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Mercury isotope fractionation during transfer from post-desulfurized seawater to air Full text
2016
Huang, Shuyuan | Lin, Kunning | Yuan, Dongxing | Gao, Yaqin | Sun, Lumin
Samples of dissolved gaseous mercury (DGM) in the post-desulfurized seawater discharged from a coal-fired power plant together with samples of gaseous elemental mercury (GEM) over the post-desulfurized seawater surface were collected and analyzed to study the mercury isotope fractionation during transfer from post-desulfurized seawater to air. Experimental results showed that when DGM in the seawater was converted to GEM in the air, the δ202Hg and Δ199Hg values were changed, ranging from −2.98 to −0.04‰ and from −0.31 to 0.64‰, respectively. Aeration played a key role in accelerating the transformation of DGM to GEM, and resulted in light mercury isotopes being more likely to be enriched in the GEM. The ratio Δ199Hg/Δ201Hg was 1.626 in all samples, suggesting that mercury mass independent fractionation occurred owing to the nuclear volume effect during the transformation. In addition, mass independent fractionation of mercury even isotopes was found in the GEM above the post-desulfurized seawater surface in the aeration pool.
Show more [+] Less [-]A preliminary approach of the spatio-temporal distribution of cationic aerosol components in the ambient atmosphere of Kochi, India Full text
2016
Gayathree Devi, P.K. | Sujatha, C.H.
Kochi City, situated in the vicinity of the industrial hub and marine niche, is significantly loaded with ionic compounds and get into the atmospheric aerosols which deteriorate the health status of the environment. The distribution of both acid and water extractable cations (Na+, NH4+, K+, Mg2+ and Ca2+) with respect to time and space, in the two phases (I and II) were performed at distinct sites of Kochi, Kerala, India. The study revealed that the water soluble Na+ ion is highlighted in the estuarine site (E1) with momentous load at the coastal site (C1) implying the sea salt influence at these two sites. The average NH4+ and K+ concentration (acid and water soluble fractions) recorded is mostly at the industrial site (R2) which may be endorsed due to the application of NPK fertilizers and also from the process of wood burning sources. Further, K+ is the prominent acid and water soluble cation recorded in the study. Mg2+ ion having both oceanic and anthropogenic origin contributes the present observed pollution load. Average acid soluble Ca2+ content is noted maximum at the estuarine spot E1, where as the hike with respect to water soluble fraction of this ion is noticed at the industrial site, R2. These inferences justify the influence of point sources such as industrial, crustal and construction related activities affecting in and around this metropolis.
Show more [+] Less [-]Marine protected area design patterns in the Mediterranean Sea: Implications for conservation Full text
2016
Rodríguez-Rodríguez, D. | Rodríguez, J. | Blanco, J.M. | Abdul Malak, D.
Mediterranean marine protected area (MPA) design patterns regarding geographic distribution, size, spacing and shape were analysed as a proxy of the region's MPA's ecological effectiveness and a first step towards an ecologically coherent MPA network.Results for legally designated MPAs and ecologically functional MPAs accounting for overlaps are presented. Geographically, Mediterranean MPA area is very unevenly distributed, with four-fifths concentrated in just three countries of the north-western part of the basin. Average distance between functional MPAs lies within recommended ecological thresholds, which suggests adequate potential connectivity of the Mediterranean MPA system. Mediterranean designated MPAs are larger than MPAs worldwide on average, although they are generally smaller than international guidance suggests at different levels: ecoregion, country and designation category. On average, Mediterranean designated and functional MPAs have relatively high compactness, which makes them prone to spillover and adequate viability, and less vulnerable to edge effects.
Show more [+] Less [-]Variations in nitrate isotope composition of wastewater effluents by treatment type in Hong Kong Full text
2016
Archana, A. | Li, Luo | Shuh-Ji, Kao | Thibodeau, Benoit | Baker, David M.
