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Occurrence, spatial deposition and footprint of polybrominated diphenyl ethers in surficial sediments of Bushehr peninsula, the Persian Gulf Full text
2016
Aghadadashi, Vahid | Mehdinia, Ali
The concentrations of polybrominated diphenyl ethers (PBDEs) were determined in the surficial sediments of Bushehr coasts, the Persian Gulf. Eighteen samples were collected from 6 sites at distances of 500, 1000 and 1500m from the coast. PBDEs were detected in all the samples, indicating their widespread occurrence in marine sediments of the studied area. BDE-209 and ∑7PBDEs were in the range of n.d. (not detected) to 6.29ngg−1 and n.d. to 0.62ngg−1 dw, respectively. The studied area can be classified as the region with the minimal contamination values reported globally as yet. The concentrations of PBDEs were lower than the Canadian benchmarks, and risk quotient assessments demonstrated low ecological risk. BDE-183 and then BDE-153 were the congeners with the highest detection frequencies in the stations, confirming extensive occurrence of Octa-mix in the studied area.
Show more [+] Less [-]Spatial and temporal analysis of the risks posed by polychlorinated biphenyl and metal contaminants in dab (Limanda limanda) collected from waters around England and Wales Full text
2016
Nicolaus, E.E Manuel | Wright, Serena R. | Bolam, Thi P.C. | Barber, Jonathan L. | Bignell, John P. | Lyons, Brett P.
The metals cadmium, mercury and lead, and the ICES7 CB levels were analysed in the common dab Limanda limanda to investigate whether concentrations of these determinants are at levels above established OSPAR assessment criteria around England and Wales. The results indicate that CB118 is above the OSPAR derived EAC at 22 out of 29 sampled stations, with 15 showing significant reductions. Cadmium is increasing significantly at six stations with two sites in the North Sea breaching corresponding OSPAR EAC. Mean results for all other PCBs and metals stayed below the EAC thresholds, with Hg concentrations even falling below BAC levels at South Eddystone located in the western English Channel. This study shows that PCBs banned over 20years ago are still found at concentrations in fish liver tissues which may pose a health risk to both the individual fish and their predators.
Show more [+] Less [-]An integrative biomarker approach to assess the environmental stress in the north coast of Shandong Peninsula using native oysters, Crassostrea gigas Full text
2016
Xie, Jia | Zhao, Yun | Wang, Qing | Wu, Huifeng | Teng, Jia | Yang, Dinglong | Cao, Ruiwen | Chen, Lizhu | Zhang, Yingjun | Li, Fei | Ji, Chenglong | Cong, Ming | Zhao, Jianmin
An integrative biomarker approach was employed to evaluate the environmental quality of the north coast of Shandong Peninsula along the southern Bohai Sea of China, where pollution is an imminent threat due to rapid urbanization and industrialization. A battery of biomarkers and the metal bioaccumulation in tissues of native oyster Crassostrea gigas were measured under field conditions. Integrative biomarker index (IBR) and metal body burden were calculated to differentiate the pollution status of seven sampling sites. According to our results, Xinzhuang (XZ) site was the most severely contaminated, with the highest IBR value of 3.58, while the lowest IBR value (0.04) was obtained at Penglai (PL). Such an integrated biomarker approach was proved as a useful method for environmental quality assessment in the study area.
Show more [+] Less [-]Anthropogenic microfibres pollution in marine biota. A new and simple methodology to minimize airborne contamination Full text
2016
Torre, Michele | Digka, Nikoletta | Anastasopoulou, Aikaterini | Tsangaris, Catherine | Mytilineou, Chryssi
Research studies on the effects of microlitter on marine biota have become more and more frequent the last few years. However, there is strong evidence that scientific results based on microlitter analyses can be biased by contamination from air transported fibres. This study demonstrates a low cost and easy to apply methodology to minimize the background contamination and thus to increase results validity. The contamination during the gastrointestinal content analysis of 400 fishes was tested for several sample processing steps of high risk airborne contamination (e.g. dissection, stereomicroscopic analysis, and chemical digestion treatment for microlitter extraction). It was demonstrated that, using our methodology based on hermetic enclosure devices, isolating the working areas during the various processing steps, airborne contamination reduced by 95.3%. The simplicity and low cost of this methodology provide the benefit that it could be applied not only to laboratory but also to field or on board work.
