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A comprehensive guide of remediation technologies for oil contaminated soil — Present works and future directions Full text
2016
Lim, Mee Wei | Lau, Ee Von | Poh, Phaik Eong
Oil spills result in negative impacts on the environment, economy and society. Due to tidal and waves actions, the oil spillage affects the shorelines by adhering to the soil, making it difficult for immediate cleaning of the soil. As shoreline clean-up is the most costly component of a response operation, there is a need for effective oil remediation technologies. This paper provides a review on the remediation technologies for soil contaminated with various types of oil, including diesel, crude oil, petroleum, lubricating oil, bitumen and bunker oil. The methods discussed include solvent extraction, bioremediation, phytoremediation, chemical oxidation, electrokinetic remediation, thermal technologies, ultrasonication, flotation and integrated remediation technologies. Each of these technologies was discussed, and associated with their advantages, disadvantages, advancements and future work in detail. Nonetheless, it is important to note that no single remediation technology is considered the best solution for the remediation of oil contaminated soil.This review provides a comprehensive literature on the various remediation technologies studied in the removal of different oil types from soil.
Show more [+] Less [-]An evaluation of oil spill responses for offshore oil production projects in Newfoundland and Labrador, Canada: Implications for seabird conservation Full text
2016
Fraser, Gail S. | Racine, Vincent
Seabirds are vulnerable to oil pollution, particularly in cold-water regions. We investigated the response of small spills (<7.95m3) at offshore production platforms in Newfoundland, a region recognized for seabird diversity and abundance. In three environmental assessments for oil production operations Environment Canada requested monitoring and mitigation of small spills potentially impacting seabird populations; suggestions supported by two independent reviews. An industry spill response plan states that operators would collect systematic observations on spills and deploy countermeasures where possible. Operators' spill reports were obtained under an Access to Information request. There were 220 daytime spills with sheens (out of 381 spills; 1997–2010). Of these, six reported time to oil dispersion and eleven the presence or absence of seabirds. Industry self-reporting has not permitted an evaluation of the impact of chronic oil spills on seabirds. We recommend that independent observers be placed on platforms to systematically collect data on spills and seabirds.
Show more [+] Less [-]A comparative proteomic study on the effects of metal pollution in oysters Crassostrea hongkongensis Full text
2016
The metal pollution has posed great risk on the coastal organisms along the Jiulongjiang Estuary in South China. In this work, two-dimensional electrophoresis-based proteomics was applied to the oysters Crassostrea hongkongensis from metal pollution sites to characterize the proteomic responses to metal pollution. Metal accumulation and proteomic responses indicated that the oysters from BJ site were more severely contaminated than those from FG site. Compared with those oyster samples from the clean site (JZ), metal pollution induced cellular injuries, oxidative and immune stresses in oyster heapatopancreas from both BJ and FG sites via differential metabolic pathways. In addition, metal pollution in BJ site induced disturbance in energy and lipid metabolisms in oysters. Results indicated that cathepsin L and ferritin GF1 might be the biomarkers of As and Fe in oyster C. hongkongensis, respectively. This study demonstrates that proteomics is a useful tool for investigating biological effects induced by metal pollution.
Show more [+] Less [-]Sediment chemistry and toxicity in Barnegat Bay, New Jersey: Pre- and post-Hurricane Sandy, 2012–13 Full text
2016
Hurricane Sandy made landfall in Barnegat Bay, October, 29, 2012, damaging shorelines and infrastructure. Estuarine sediment chemistry and toxicity were investigated before and after to evaluate potential environmental health impacts and to establish post-event baseline sediment-quality conditions. Trace element concentrations increased throughout Barnegat Bay up to two orders of magnitude, especially north of Barnegat Inlet, consistent with northward redistribution of silt. Loss of organic compounds, clay, and organic carbon is consistent with sediment winnowing and transport through the inlets and sediment transport modeling results. The number of sites exceeding sediment quality guidance levels for trace elements tripled post-Sandy. Sediment toxicity post-Sandy was mostly unaffected relative to pre-Sandy conditions, but at the site with the greatest relative increase for trace elements, survival rate of the test amphipod decreased (indicating degradation). This study would not have been possible without comprehensive baseline data enabling the evaluation of storm-derived changes in sediment quality.