Stable isotopes (δ15N, δ18O) can serve as tracers for sources of nitrogen in the receiving environment. Hong Kong discharges ~3×106m3d−1 of treated wastewater into the ocean from 68 facilities implementing preliminary to tertiary treatment. We sampled treated sewage from 18 plants across 5 treatment types and examined receiving seawater from northeast Hong Kong. We analyzed nitrate and nitrite (NO3−+NO2−, hereafter NOx) ammonium (NH4+), phosphate (PO4+) concentrations and δ15NNOx, δ18ONOx. Sewage effluents contained high mean nutrient concentrations (NO3−=260μmolL−1, NH4+=1400μmolL−1, PO4+=50μmolL−1) with some indication of nitrogen removal in advanced treatment types. Mean δ15NNOx of sewage effluents from all plants and treatment types (12‰) was higher than natural sources and varied spatially and seasonally. There was no overall effect of sewage treatment type on δ15NNOx. A mass balance model indicated that sewage (>68%) remains a dominant source of nitrate pollution in seawater in Tolo Harbor.
Show more [+] Less [-]Description of plastic remains found in the stomach contents of the jumbo squid Dosidicus gigas landed in Ecuador during 2014 Full text
2016
Rosas-Luis, Rigoberto
Squids are active and opportunistic predators that feed on a wide range of prey. Their active movements in the water column and their voracity promote a high consumption of food. In the pelagic environment off Ecuador, marine pollution is characterized by plastic debris with a mainland origin, including plastics trash of fishing gears. The objective of this work was to describe the presence of plastic remains in the stomach contents of Dosidicus gigas caught off the coast of Ecuador. Results demonstrated that 12% of the stomachs contained plastic remains. These plastics were identified as multifilament of polyethylene lines and polyvinyl chloride remains. Findings of this work could be related to an increase in the discharge of solid materials in the water column, increasing the probability to be ingested by the jumbo squid.
Show more [+] Less [-]Quantifying the influence of meteorological variables on particle-bound PAHs in urban environments Full text
2016
Amarillo, Ana C. | Carreras, Hebe
Quantifying the influence of meteorological variables on particle-bound PAHs in urban environments Full text
2016
Amarillo, Ana C. | Carreras, Hebe
Seasonal trend of polycyclic aromatic hydrocarbons (PAHs) associated with PM10 particles was assessed in an urban area in Cordoba, Argentina, during 2011–2013. In addition, we quantified the contribution of temperature, relative humidity, rainfall, atmospheric pressure and wind speed on total and individual PAH concentrations. Mean PAH concentrations were higher during autumn and winter. Temperature was the meteorological parameter that affected the most total and individual PAHs. Its influence was stronger in lightweight than in heavy PAHs, since they are more easily partitioned in the vapor phase. We found also that temperature has a lagged effect on PAHs concentration with the strongest association observed with 2-day lag temperature. Wind speed and relative humidity were also significant predictors for both light and heavy PAHs. Despite the fact that we observed a decreasing trend in the concentration levels of PAHs, they are still high enough to pose a risk to human health due to chronic exposure.
Show more [+] Less [-]Quantifying the influence of meteorological variables on particle-bound PAHs in urban environments Full text
2016
Amarillo, Ana Carolina | Carreras, Hebe Alejandra
Seasonal trend of polycyclic aromatic hydrocarbons (PAHs) associated with PM10 particles was assessed in an urban area in Cordoba, Argentina, during 2011-2013. In addition, we quantified the contribution of temperature, relative humidity, rainfall, atmospheric pressure and wind speed on total and individual PAH concentrations. Mean PAH concentrations were higher during autumn and winter. Temperature was the meteorological parameter that affected the most total and individual PAHs. Its influence was stronger in lightweight than in heavy PAHs, since they are more easily partitioned in the vapor phase. We found also that temperature has a lagged effect on PAHs concentration with the strongest association observed with 2-day lag temperature. Wind speed and relative humidity were also significant predictors for both light and heavy PAHs. Despite the fact that we observed a decreasing trend in the concentration levels of PAHs, they are still high enough to pose a risk to human health due to chronic exposure. | Fil: Amarillo, Ana Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina | Fil: Carreras, Hebe Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto Multidisciplinario de Biología Vegetal. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto Multidisciplinario de Biología Vegetal; Argentina
Show more [+] Less [-]Isolation of plant-growth-promoting and metal-resistant cultivable bacteria from Arthrocnemum macrostachyum in the Odiel marshes with potential use in phytoremediation Full text
2016
Navarro-Torre, S. | Mateos-Naranjo, E. | Caviedes, M.A. | Pajuelo, E. | Rodríguez-Llorente, I.D.
