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Time series analysis of aerosol optical depth over New Delhi using Box–Jenkins ARIMA modeling approach
2016
Taneja, Kanika | Aḥmad, Shamshād | Kafīl, Aḥmad | Attri, S.D.
The present study focuses on the application of stochastic modeling technique in analyzing the future trends of aerosol optical properties. For this, the Box–Jenkins ARIMA (Autoregressive Integrated Moving Average) model has been used for simulating the monthly average Aerosol Optical Depth (AOD550 nm) retrieved from Terra MODIS (Moderate Resolution Imaging Spectroradiometer) over New Delhi, the urban capital of India. The satellite dataset has been collected for a period of ten years from 2004 to 2014. The analysis of autocorrelation function indicates existence of seasonality in the AOD time series. Several seasonal ARIMA models have been generated and their validation has been verified by assessing various estimation parameters, using the Statistical Package for the Social Sciences (SPSS, version 20). After rigorous evaluation of the selected models, the ARIMA (1,0,0)x(0,1,2)12 is identified as the best fit model w.r.t. measures of goodness-of-fit like Stationary R-square (0.530), R-square (0.674), Root Mean Squared Error (0.128); Mean Absolute Error (0.095); Mean Absolute Percentage Error (16.942); and normalized Bayesian Information Criteria (−3.941). The selected models have been further used to forecast AOD values for the year 2014 at 95% level of confidence. However, the ARIMA (1,0,0)x(2,1,1)12 model is found to have minimum forecasting error, calculated as Mean Percentage Error (0.220). As the difference in BIC of both the models is minimal (0.046), so both the models have been considered as best fit models and utilized for prediction of AOD. Satisfactory results have been obtained using the selected ARIMA models, suggesting that a simplistic modeling technique for determining the future values of AOD is feasible.
Show more [+] Less [-]A novel bioassay using the barnacle Amphibalanus amphitrite to evaluate chronic effects of aluminium, gallium and molybdenum in tropical marine receiving environments
2016
van Dam, Joost W. | Trenfield, Melanie A. | Harries, Simon J. | Streten, Claire | Harford, Andrew J. | Parry, David | van Dam, Rick A.
A need exists for appropriate tools to evaluate risk and monitor potential effects of contaminants in tropical marine environments, as currently impact assessments are conducted by non-representative approaches. Here, a novel bioassay is presented that allows for the estimation of the chronic toxicity of contaminants in receiving tropical marine environments. The bioassay is conducted using planktonic larvae of the barnacle Amphibalanus amphitrite and is targeted at generating environmentally relevant, chronic toxicity data for water quality guideline derivation or compliance testing. The developmental endpoint demonstrated a consistently high control performance, validated through the use of copper as a reference toxicant. In addition, the biological effects of aluminium, gallium and molybdenum were assessed. The endpoint expressed high sensitivity to copper and moderate sensitivity to aluminium, whereas gallium and molybdenum exhibited no discernible effects, even at high concentrations, providing valuable information on the toxicity of these elements in tropical marine waters.
Show more [+] Less [-]The implications of recurrent disturbances within the world's hottest coral reef
2016
Bento, Rita | Hoey, Andrew S. | Bauman, Andrew G. | Feary, David A. | Burt, John A.
Determining how coral ecosystems are structured within extreme environments may provide insights into how coral reefs are impacted by future climate change. Benthic community structure was examined within the Persian Gulf, and adjacent Musandam and northern Oman regions across a 3-year period (2008–2011) in which all regions were exposed to major disturbances. Although there was evidence of temporal switching in coral composition within regions, communities predominantly reflected local environmental conditions and the disturbance history of each region. Gulf reefs showed little change in coral composition, being dominated by stress-tolerant Faviidae and Poritidae across the 3years. In comparison, Musandam and Oman coral communities were comprised of stress-sensitive Acroporidae and Pocilloporidae; Oman communities showed substantial declines in such taxa and increased cover of stress-tolerant communities. Our results suggest that coral communities may persist within an increasingly disturbed future environment, albeit in a much more structurally simple configuration.
