor, and measured values at urban background stations. The agreement of the predicted and measured hourly and daily time-series has been assessed statistically for all of the campaigns and pollutants. For instance, the Indices of Agreement (IA) in all the campaigns ranged from 0.68 to 0.78, 0.87, from 0.70 to 0.80, and from 0.61 to 0.83 for PM2.5, PM10, NOx and NO2, respectively. However, in case of the campaigns in London, both the PM fractions and the nitrogen oxide concentrations were under-predicted. The model performance in terms of atmospheric stability, wind speeds and other factors was analysed, and reasons for the disagreement of predictions and measurements have been discussed. It is useful to consider the model performance statistics for several measurement campaigns simultaneously, as some of the results were found to be specific only to one or two campaigns. The spatial concentration distribution of NOx in London for 2008 has also been presented.
Show more [+] Less [-]Coral microbial community dynamics in response to anthropogenic impacts near a major city in the central Red Sea Full text
2016
Ziegler, Maren | Roik, Anna | Porter, Adam | Zubier, Khalid | Mudarris, Mohammed S. | Ormond, Rupert | Voolstra, Christian R.
Coral-associated bacteria play an increasingly recognized part in coral health. We investigated the effect of local anthropogenic impacts on coral microbial communities on reefs near Jeddah, the largest city on the Saudi Arabian coast of the central Red Sea. We analyzed the bacterial community structure of water and corals (Pocillopora verrucosa and Acropora hemprichii) at sites that were relatively unimpacted, exposed to sedimentation & local sewage, or in the discharge area of municipal wastewaters. Coral microbial communities were significantly different at impacted sites: in both corals the main symbiotic taxon decreased in abundance. In contrast, opportunistic bacterial families, such as e.g. Vibrionaceae and Rhodobacteraceae, were more abundant in corals at impacted sites. In conclusion, microbial community response revealed a measurable footprint of anthropogenic impacts to coral ecosystems close to Jeddah, even though the corals appeared visually healthy.
Show more [+] Less [-]Study of chemical species associated with fine particles and their secondary particle formation at semi-arid region of India Full text
2016
Satsangi, P.G. | Pipal, A.S. | Budhavant, K.B. | Rao, P.S.P. | Taneja, A.
The fine particles (PM2.5) were collected for 24 h from Agra atmosphere and chemically characterized during the one year study period. The average concentration of PM2.5 was 90.21 ± 20.62 μg m−3 which is higher than NAAQS and WHO annual standards and their seasonal trend was winter > summer > monsoon. Ionic study indicates that cations were dominant in comparison to anions. Seasonally, F−, Ca2+ and Mg2+ were higher during summer period and Cl−, NO3−, NH4+ and K+ were higher during monsoon period while SO42− was higher during winter season. The ratios Ca2+/Na+, Mg2+/Na+ and SO42−/Na+ were higher, while Cl−/Na ratio was lower than sea water ratio indicating the incorporation of non marine constituents in aerosols. The observed Cl−/Na+ (average 0.71) deviate considerable from the Sea water ratio suggesting either a fractionation of Cl− or enrichment of Na+ as there was significant deviation from marine sources. Linear correlation was observable between nss-Ca2+ and nss-Mg2+ with HCO3− throughout the annual seasonal cycle (HCO3−: Ca = 0.59, HCO3−: Mg2+ = 0.53) suggesting the origination of these species from soil dust. The calculated conversion ratio of ‘S’ (CRS) was lower than ‘N’ (CRN) which suggests that the secondary formation of NO3− aerosol from NO2 was more predominant than SO42−. Trajectory analysis indicates that long range transportation also contributes to PM2.5 mass over the measurement site.
Show more [+] Less [-]Influence of 2015 flood on the distribution and occurrence of microplastic pellets along the Chennai coast, India Full text
2016
Veerasingam, S. | Mugilarasan, M. | Venkatachalapathy, R. | Vethamony, P.
The sources, distribution, surface features, polymer composition and age of microplastic pellets (MPPs) in surface sediments along the Chennai coast during March 2015 (pre-Chennai flood) and November 2015 (post-Chennai flood) were characterised using a Stereoscopic microscope and FTIR-ATR spectroscopy. White MPPs were the most abundant, and specifically polyethylene (PE) and polypropylene (PP) were the dominant polymer types of MPPs found on the coast during both the times. The abundance of MPPs in November 2015 was three-fold higher than those found in March 2015, confirming that huge quantity of fresh MPPs washed through Cooum and Adyar rivers from land during the flood. The winds and surface currents during November were the driving forces for the transportation and deposition of MPPs from the sea to beaches. The results of this study will be useful to formulate beach MPPs litter management policies to effectively create long-term solutions.
Show more [+] Less [-]Seasonal variation and annual trends of metals and metalloids in the blood of the Little Penguin (Eudyptula minor) Full text
2016
Finger, Annett | Lavers, Jennifer L. | Orbell, John D. | Dann, Peter | Nugegoda, Dayanthi | Scarpaci, Carol
Seasonal variation and annual trends of metals and metalloids in the blood of the Little Penguin (Eudyptula minor) Full text
2016
Finger, Annett | Lavers, Jennifer L. | Orbell, John D. | Dann, Peter | Nugegoda, Dayanthi | Scarpaci, Carol
Little Penguins (Eudyptula minor) are high-trophic coastal feeders and are effective indicators of bioavailable pollutants in their foraging zones. Here, we present concentrations of metals and metalloids in blood of 157 Little Penguins, collected over three years and during three distinct seasons (breeding, moulting and non-breeding) at two locations: the urban St Kilda colony and the semi-rural colony at Phillip Island, Victoria, Australia. Penguin metal concentrations were foremostly influenced by location (St Kilda>Phillip Island for non-essential elements) and differed among years and seasons at both locations, reflecting differences in seasonal metal bioaccumulation or seasonal exposure through prey. Mean blood mercury concentrations showed an increasing annual trend and a negative correlation with flipper length at St Kilda. Notably, this study is the first to report on blood metal concentrations during the different stages of moult, showing the mechanism of non-essential metal mobilisation and detoxification.
Show more [+] Less [-]Seasonal variation and annual trends of metals and metalloids in the blood of the Little Penguin (Eudyptula minor) Full text
2016
Finger, Annett | Lavers, JL | Orbell, John | Dann, Peter | Nugegoda, D | Scarpaci, Carol
Mercury concentrations in marine sediments near a former mercury cell chlor-alkali plant in eastern Canada Full text
2016
Walker, Tony R.
Concentrations of total mercury (THg) were measured in coastal marine sediments near a former chlor-alkali plant in Chaleur Bay, New Brunswick. The chlor-alkali plant has been a local point source of THg since operation began in 1963. Historical THg contamination of marine sediments and biota has been widely reported. No baseline assessment has been conducted following plant closure in 2008. Surface (0–2cm) oxidized marine sediments were sampled along a single 5.2km transect radiating from the former plant and analysed for THg. THg concentrations ranged from 0.04–0.28μgg−1. Some localised THg concentrations exceeded Canadian marine sediment quality guidelines (n=4), but all samples (n=14) were significantly lower than previous studies conducted during plant operation. Plant closure (source control) and natural sediment recovery likely responsible for attenuating THg concentrations, but burial in deeper anoxic sediments may increase bioavilability of Hg that could pose ecological risks to marine biota.
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