Isolation of plant-growth-promoting and metal-resistant cultivable bacteria from Arthrocnemum macrostachyum in the Odiel marshes with potential use in phytoremediation Full text
2016
Navarro-Torre, S. | Mateos-Naranjo, E. | Caviedes, M.A. | Pajuelo, E. | Rodríguez-Llorente, I.D.
Arthrocnemum macrostachyum is a halophyte naturally growing in southwest coasts of Spain that can tolerate and accumulate heavy metals. A total of 48 bacteria (30 endophytes and 18 from the rhizosphere) were isolated from A. macrostachyum growing in the Odiel River marshes, an ecosystem with high levels of contamination. All the isolates exhibited plant-growth-promoting (PGP) properties and most of them were multiresistant to heavy metals. Although the presence of heavy metals reduced the capability of the isolates to exhibit PGP properties, several strains were able to maintain their properties or even enhance them in the presence of concrete metals. Two bacterial consortia with the best-performing endophytic or rhizospheric strains were selected for further experiments. Bacterial inoculation accelerated germination of A. macrostachyum seeds in both the absence and presence of heavy metals. These results suggest that inoculation of A. macrostachyum with the selected bacteria could ameliorate plant establishment and growth in contaminated marshes.
Show more [+] Less [-]Isolation of plant-growth-promoting and metal-resistant cultivable bacteria from Arthrocnemum macrostachyum in the Odiel marshes with potential use in phytoremediation Full text
2016
Navarro Torre, Salvadora | Mateos Naranjo, Enrique | Caviedes Formento, Miguel Ángel | Pajuelo Domínguez, Eloísa | Rodríguez Llorente, Ignacio David | Universidad de Sevilla. Departamento de Microbiología y Parasitología | Universidad de Sevilla. Departamento de Biología Vegetal y Ecología | Junta de Andalucía | Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria (INIA)
Arthrocnemum macrostachyum is a halophyte naturally growing in southwest coasts of Spain that can tolerate and accumulate heavy metals. A total of 48 bacteria (30 endophytes and 18 from the rhizosphere) were isolated from A. macrostachyum growing in the Odiel River marshes, an ecosystem with high levels of contamination. All the isolates exhibited plant-growth-promoting (PGP) properties and most of them were multiresistant to heavy metals. Although the presence of heavy metals reduced the capability of the isolates to exhibit PGP properties, several strains were able to maintain their properties or even enhance them in the presence of concrete metals. Two bacterial consortia with the best-performing endophytic or rhizospheric strains were selected for further experiments. Bacterial inoculation accelerated germination of A. macrostachyum seeds in both the absence and presence of heavy metals. These results suggest that inoculation of A. macrostachyum with the selected bacteria could ameliorate plant establishment and growth in contaminated marshes.
Show more [+] Less [-]Environmental quality in sediments of Cadiz and Algeciras Bays based on a weight of evidence approach (southern Spanish coast) Full text
2016
Usero, José Antonio | Rosado, Daniel | Usero, José | Morillo, José
Environmental quality in sediments of Cadiz and Algeciras Bays based on a weight of evidence approach (southern Spanish coast) Full text
2016
Usero, José Antonio | Rosado, Daniel | Usero, José | Morillo, José
This research applies an integrated sediment quality assessment method using a weight of evidence approach to Cadiz and Algeciras Bays (southern Spain). The method is composed of several analyses (particle size profile, aqua regia extractable metals, acid labile metals, total organic carbon, toxicity bioassay with Photobacterium phosphoreum and macrobenthic community alteration).The proposed method provides a single result, the environmental degradation index (EDI). EDI defined samples as low degraded (outer areas of both bays) and moderately degraded (Inner Bay of Cadiz Bay, the surroundings of Algeciras port and the northern part of Algeciras Bay). These samples showed the highest concentration of aqua regia extractable metals, which exceeded effects range-low (ERL) for Zn (51–176mg/l), Cu (11–54mg/l), As (4.3–9.5mg/l), Hg (0.17–0.28mg/l), Ni (23–82mg/l), and. Cr (37–134mg/l). They also exceeded some quality criteria for total organic carbon (4.0–6.5%) and toxicity (120–240TU/g) and showed poor results for macrobenthic community.
