Polybrominated diphenyl ethers (PBDEs), a persistent organic pollutant are ubiquitous in aquatic ecosystems, which are causing serious environmental concerns. In this study, we chose BDE-47 as a representative PBDEs, to investigate its toxic effects on two microalgal species and the response of their antioxidant system. The results indicated Alexandrium minutum (a dinoflagellate) was more sensitive to BDE-47 than Dunaliella salina (a chlorophyte), as determined by growth rates, cellular structure and photosynthetic parameters. Cellular reactive oxygen species (ROS) levels were significantly elevated under the exposure of BDE-47 in both species, corresponding to an increase of superoxide dismutase (SOD), catalase (CAT) and glutathione reductase (GR) activities, while glutathione peroxidase (GPX) activities decreased in D. salina and increased in A. minutum. The different enzymes responses between the two species indicated different mechanisms in their antioxidant system, and we deduced that A. minutum might have a higher efficiency for scavenging H2O2 than D. salina.

The management of underwater noise within the European Union's waters is a significant component (Descriptor 11) of the Marine Strategy Framework Directive (MSFD). The indicator related to continuous noise, is the noise levels in two one-third octave bands centered at 63Hz and 125Hz. This paper presents an analysis of underwater noise in the Celtic Sea, a heavy shipping area which also hosts the seasonal Ushant thermal front. In addition to the MSFD recommended frequency bands, the analysis was extended to lower and upper frequency bands. Temporal and spatial variations as well as the influence of the properties of the water column on the noise levels were assessed. The noise levels in the area had a high dynamic range and generally exceeded 100dB re 1μPa. Finally, the results highlighted that oceanic mooring must be designed to minimize the pseudo-noise and consider the water column physical properties.

Twenty-five surface sediments and one sediment core sample were collected from the study area. Grain size, major elements, and heavy metals were determined. The content of fine-grained sediments (silt and clay), as well as the concentrations of major elements and heavy metals, showed seaward decreasing trends, with high content in the coastal areas of the East China Sea (ECS) and south west of Jeju Island. Low enrichment factor (EF) and geoaccumulation index (Igeo) values were found, indicating that the ecological risk of heavy metals was low. The EF values obtained from the high-resolution sedimentary records of heavy metals in the Yangtze River Estuary could be divided into Stage 1 (1950s to the late 1970s) and Stage 2 (late 1970s to the current sampling day), which coincided with economic development of the Yangtze River Basin, implementation of environmental protection, and impoundment of the Three Gorges Dam.

A novel platform and procedure were developed to characterize the ignitability of Alaska North Slope (ANS) crude oil and its water-in-oil products with water content up to 60% at low temperatures (−20–0°C). Time to ignition, critical heat flux, in-depth temperature profiles were investigated. It was observed that a cold boundary and consequent low oil temperature increased the thermal inertia of the oil/mixture and consequently the time to sustained ignition also increased. As the water content in the ANS water-in-oil mixture increased, the critical heat flux for ignition was found to increase. This is mainly because of an increase in the thermal conductivity of the mixture with the addition of saltwater. The results of the study can be used towards design of ignition strategies and technologies for in situ burning of oil spills in cold climates such as the Arctic.

In this study an algal bloom event in fall 2013 in the Strait of Hormuz was thoroughly investigated using satellite remote sensing and hydrodynamic modeling. The motivation of this study is to deduce ambient conditions prior to and during the bloom outbreak and understand its trigger. Bloom tracking was achieved by sequential MODIS imagery and numerical simulations. Satellite observations showed that the bloom was initiated in late October 2013 and dissipated in early June 2014. Trajectories of bloom patches were simulated using a Lagrangian transport model. Model-based predictions of bloom patches' trajectories were in good agreement with satellite observations with a probability of detection (POD) reaching 0.85. Analysis of ancillary data, including sea surface temperature, ocean circulation, and wind, indicated that the bloom was likely caused by upwelling conditions in the Strait of Hormuz. Combined with numerical models, satellite observations provide an essential tool for investigating bloom conditions.

