A comprehensive analysis of 15 target chemical compounds (pharmaceuticals and personal care product, perfluoroalkyl compounds and industrial chemicals) were carried out to determine their concentrations in selected commercially exploited, wild caught small and medium sized pelagic fish species and their organs (Thyrsites atun (snoek), Sarda orientalis (bonito), Pachymetopon blochii (panga) and Pterogymnus laniarius (hottentot)) obtained from Kalk Bay harbour, Cape Town. Solid phase extraction (SPE) method based on Oasis HLB cartridges were used to concentrate and clean-up the samples. Liquid chromatography–mass spectrometry analysis of these chemical compounds revealed the simultaneous presence of at least 12 compounds in different parts of the selected fish species in nanogram-per-gram dry weight (ng/g dw) concentrations. The results revealed that perfluorodecanoic acid, perfluorononanoic acid and perfluoroheptanoic acid were the most predominant among the perfluorinated compounds and ranged between: (20.13–179.2 ng/g), (21.22–114.0 ng/g) and (40.06–138.3 ng/g). Also, diclofenac had the highest concentration in these edible fish species out of all the pharmaceuticals detected (range: 551.8–1812 ng/g). The risk assessment values were above 0.5 and 1.0 for acute and chronic risk respectively which shows that these chemicals have a high health risk to the pelagic fish, aquatic organisms and to humans who consume them. Therefore, there is an urgent need for a precautionary approach and the adequate regulation of the use and disposal of synthetic chemicals that persist in aquatic/marine environment in this province and other parts of South Africa, to prevent impacts on the sustainability of our marine environment, livelihood and lives.

The binding of metal ions with humic acid (HA) plays an important role in the aggregation of HA and the migration of metal ions in the environments. The effects of common cations (Na⁺, Mg²⁺, Ca²⁺ and Al³⁺) and heavy metal ions (Ag⁺, Cd²⁺, Cu²⁺, Cr³⁺ and Eu³⁺) on the aggregation of HA were investigated systematically by aggregation kinetics, spectroscopic techniques and molecular dynamic (MD) simulations. The critical coagulation concentration (CCC) of mono-, di- and trivalent cations could be predicted by the Schulze-Hardy rule. The aggregation of HA in the presence of Na⁺ and Ag⁺ was mainly due to the reduction of repulsive force and the hydrogen bonds between HA molecules. While the complexation of di- and trivalent cations with carboxylic/phenolic groups, or the cation-π interactions enhanced the intra- or inter-molecular bridges in HA and then contributed greatly to the aggregation of HA. Heavy metal ions could easily pass through the electric double-layer of HA compared with common cations. MD simulations further signified the strong aggregation ability of HA molecules in solutions containing high valence metal ions. These findings are important for understanding not only how the influence of metal ions on the aggregation of HA, but also the conditions which ions more efficient for aggregation.

Pollutants, which are usually transported from urban cities to remote glacier basins, and aerosol impurities affect the earth's temperature and climate by altering the radiative properties of the atmosphere. This work focused on the physicochemical properties of atmospheric pollutants across the urban and remote background sites in northwest China. Information on individual particles was obtained using transmission electron microscopy (TEM) and energy dispersive X-ray spectrometry (EDX). Particle size and age-dependent mixing structures of individual particles in clean and polluted air were investigated. Aerosols were classified into eight components: mineral dust, black carbon (soot)/fly ash, sulfates, nitrates, NaCl salt, ammonium, organic matter, and metals. Marked spatial and seasonal changes in individual particle components were observed in the study area. Aerosol particles were generally found to be in the mixing state. For example, salt-coated particles in summer accounted for 31.2–44.8% of the total particles in urban sites and 37.5–74.5% of the total particles in background sites, while in winter, almost all urban sites comprised >50%, which implies a significant effect on the radiative forcing in the study area. We found that in PM₂.₅ section, the internally mixed black carbon/organic matter particles clearly increased with diameter. Moreover, urban cities were characterized by atmospheric particles sourced from anthropogenic activities, whereas background locations exhibited much lower aerosol concentrations and increased particle density, originating from natural crustal sources (e.g., mineral dust and NaCl salt), which, together with air mass trajectory analysis, indicates a potential spatial transport process and routes of atmospheric transport from urban cities to background locations. Thus, this work is of importance in evaluating atmospheric conditions in northwest China and northeast Tibetan Plateau regions, to discover the transport processes and facilitate improvements in climatic patterns concerning atmospheric impurities.