Show more [+] Less [-]Environmental quality in sediments of Cadiz and Algeciras Bays based on a weight of evidence approach (southern Spanish coast) Full text
2016
Usero, José Antonio | Rosado Alcarria, Daniel | Usero García, José | Morillo Aguado, José | Universidad de Sevilla. Departamento de Ingeniería Química y Ambiental
This research applies an integrated sediment quality assessment method using a weight of evidence approach to Cadiz and Algeciras Bays (southern Spain). The method is composed of several analyses (particle size profile, aqua regia extractable metals, acid labile metals, total organic carbon, toxicity bioassay with Photobacterium phosphoreum and macrobenthic community alteration). The proposed method provides a single result, the environmental degradation index (EDI). EDI defined samples as low degraded (outer areas of both bays) and moderately degraded (Inner Bay of Cadiz Bay, the surroundings of Algeciras port and the northern part of Algeciras Bay). These samples showed the highest concentration of aqua regia extractable metals, which exceeded effects range-low (ERL) for Zn (51–176 mg/l), Cu (11–54 mg/l), As (4.3–9.5 mg/l), Hg (0.17–0.28 mg/l), Ni (23–82 mg/l), and. Cr (37–134 mg/l). They also exceeded some quality criteria for total organic carbon (4.0–6.5%) and toxicity (120–240 TU/g) and showed poor results for macrobenthic community.
Show more [+] Less [-]Bioindicators as metrics for environmental monitoring of desalination plant discharges Full text
2016
de-la-Ossa-Carretero, J.A. | Del-Pilar-Ruso, Y. | Loya-Fernández, A. | Ferrero-Vicente, L.M. | Marco-Méndez, C. | Martinez-Garcia, E. | Giménez-Casalduero, F. | Sánchez-Lizaso, J.L.
Bioindicators as metrics for environmental monitoring of desalination plant discharges Full text
2016
de-la-Ossa-Carretero, J.A. | Del-Pilar-Ruso, Y. | Loya-Fernández, A. | Ferrero-Vicente, L.M. | Marco-Méndez, C. | Martinez-Garcia, E. | Giménez-Casalduero, F. | Sánchez-Lizaso, J.L.
Development of desalination projects requires simple methodologies and tools for cost-effective and environmentally-sensitive management. Sentinel taxa and biotic indices are easily interpreted in the perspective of environment management. Echinoderms are potential sentinel taxon to gauge the impact produced by brine discharge and the BOPA index is considered an effective tool for monitoring different types of impact. Salinity increase due to desalination brine discharge was evaluated in terms of these two indicators. They reflected the environmental impact and recovery after implementation of a mitigation measure. Echinoderms disappeared at the station closest to the discharge during the years with highest salinity and then recovered their abundance after installation of a diffuser reduced the salinity increase. In the same period, BOPA responded due to the decrease in sensitive amphipods and the increase in tolerant polychaete families when salinities rose. Although salinity changes explained most of the observed variability in both indicators, other abiotic parameters were also significant in explaining this variability.
Show more [+] Less [-]Bioindicators as metrics for environmental monitoring of desalination plant discharges Full text
2016
de-la-Ossa-Carretero, Jose Antonio | Del-Pilar-Ruso, Yoana | Loya-Fernández, Angel | Ferrero-Vicente, Luis Miguel | Marco-Méndez, Candela | Martinez-Garcia, Elena | Gimenez-Casalduero, Francisca | Sánchez-Lizaso, José Luis | Del-Pilar-Ruso, Yoana | Sánchez-Lizaso, José Luis | Gimenez-Casalduero, Francisca | Universidad de Alicante. Departamento de Ciencias del Mar y Biología Aplicada | Biología Marina | Recursos Hídricos y Desarrollo Sostenible
Development of desalination projects requires simple methodologies and tools for cost-effective and environmentally-sensitive management. Sentinel taxa and biotic indices are easily interpreted in the perspective of environment management. Echinoderms are potential sentinel taxon to gauge the impact produced by brine discharge and the BOPA index is considered an effective tool for monitoring different types of impact. Salinity increase due to desalination brine discharge was evaluated in terms of these two indicators. They reflected the environmental impact and recovery after implementation of a mitigation measure. Echinoderms disappeared at the station closest to the discharge during the years with highest salinity and then recovered their abundance after installation of a diffuser reduced the salinity increase. In the same period, BOPA responded due to the decrease in sensitive amphipods and the increase in tolerant polychaete families when salinities rose. Although salinity changes explained most of the observed variability in both indicators, other abiotic parameters were also significant in explaining this variability. | These surveys were funded by the Mancomunidad de Canales del Taibilla.