Show more [+] Less [-]Arsenic speciation in water, suspended particles, and coastal organisms from the Taehwa River Estuary of South Korea Full text
2016
Hong, Seongjin | Kwon, Hye-Ok | Choi, Sung-Deuk | Lee, Jung-Suk | Khim, Jong Seong
Water, suspended particulate matter (SPM), and biota samples were collected from the Taehwa River Estuary to determine the distributions, partitioning, and bioaccumulation of arsenicals. Six forms of As were quantitated by the use of HPLC-ICP/MS. As was found mainly near urban and industrial areas, and inorganic AsV was the predominant As form in both water and SPM. Particulate arsenicals were found at the greatest concentrations in coarse particles (>180μm), followed by medium (30–180μm) and fine (0.45–30μm) particles, in freshwater. Arsenical concentrations were similar across the three particle fractions in saltwater. Field-based distribution coefficient (Kd) values for As depended strongly on SPM, with a less robust dependence on salinity. Concentrations of As were greater in macroalgae than in marine animals, such as fishes, bivalves, crabs, shrimps, and gastropods. Overall, the results of the present study provide useful information on the behaviors and fate of arsenicals in an estuarine environment.
Show more [+] Less [-]Isolation, identification and diesel-oil biodegradation capacities of indigenous hydrocarbon-degrading strains of Cellulosimicrobium cellulans and Acinetobacter baumannii from tarball at Terengganu beach, Malaysia Full text
2016
Nkem, Bruno Martins | Halimoon, Normala | Fatimah Md. Yusoff, | Johari, Wan Lufti Wan | Zakaria, Mohamad Pauzi | Medipally, Srikanth Reddy | Kannan, Narayanan
In this study, we isolated two indigenous hydrocarbon-degrading bacteria from tarball found in Rhu Sepuluh beach, Terengganu, Malaysia. These bacteria were identified based on their physiological characteristic and 16S rRNA gene sequence analysis, and they showed 99% similarity with Cellulosimicrobium cellulans DSM 43879 and Acinetobacter baumannii ATCC 19606 respectively. Their hydrocarbon-degrading capabilities were tested using diesel-oil as sole carbon source. Results analysed using GC–MS, showed diesel-oil alkanes were degraded an average 64.4% by C. cellulans and 58.1% by A. baumannii with medium optical density reaching 0.967 (C. cellulans) and 1.515 (A. baumannii) in minimal salt media at 32°C for 10days. Individual diesel-oil alkanes were degraded between 10%–95.4% by C. cellulans and 0.2%–95.9% by A. baumannii. Both strains utilized diesel-oil for growth. The study suggests both strains are part of indigenous hydrocarbon-degrading bacteria in tarball with potential for bioremediation of oil-polluted marine environment.
Show more [+] Less [-]Hepatic and renal metallothionein concentrations in Commerson's dolphins (Cephalorhynchus commersonii) from Tierra del Fuego, South Atlantic Ocean Full text
2016
Cáceres-Saez, Iris | Polizzi, Paula | Romero, Belén | Dellabianca, Natalia A. | Ribeiro Guevara, Sergio | Goodall, R. Natalie P. | Cappozzo, H Luis | Gerpe, Marcela
The Commerson's dolphin is the most common endemic odontocete of subantarctic waters of Tierra del Fuego, Argentina incidentally caught in fishing nets. The species is classified as “Data Deficient” by the IUCN. Metallothioneins (MTs) are considered as suitable biomarkers for health and environmental monitoring. The aims of the study were to assess MT concentrations in the liver and kidney of bycaught specimens. Moreover, correlations with Zn, Se, Cd, Ag and Hg, and the molar ratios of MT:metals were estimated to evaluate if there is an indication of their respective protective role against metal toxicity in tissues. Hepatic and renal MT concentrations were similar, ranging from 11.6 to 29.1nmol·g−1 WW, and Kidney/Liver ratios ranging from 0.73 to 1.93 corresponded to normal ranges. Results suggest that MTs are related to physiological ranges for the species. This information constitutes the first MT report on Commerson's dolphins and possibly considered as baseline for species' conservation.