The average herded slick thickness, surface distribution and burning efficiency of a light crude oil were studied in ice-infested water to determine the effectiveness of a chemical herder in facilitating the in-situ burning of oil. Experiments were performed in a small scale (1.0m2) and an intermediate scale (19m2) setup with open water and 3/10, 5/10 and 7/10 brash ice coverages. The herded slick thicknesses (3–8mm) were ignitable in each experiment. The presence of ice caused fracturing of the oil during the herding process, which reduced the size of the herded slicks and, as a consequence, their ignitability, which in turn decreased the burning efficiency. Burning efficiencies relative to the ignited fraction of the oil were in the expected range (42–86%). This shows that the herder will be an effective tool for in-situ burning of oil when the ignitability issues due to fracturing of the oil are resolved.

Total mercury (Hg) was measured in coastal fishes from Southern New England (RI, USA), and Hg exposure was estimated for anglers and family members that consumed these resources. Fish Hg was positively related to total length (n = 2028 across 7 fish species), and interspecies differences were evident among legally harvestable fish. Many recreational anglers and their families experienced excessively high Hg exposure rates, which was attributed to the enriched Hg content of frequently consumed fishes. Specifically, 51.5% of participants in this study had Hg exposures exceeding the US EPA reference dose, including 50.0% of women of childbearing years. These results are noteworthy given that Hg neurotoxicity occurs in adults and children from direct and prenatal low-dose exposure. Moreover, this study underscores the need for geographic-specific research that accounts for small-scale spatial variations in fish Hg and dietary habits of at-risk human populations.

To achieve a better contaminant removal efficiency in a low-temperature and high-salt environment, two novel strains of cold- and salt-tolerant ammonia-oxidizing bacteria (AOB), i.e., Ochrobactrum sp. (HXN-1) and Aquamicrobium sp. (HXN-2), were isolated from the surface sediment of Liaohe Estuarine Wetland (LEW), China. The optimization of initial ammonia nitrogen concentration, pH, carbon–nitrogen ratio, and petroleum hydrocarbons (PHCs) to improve the ammonia-oxidation capacity of the two bacterial strains was studied. Both bacterial strains showed a high ammonia nitrogen removal rate of over 80% under a high salinity of 10‰. Even at a temperature as low as 15°C, HXN-1 and HXN-2 could achieve an ammonia nitrogen removal rate of 53% and 62%, respectively. The cold- and salt-tolerant AOB in this study demonstrated a high potential for ammonia nitrogen removal from LEW.

This study investigated the trace element bioaccumulation capacity of the Mediterranean seagrass Posidonia oceanica, and its suitability as a bioindicator of contamination in water and sediments. Results showed that P. oceanica leaves accumulate higher concentrations of Ni and Zn. Since P. oceanica regenerates its leaves periodically, the higher concentrations in aerial organs may suggest a “removal” strategy according to which P. oceanica accumulates greater concentrations of trace elements in its temporary organs. In turn, P. oceanica seems to adopt an exclusion strategy for toxic non-essential elements (As, Cr, Pb). Results showed also that P. oceanica organs are correlated with As, Cd, Cu, Ni, and Zn concentrations in sediments. No significant relationship was found between P. oceanica and water. This study showed that P. oceanica may adopt different tolerance strategies compared to mainland-rooted macrophytes, and its possible use as a bioindicator of trace elements in sediments should be considered.

Trace element concentration in the beach placer mining areas of Kanyakumari coast, South India was assessed. Sewage and contaminated sediments from mining sites has contaminated the surface sediments. Enrichment factor indicates moderately severe enrichment for Pb, minor enrichment for Mn, Zn, Ni, Fe and no enrichment for Cr and Cu. The Igeo values show higher concentration of Pb ranging in the scale of 3–4, which shows strong contamination due to high anthropogenic activity such as mining and terrestrial influences into the coastal regions. Correlation coefficient shows that most of the elements are associated with each other except Ni and Pb. Factor analysis reveals that Mn, Zn, Fe, Cr, Pb and Cu are having a significant loading and it indicates that these elements are mainly derived from similar origin. The cluster analysis clearly indicated that the mining areas are grouped under cluster 2 and non-mining areas are clustered under group 1.