Show more [+] Less [-]Isahaya Bay, freshwater lake to an estuary again
2016
Hayami, Yuichi | Hamada, Takaharu
The inner 1/3 of Isahaya Bay which is a tributary of Ariake Sea in Japan was shut off from the sea by a dike for the reclamation and disaster prevention in 1997. On the other hand, several environmental and fisheries problems occurred in Ariake Sea after 1990s. Some fishermen insisted that the major reason for the decrease of fishing must be the influence of the dike construction and filed lawsuits. Now the court decision is fixed and Japanese government must open the gates to reintroduce sea water into the reservoir. We made numerical simulations of currents, hydrography and sediment transport to assess the influences of the gate opening. To choose the environmentally wise procedure of gate opening, it is needed to reduce the erosion and deposition of bottom sediments caused by the enhanced tidal current and to minimize the occurrence of hypoxia in the reservoir.
Show more [+] Less [-]Succession in an intertidal benthic community affected by untreated sewage effluent: A case of study in the SW Atlantic shore
2016
Becherucci, M.E. | Llanos, E.N. | Garaffo, G.V. | Vallarino, E.A.
A study of benthic succession related with sewage pollution was conducted in a warm-temperate coastal area of Mar del Plata city, Argentina. The effect of nutrient enrichment and starting period of the succession was tested after cleared space in the intertidal rocky shore benthic community. The time of recovery after a disturbance in enriched sites was considerably lower (20–29weeks) than in non-enriched sites based on the diatom Berkeleya sp. and the polychaete Boccardia proboscidea developed in the early succession stage, and Brachidontes rodriguezii or B. proboscidea occurring with Polysiphonia sp., Petalonia fascia and Ulva spp. developed in the late succession stage of the enriched sites. The very low time at which the community recovered in the enriched environments turned out to be one of the assets of the present study and this parameter can be used as a quick indicator of sewage pollution in the area.
Show more [+] Less [-]Simulation of oil pollution in the Persian Gulf near Assaluyeh oil terminal
2016
Faghihifard, M. | Badri, M.A.
Numerical simulation of oil slick movement with respect to tidal factors and wind effects was performed in order to counteract oil pollution in the Persian Gulf. First, a flow model was invoked with respect to water level fluctuations. The main tidal constituents were applied to the model using the initial conditions of water level variations in the Hormuz Strait near the Hangam Island. The movement of oil pollution was determined due to wind, tide and temperature effects and confirmed by applying a verified field results. Simulations were focused near an important terminal in the Persian Gulf, Assaluyeh Port. The results were led to preparing a risk-taking map in a parallel research for the Persian Gulf.
Show more [+] Less [-]Trace/heavy metal pollution monitoring in estuary and coastal area of Bay of Bengal, Bangladesh and implicated impacts
2016
Kibria, Golam | Hossain, Md Maruf | Mallick, Debbrota | Lau, T.C. | Wu, R. S. S. (Rudolf Shiu-sun)
Using artificial mussels (AMs), this study reports and compares time-integrated level of eleven trace metals (Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, U, Zn) in Karnafuli River estuary and coastal area of the Bay of Bengal, Bangladesh.Through this study, “hot spots” of metal pollution were identified. The results may demonstrate that the Karnafuli Estuary, and adjacent coastal area of Chittagong, Bangladesh are highly polluted by high risk metals (cadmium, chromium, copper, mercury, nickel, lead, uranium). Agricultural, domestic and industrial wastes directly discharged into the waterways have been identified as the main causes of metal pollution in Chittagong, Bangladesh. The high level of metal pollution identified may impact on local water quality, and seafood catch, livelihoods of people and public health resulting from seafood consumption. There is a need for regular monitoring to ascertain that local water quality with respect to metal levels are within acceptable levels to safeguards both environmental health and public health.