Show more [+] Less [-]Benthic assemblages associated with native and non-native oysters are similar Full text
2016
Zwerschke, Nadescha | Emmerson, Mark C. | Roberts, Dai | O'Connor, Nessa E.
Invasive species can impact native species and alter assemblage structure, which affects associated ecosystem functioning. The pervasive Pacific oyster, Crassostrea gigas, has been shown to affect the diversity and composition of many host ecosystems. We tested for effects of the presence of the invasive C. gigas on native assemblages by comparing them directly to assemblages associated with the declining native European oyster, Ostrea edulis. The presence of both oyster species was manipulated in intertidal and subtidal habitats and reefs were constructed at horizontal and vertical orientation to the substratum. After 12months, species diversity and benthic assemblage structure between assemblages with C. gigas and O. edulis were similar, but differed between habitats and orientation, suggesting that both oyster species were functionally similar in terms of biodiversity facilitation. These findings support evidence, that non-native species could play an important role in maintaining biodiversity in systems with declining populations of native species.
Show more [+] Less [-]Spatial variability in persistent organic pollutants and polycyclic aromatic hydrocarbons found in beach-stranded pellets along the coast of the state of São Paulo, southeastern Brazil Full text
2016
Taniguchi, Satie | Colabuono, Fernanda I. | Dias, Patrick S. | Oliveira, Renato | Fisner, Mara | Turra, Alexander | Izar, Gabriel M. | Abessa, Denis M.S. | Saha, Mahua | Hosoda, Junki | Yamashita, Rei | Takada, Hideshige | Lourenço, Rafael A. | Magalhães, Caio A. | Bícego, Márcia C. | Montone, Rosalinda C.
High spatial variability in polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organochlorine pesticides, such as DDTs, and polybrominated diphenylethers was observed in plastic pellets collected randomly from 41 beaches (15 cities) in 2010 from the coast of state of São Paulo, southeastern Brazil. The highest concentrations ranged, in ng g−1, from 192 to 13,708, 3.41 to 7554 and <0.11 to 840 for PAHs, PCBs and DDTs, respectively. Similar distribution pattern was presented, with lower concentrations on the relatively less urbanized and industrialized southern coast, and the highest values in the central portion of the coastline, which is affected by both waste disposal and large port and industrial complex. Additional samples were collected in this central area and PCB concentrations, in ngg−1, were much higher in 2012 (1569 to 10,504) than in 2009/2010 (173 to 309) and 2014 (411), which is likely related to leakages of the PCB commercial mixture.
Show more [+] Less [-]Time series analysis of aerosol optical depth over New Delhi using Box–Jenkins ARIMA modeling approach Full text
2016
Taneja, Kanika | Aḥmad, Shamshād | Kafīl, Aḥmad | Attri, S.D.
The present study focuses on the application of stochastic modeling technique in analyzing the future trends of aerosol optical properties. For this, the Box–Jenkins ARIMA (Autoregressive Integrated Moving Average) model has been used for simulating the monthly average Aerosol Optical Depth (AOD550 nm) retrieved from Terra MODIS (Moderate Resolution Imaging Spectroradiometer) over New Delhi, the urban capital of India. The satellite dataset has been collected for a period of ten years from 2004 to 2014. The analysis of autocorrelation function indicates existence of seasonality in the AOD time series. Several seasonal ARIMA models have been generated and their validation has been verified by assessing various estimation parameters, using the Statistical Package for the Social Sciences (SPSS, version 20). After rigorous evaluation of the selected models, the ARIMA (1,0,0)x(0,1,2)12 is identified as the best fit model w.r.t. measures of goodness-of-fit like Stationary R-square (0.530), R-square (0.674), Root Mean Squared Error (0.128); Mean Absolute Error (0.095); Mean Absolute Percentage Error (16.942); and normalized Bayesian Information Criteria (−3.941). The selected models have been further used to forecast AOD values for the year 2014 at 95% level of confidence. However, the ARIMA (1,0,0)x(2,1,1)12 model is found to have minimum forecasting error, calculated as Mean Percentage Error (0.220). As the difference in BIC of both the models is minimal (0.046), so both the models have been considered as best fit models and utilized for prediction of AOD. Satisfactory results have been obtained using the selected ARIMA models, suggesting that a simplistic modeling technique for determining the future values of AOD is feasible.