Show more [+] Less [-]Dynamics of phytoplankton communities in eutrophying tropical shrimp ponds affected by vibriosis Full text
2016
Lemonnier, Hugues | Lantoine, François | Courties, Claude | Guillebault, Delphine | Nézan, Elizabeth | Chomérat, Nicolas | Escoubeyrou, Karine | Galinié, Christian | Blockmans, Bernard | Laugier, Thierry
Dynamics of phytoplankton communities in eutrophying tropical shrimp ponds affected by vibriosis Full text
2016
Lemonnier, Hugues | Lantoine, François | Courties, Claude | Guillebault, Delphine | Nézan, Elizabeth | Chomérat, Nicolas | Escoubeyrou, Karine | Galinié, Christian | Blockmans, Bernard | Laugier, Thierry
Tropical shrimp aquaculture systems in New Caledonia regularly face major crises resulting from outbreaks of Vibrio infections. Ponds are highly dynamic and challenging environments and display a wide range of trophic conditions. In farms affected by vibriosis, phytoplankton biomass and composition are highly variable. These conditions may promote the development of harmful algae increasing shrimp susceptibility to bacterial infections. Phytoplankton compartment before and during mortality outbreaks was monitored at a shrimp farm that has been regularly and highly impacted by these diseases. Combining information from flow cytometry, microscopy, pigment and phylogenetic analysis, the presence of Picocyanobacteria, Prasinophyceae and Diatomophyceae were detected as dominant phytoplankton groups and Cryptophyceae, Prymnesiophyceae and Dinophyceae as minor components. At the onset of the first shrimp mortalities, Bacillariophyceae increased while Cyanobacteria, Prymnesiophyceae and Dinophyceae decreased in the water column, followed by proliferation of Prasinophyceae. Several taxa were identified as potential harmful algae (Cyanobacteria, dinoflagellates and Phaeocystis).
Show more [+] Less [-]Dynamics of phytoplankton communities in eutrophying tropical shrimp ponds affected by vibriosis Full text
2016
Lemonnier, Hugues | Lantoine, Francois | Courties, Claude | Guillebault, Delphine | Nezan, Elisabeth | Chomerat, Nicolas | Escoubeyrou, Karine | Galinie, Christian | Blockmans, Bernard | Laugier, Thierry
Tropical shrimp aquaculture systems in New Caledonia regularly face major crises resulting from outbreaks of Vibrio infections. Ponds are highly dynamic and challenging environments and display a wide range of trophic conditions. In farms affected by vibriosis, phytoplankton biomass and composition are highly variable. These conditions may promote the development of harmful algae increasing shrimp susceptibility to bacterial infections. Phytoplankton compartment before and during mortality outbreaks was monitored at a shrimp farm that has been regularly and highly impacted by these diseases. Combining information from flow cytometry, microscopy, pigment and phylogenetic analysis, the presence of Picocyanobacteria, Prasinophyceae and Diatomophyceae were detected as dominant phytoplankton groups and Cryptophyceae, Prymnesiophyceae and Dinophyceae as minor components. At the onset of the first shrimp mortalities, Bacillariophyceae increased while Cyanobacteria, Prymnesiophyceae and Dinophyceae decreased in the water column, followed by proliferation of Prasinophyceae. Several taxa were identified as potential harmful algae (Cyanobacteria, dinoflagellates and Phaeocystis).
Show more [+] Less [-]