Ionic liquids (ILs) are extensively used in several chemistry fields. And research about the effects of ILs on soil microbes is needed. In this study, brown soil was exposed to 1-butyl-3-methylimidazolium bromide ([C₄mim]Br), 1-hexyl-3-methylimidazolium bromide ([C₆mim]Br) and 1-decyl-3-methylimidazolium bromide ([C₁₀mim]Br). The toxicities of the three ILs are evaluated by measuring the soil culturable microbial number, enzyme activity, microbial diversity and, abundance of the ammonia monooxygenase (amoA) genes of ammonia-oxidizing bacteria (AOB) and ammonia-oxidizing archaea (AOA). Results showed that all tested ILs caused a decrease in culturable microbial abundance. Tested ILs exposure inhibit urease activity and promote acid phosphatase and β-glucosidase activities. Tested ILs reduced soil microbial diversity and the abundances of AOB-amoA and AOA-amoA genes significantly. After a comparison of the integrated biomarker response (IBR) index, the toxicities of tested ILs to soil microorganisms were as follows: [C₁₀mim]Br > [C₆mim]Br > [C₄mim]Br. Among all collected biomarkers, the abundance of the AOA-amoA gene was the most sensitive one and was easily affected after ILs exposure.

Polychlorinated biphenyls (PCBs) are a class of persistent organic pollutants that have been shown to be related to the occurrence of type 2 diabetes mellitus (T2DM). Nevertheless, it is necessary to further explore the development of T2DM caused by PCBs and its underlying mechanisms. In the present study, 21-day-old C57BL/6 male mice were orally treated with Aroclor 1254 (0.5, 5, 50 or 500 μg kg−1) once every three days. After exposure for 66 d, the mice showed impaired glucose tolerance, 13% and 14% increased fasting serum insulin levels (FSIL), and 63% and 69% increases of the pancreatic β-cell mass in the 50 and 500 μg kg−1 groups, respectively. After stopping exposure for 90 d, treated mice returned to normoglycemia and normal FSIL. After re-exposure of these recovered mice to Aroclor 1254 for 30 d, fasting plasma glucose showed 15%, 28% and 16% increase in the 5, 50 and 500 μg kg−1 treatments, FSIL exhibited 35%, 27%, 30% and 32% decrease in the 0.5, 5, 50 or 500 μg kg−1 groups respectively, and there was no change in pancreatic β-cell mass. Transcription of the pancreatic insulin gene (Ins2) was significantly down-regulated in the 50 and 500 μg kg−1 groups, while DNA-methylation levels were simultaneously increased in the Ins2 promoter during the course of exposure, recovery and re-exposure. Reduced insulin levels were initially rescued by a compensative increase in β-cell mass. However, β-cell mass eventually failed to make sufficient levels of insulin, resulting in significant increases in fasting blood glucose, and indicating the development of T2DM.

Little is known about the impacts of maternal exposure to acute episodes of outdoor air pollution, such as that resulting from wildfires, on obstetric and neonatal outcomes. This systematic review aims to synthesise the existing literature exploring the relationship between maternal exposure to short-to medium-term changes in outdoor air quality and obstetric and neonatal outcomes.A systematic search of peer-reviewed articles using PubMed, Cochrane Library, EMBASE, ScienceDirect, Web of Science, ProQuest, GreenFILE and Scopus was conducted in January 2018 using selected search terms. Quality of included studies were assessed using the Newcastle Ottawa Scale.Eleven studies were included; eight assessed the impact of maternal exposure to air pollution exacerbation events, such as wildfires, oil well fires and volcanic eruptions, and three assessed the impact of improvement events, such as the 2018 Beijing Olympics and closure of industrial activities, on obstetric and neonatal outcomes. Studies were highly heterogenous in methodology. Six studies found a significant association between acute changes in air quality and markers of fetal growth restriction, while two did not. Three studies found an adverse association between acute changes in air quality and markers of gestational maturity, and one did not.Overall, there is some evidence that maternal exposure to acute changes in air quality of short-to medium-term duration increases the risk of fetal growth restriction and preterm birth. The relationship for other adverse obstetric or neonatal outcomes is less clear.