Show more [+] Less [-]Beach debris on Aruba, Southern Caribbean: Attribution to local land-based and distal marine-based sources Full text
2016
de Scisciolo, Tobia | Mijts, Eric N. | Becker, Tatiana | Eppinga, Maarten B.
Accumulation of marine (plastic) debris from local land-based and distal marine-based sources along coastlines is a pressing modern issue. Hitherto, assessing the relative contribution of pollution sources through beach surveys is methodologically challenging. We surveyed ten beaches along the leeward and windward coastlines of Aruba (southern Caribbean) to determine differences in macro- and meso-debris densities. Differences were quantified using three metrics: 1) the gradient in macro-debris density away from the waterfront; 2) the proportion of plastic within macro-debris; 3) the meso-:macro-debris ratio. Overall 42,585 macro-debris items and 884 meso-debris items were collected. The density of near-shore macro-debris, proportion of plastic debris herein, and meso-:macro-debris ratio were highest on the windward coastline. These results suggest that southern Caribbean windward coastlines are mainly exposed to debris originating from distal marine-based sources, and leeward coastlines to local land-based sources. Our metrics clearly reflect these differences, providing novel means to survey debris source origin.
Show more [+] Less [-]Evaluation of two indoor air pollution abatement techniques in forced-ventilation fattening pig barns Full text
2016
Mostafa, Ehab | Hoelscher, Richard | Diekmann, Bernd | Ghaly, A.E. | Buescher, Wolfgang
Animal agricultural activities can be a significant source of pollutants affecting the health of farmers and neighboring communities. The main objective of this research was to improve the air quality by reducing the interior concentrations of emitting pollutants such as particulate matter (PM) and ammonia (NH3) within forced-ventilated fattening pig barns in order to improve the working conditions for human and the living conditions for animals as well as to have less impact on the surrounding environment. The mitigation techniques were a recirculating air scrubber and spraying of a water-oil mixture. The reduction efficiencies of the two mitigation techniques for PM and NH3 concentrations inside the barns were investigated. Two air scrubbers were mounted in a barn occupied with 515 pigs. A water-oil mixture spraying system with two different nozzles geometries was installed in a barn with 680 pigs. The data obtained from the mitigation system was compared with that obtained from a control barn with the same animal capacity and conditions. The results indicated that the average reduction efficiencies were 63% for total PM, 61% for PM10 and 32% for NH3. The results indicated that the average reduction efficiencies of the spraying system for the whole periods were 74% for total PM, 72% for PM10 and 19.5% for NH3 when using small nozzles and 44% for total PM, 39% for PM10 and 16% for NH3 when using large nozzles. The spraying system reduced the germs and fungal spore concentrations by 14 and 58%, respectively.
Show more [+] Less [-]Spatial and temporal distributions of polycyclic aromatic hydrocarbons in the Northern Arabian Gulf sediments Full text
2016
Gevao, Bondi | Boyle, Edward A. | Carrasco, Gonzalo G. | Ghadban, Abdul Nabi | Zafar, Jamal | Bahloul, Majed
Surficial sediment samples were collected from 25 locations within Kuwait Bay and outside the Bay, in the Northwestern Arabian Gulf, to access recent polycyclic aromatic hydrocarbon pollution in Kuwait. Time trends in the depositional history of PAHs to this portion of the Arabian Gulf was reconstructed from the analysis of a dated sediment core. Intersite differences in concentration exist although these differences were not statistically significant (p=0.08). However, organic carbon normalized concentrations within Kuwait Bay were 4 times higher than the average concentrations outside the Bay and were shown to be statistically significant (p<0.001). The sedimentary record showed that ΣPAHs concentration fluctuated between 12 and 25ngg−1 before 1970. Concentrations then increased sharply to a maximum of 45ngg−1 around the late 1970s and early 1980s followed by an exponential decrease in concentration to pre-1970 “background” concentrations of between 12 and 25ngg−1.
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