Show more [+] Less [-]Occurrence of chlorpyrifos in the atmosphere of the Araucanía Region in Chile using polyurethane foam-based passive air samplers
2016
Pozo, Karla | Llanos, Yasna | Estellano, Victor H. | Cortés, Sandra | Jorquera, Héctor | Gerli, Lorena | Pozo, Katerine | Encina, Francisco | Palma, Rodrigo | Focardi, S. (Silvano)
Little is known regarding the use and ambient levels of pesticides in Chilean agricultural regions. Chlorpyrifos (CPF) is one of the most used active ingredients in Chile and in the world. However, few investigations have been conducted to understand its environmental distribution and fate. In this study, PUF disk passive air samples were deployed during ∼one year in two areas, Angol (5 sites) and Villarrica (2 sites), in the Araucanía Region. The concentration in air of CPF ranged from ten to thousands of pg m−3 (∼20–14 600). The highest CPF concentrations were detected at the Angol sites (∼14 600 pg m3) during period 2 (August–December 2008). These results were higher by a factor of ∼10–15 than those detected in Villarica sites (∼2000 pg m3) in period 1 (April–July 2008). Seasonal CPF variations were observed, at both sites, within the sampling periods. Air back trajectory analyses showed that air masses from nearby agricultural zones contributed most of the CPF detected in Angol sites when the wind speed was low and at Villarrica when those sources were likely located north of the VMA site. These results provide initial data for CPF in the Chilean atmosphere and contribute new information to understanding distribution of CPF in Chilean environments.
Show more [+] Less [-]Determination of PM2.5 and polycyclic aromatic hydrocarbons from incense burning emission at shrine for health risk assessment
2016
Bootdee, Susira | Chantara, Somporn | Prapamontol, Tippawan
This study aims to determine fine particles (PM2.5) and polycyclic aromatic hydrocarbons (PAHs) bounded with PM2.5 emitted from incense burning at shrine to assess human health risk. The PM2.5 samples were collected by a mini volume air sampler during special occasions and normal period at a shrine located in the city center of Chiang Mai, Thailand. The samples were analyzed for 16-PAHs by GC–MS. The descending order of 8- and 24-hrs PM2.5 concentrations (μg/m3) were 625 ± 147 and 406 ± 159 (Chinese New Year) > 184 ± 85 and 133 ± 71 (other special occasions) > 100 ± 35 and 50 ± 20 (normal period). Their concentrations in each occasion were significantly different due to number of visitors and amount of incense being burned. Total PAHs concentrations (ng/m3) for 8- and 24-hrs in descending order were 90 ± 41 and 45 ± 29 (Chinese New Year), 71 ± 30 and 30 ± 12 (other special occasions) and 25 ± 15 and 14 ± 9 (normal periods). Correlation between PM2.5 and total PAHs concentrations was relatively strong. In addition, PM2.5 concentrations were highly correlated (r = 0.618) with carcinogenic PAHs (c-PAHs) indicated that carcinogenic compounds were dominant in particulate PAHs and generated from incense burning. The values of toxicity equivalent concentration (TEQ) indicate human health risk from PAHs inhalation. According to European guideline, it should be less than1 ng/m3 in ambient air. During Chinese New Year, they were relatively high (32 ± 27 ng/m3 (8 h) and 10 ± 4 ng/m3 (24 h)). Moreover, the isometric ratio analysis revealed that emission from incense burning was the main source of PM2.5 and PM2.5-bound PAHs.
Show more [+] Less [-]Long-term aging and degradation of microplastic particles: Comparing in situ oceanic and experimental weathering patterns
2016
Brandon, Jennifer | Goldstein, Miriam | Ohman, Mark D.
Polypropylene, low-density polyethylene, and high-density polyethylene pre-production plastic pellets were weathered for three years in three experimental treatments: dry/sunlight, seawater/sunlight, and seawater/darkness. Changes in chemical bond structures (hydroxyl, carbonyl groups and carbon-oxygen) with weathering were measured via Fourier Transform Infrared (FTIR) spectroscopy. These indices from experimentally weathered particles were compared to microplastic particles collected from oceanic surface waters in the California Current, the North Pacific Subtropical Gyre, and the transition region between the two, in order to estimate the exposure time of the oceanic plastics. Although chemical bonds exhibited some nonlinear changes with environmental exposure, they can potentially approximate the weathering time of some plastics, especially high-density polyethylene. The majority of the North Pacific Subtropical Gyre polyethylene particles we measured have inferred exposure times>18months, with some >30months. Inferred particle weathering times are consistent with ocean circulation models suggesting a long residence time in the open ocean.
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