In this study, carbon nanotube-based adsorbents, oxidized multi-walled carbon nanotube (OMWCNT) with non-magnetic property and OMWCNT-Fe₃O₄ and OMWCNT-κ-carrageenan-Fe₃O₄ nanocomposites with magnetic property, having different structural and surface properties were prepared and their adsorptive properties for the removal of toxic diquat dibromide (DQ) herbicide from water by adsorption were determined in detail. For each adsorption system, the effects of initial DQ concentration, contact time and temperature on the adsorption processes were determined. Equilibrium time was found to be 300 min for DQ solutions. OMWCNT showed faster adsorption and higher maximum adsorption capacity value than magnetic adsorbents. With increasing initial herbicide concentration from 5.43 mg.L⁻¹ to 16.3 mg.L⁻¹, the values of initial sorption rate exhibited a decrease from 29.1 mg.g⁻¹.min⁻¹ to 4.28 mg.g⁻¹.min⁻¹ for OMWCNT-DQ system, from 1.21 mg.g⁻¹.min⁻¹ to 0.823 mg.g⁻¹.min⁻¹ for OMWCNT-Fe₃O₄-DQ system and from 0.674 mg.g⁻¹.min⁻¹ to 0.612 mg.g⁻¹.min⁻¹ OMWCNT-κ-carrageenan-Fe₃O₄ system. Maximum adsorption capacity value of OMWCNT was approximately 2.8-fold higher than magnetic OMWCNT-Fe₃O₄ and 5.4-fold higher than magnetic OMWCNT-κ-carrageenan-Fe₃O₄ at 25 °C. Adsorption kinetic and isotherm data obtained for all adsorption systems were well-fitted by pseudo second-order and Langmuir models, respectively. Thermodynamic parameters indicated that the adsorption of DQ onto carbon nanotube-based adsorbents was spontaneous and endothermic process. Furthermore, OMWCNT having the highest herbicide adsorption capacity could be regenerated and reused at least five times. This study showed that carbon nanotube-based adsorbents with magnetic and non-magnetic property were of high adsorption performance for the removal of DQ from water and could be promising adsorbent materials for the efficient removal of herbicides from wastewaters.

Microplastic (MP) has become ubiquitous in the marine environment. Its threat to marine organisms has been demonstrated under laboratory conditions, yet studies on wild populations still face methodological difficulties. We reviewed the methods used to separate MP from soft animal tissues and highlighted a lack of standardised methodologies, particularly critical for synthetic microfibres. We further compared enzymatic and a potassium hydroxide (KOH)-based alkaline digestion protocols on wild crabs (Carcinus aestuarii) collected from three coastal lagoons in the north Adriatic Sea and on laboratory-prepared synthetic polyester (PES) of different colour and polypropylene (PP). We compared the cost-effectiveness of the two methods, together with the potential for adverse quantitative or qualitative effects on MP that could alter the capability of the polymers to be recognised via microscopic or spectroscopic techniques. Only 5.5% of the 180 examined crabs contained MP in their gastrointestinal tracts, with a notably high quantitative variability between individuals (from 1 to 117 particles per individual). All MP found was exclusively microfibres, mainly PES, with a mean length (±SE) of 0.5 ± 0.03 mm. The two digestion methods provided comparable estimates on wild crabs and did not cause any visible physical or chemical alterations on laboratory-prepared microfibres treated for up to 4 days. KOH solution was faster and cheaper compared to the enzymatic extraction, involving fewer procedural steps and therefore reducing the risk of airborne contamination. With digestion times longer than 4 days, KOH caused morphological alterations of some of the PES microfibres, which did not occur with the enzymatic digestion. This suggests that KOH is effective for the digestion of small marine invertebrates or biological samples for which shorter digestion time is required, while enzymatic extraction should be considered as alternative for larger organisms or sample sizes requiring longer digestion times.