Show more [+] Less [-]Public awareness and attitudes towards marine protection in the United Kingdom Full text
2016
Hawkins, Julie P. | O'Leary, Bethan C. | Bassett, Nicola | Peters, Howard | Rakowski, Sarah | Reeve, Georgina | Roberts, Callum M.
Public perception research evaluating awareness and attitudes towards marine protection is limited in the United Kingdom (UK) and worldwide. Given public opinion can help drive policy and affect its successful delivery we conducted nationwide surveys in 2005, 2010 and 2015 to assess public knowledge of UK (England, Scotland and Wales) sea ‘health’ and management. Respondents from all three surveys were relatively pessimistic about sea ‘health’, perceiving this as poor-fair and largely in decline. Enthusiasm for marine conservation was high with almost two-thirds of respondents in each survey wanting >40% of UK seas highly protected from fishing and damaging activities. In 2015 there was considerable dissatisfaction with the rate of progress in Marine Conservation Zone designation and over three-quarters of respondents considered dredging and trawling to be inappropriate in protected areas, contrary to management. The UK government and devolved administrations need to better align future conservation and management with public expectations.
Show more [+] Less [-]Heavy metal accumulation in surface sediments at the port of Cagliari (Sardinia, western Mediterranean): Environmental assessment using sequential extractions and benthic foraminifera Full text
2016
Schintu, Marco | Marrucci, Alessandro | Marras, Barbara | Galgani, François | Buosi, Carla | Ibba, Angelo | Cherchi, A. (Antonietta)
Superficial sediments were taken at the port of Cagliari (Sardinia, Italy), which includes the oil terminal of one of the largest oil refineries in the Mediterranean. Significant trace metal concentrations were found in the whole port area. Sequential extraction of metals from the different sediment fractions (BCR method) showed a higher risk of remobilisation for Cd, which is mostly bound to the exchangeable fraction. Foraminiferal density and richness of species were variable across the study area. The living assemblages were characterized by low diversity in samples collected close to the port areas. Ammonia tepida and bolivinids, which were positively correlated with concentrations of heavy metals and organic matter content, appeared to show tolerance to the environmental disturbance. The sampling sites characterized by the highest values of biotic indices were located far from the port areas and present an epiphytic and epifaunal biocoenosis.
Show more [+] Less [-]Changes to nitrate isotopic composition of wastewater treatment effluent and rivers after upgrades to tertiary treatment in the Narragansett Bay watershed, RI Full text
2016
Schmidt, Courtney E. | Robinson, Rebecca S. | Fields, Lindsey | Nixon, Scott W.
Due to nitrogen load reduction policies, wastewater treatment facilities (WWTFs) have upgraded to tertiary treatment — where denitrification reduces and removes nitrogen. Changes to the stable isotopic composition of nitrate inputs after upgrades or how it transfers to the estuary have not been assessed in Rhode Island. We investigate whether these upgrades impact the isotopic signature of nitrate inputs to Narragansett Bay. Samples from rivers and WWTFs discharging to Narragansett Bay characterize the anthropogenic source nitrate (NO3−) isotopic composition (δ15N–NO3− and δ18O–NO3−) and temporal variability. At one WWTF, tertiary treatment increased effluent nitrate δ15N–NO3− and δ18O–NO3− values by ~16‰. Riverine values increased by ~4‰, likely due to the combination of decreases in N and upgrades. Combined river and WWTF flux-weighted isotopic compositions showed enriched values and an amplitude reduction in monthly variability. When seasonal isotopic means are significantly different from other sources, δ15N–NO3− may be a useful tracer of inputs.
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