We investigated the bioavailability, mobility, and origin of heavy metals present in sediments from the Anzali Wetland. Chemical speciation of the metals was performed according to the Tessier method. Results indicated that Cd and As showed the highest level of bioavailability, whereas Cr showed the lowest level. Cr, Co, and V were shown to have a terrestrial origin. The metal As was mostly found in the reducible fraction (F3), whereas other metals were highest in the residual phase. The levels of Co present in the oxidizable fraction (F4); Pb and Cd present in the carbonate fraction (F2); and the other metals present in the exchangeable fraction (F1) were found to be the lowest. On the basis of the Risk Assessment Code of metals, Cd at most stations, As and Ni at some stations, and Zn at one station revealed to have a moderate risk. Co and Pb were found to have a low risk at all stations. Considering Pollution Load Index, stations 2 and 3 were classified as moderately polluted and the remaining stations were unpolluted. As suggested by enrichment factor analysis, As was moderately enriched and other metals had a deficiency to minimal enrichment at all the stations.

High-risk contaminants, OCPs and PCBs, were investigated in marine fish from the Adriatic Sea, from which retail fish in Croatia is commonly sourced. The pollutant levels in sardine, horse and chub mackerel, anchovy and round sardinella were analysed based on a two-year sampling and the joint use of generally accepted statistics and advanced clustering methods − self-organizing maps (SOM) and decision tree analysis (DT). Both the SOM and DT suggested fish mass and length rather than fat along with α-HCH, p,p′-DDT, PCB-74 and PCB-189 to cause variable pollutant uptake among species. Main distinctions of sardines occur in coastal and off coast regions rather than in a particular fishing zone and they are associated with both fish characteristics, levels of γ-HCH and PCBs: −60, −105, −150, −170, and −189. The results, mutually compatible or in agreement, could be useful for the design and implementation of the abatement strategies of fish pollution.

Mercury (Hg) and its bioaccumulation are important in evaluating the health risk through fish consumption. In the Marano and Grado Lagoon a historical contamination originating from both mining and industrial sources is present.In this study the Hg levels in the grass goby and the protective effect of selenium (Se) were determined as a function of size, sex, sampling sites and season.Mercury often exceeded the limit for commercialisation, whereas Se was mostly constant being homeostatically regulated.The mean Se/Hg molar ratio showed about 40% of data >1.0 and the HBVSe index was on average equal to 0.0. Thus, grass goby of this area is not a Se source food indicated for pregnant and/or breastfeeding women, but its occasional consumption would appear to have no contraindications if integrated with other Se rich foods: the ingestion of about 10 fish fillets per week can be safely consumed by adults.

This study's objectives were to evaluate the elements degree of contamination in the Tajan River and the status of contamination in this river for future ecotoxicology studies. Based on geo-accumulation index (Igₑₒ) and contamination factor (CF) indices, Cr, Mn, Fe, Ci, Ni and Zn showed low contamination levels at all stations, while Se showed a very high degree of contamination. Potential ecological risk factor (Eᵣⁱ) and risk index (RI) indices values showed low ecological risk for the river, and this was confirmed by the pollution load index (PLI) results as well as a comparison of the concentrations of these elements with the mean values of the earth's crust and sediments worldwide. Overall, the results showed that the river cannot be regarded as a contaminated river with respect to the elements studied (with the exception of selenium and arsenic) for ecotoxicology studies, but can be considered a reference river.

A wide range of ecological and environmental factors influence metal bioaccumulation in fish. Studies of mercury and other metal contaminants in invasive Indo-Pacific lionfish are limited, yet consumption of the invasive predator is increasingly utilized as a management strategy. In this study, we examined the effects of body size, body condition, sex, trophic level, carbon source, diet, depth and capture location on mercury concentrations in lionfish collected from Curaçao. In addition, we examined whether or not a local petroleum refinery is the source of metal contamination in lionfish. Mercury concentrations ranged from 0.008 to 0.106 mg/kg and we found no effect of the petroleum refinery on metal bioaccumulation in lionfish. Low concentrations of metal contaminants indicate lionfish from Curaçao are safe for human consumption.

The gastrointestinal tract (GIT) of fish is a target of contaminants since it can absorb these substances. We evaluated the morphophysiological alterations in the GIT of Sphoeroides testudineus collected in two estuaries presenting differences in their environmental quality (NIA and IA). The intestine was analyzed for histological and neuronal changes; liver and gills for biochemical markers; muscle tissues for neurotoxicity and peripheral blood for genotoxic damage. The results showed alterations in the GIT of the animals collected in the IA, such as muscle tunica and goblet cell density reduction, increased intraepithelial lymphocytes density and changes in neuronal density. Furthermore, changes were observed in MTs and LPO in the gills. Thus, we suggest that TGI is functioning as a barrier that responds to ingested contaminants, in order to reduce their absorption and translocation. Thus, alterations in morphophysiological and enteric neurons in S. testudineus can be used as biomarkers of environmental contamination.

Increasing maritime traffic in the Arctic has heightened the oil spill-related risks in this highly sensitive environment. To quantitatively assess these risks, we need knowledge about both the vulnerability and sensitivity of the key Arctic functional groups that may be affected by spilled oil. However, in the Arctic these data are typically scarce or lacking altogether. To compensate for this limited data availability, we propose the use of a probabilistic expert elicitation methodology, which we apply to seals, anatids, and seabirds. Our results suggest that the impacts of oil vary between functional groups, seasons, and oil types. Overall, the impacts are least for seals and greatest for anatids. Offspring seem to be more sensitive than adults, the impact is greatest in spring, and medium and heavy oils are the most harmful oil types. The elicitation process worked well, yet finding enough skilled and motivated experts proved to be difficult.

In coastal waters the identification of sources, trajectories and deposition sites of marine litter is often hampered by the complex oceanography of shallow shelf seas. We conducted a multi-annual survey on litter at the sea surface and on the seafloor in the south-eastern North Sea. Bottom trawling was identified as a major source of marine litter. Oceanographic modelling revealed that the distribution of floating litter in the North Sea is largely determined by the site of origin of floating objects whereas the trajectories are strongly influenced by wind drag. Methods adopted from species distribution modelling indicated that resuspension of benthic litter and near-bottom transport processes strongly influence the distribution of litter on the seafloor. Major sink regions for floating marine litter were identified at the west coast of Denmark and in the Skagerrak. Our results may support the development of strategies to reduce the pollution of the North Sea.

Modified clay (MC) removed harmful algae Karenia mikimotoi effectively, and significantly inhibited residual algae growth. Hydrogen peroxides (H₂O₂) and malondialdehyde (MDA) contents of K. mikimotoi increased significantly after treatment, indicating that MC induced oxidative stress. Moreover, H₂O₂ content was significantly correlated with cell density, indicating that increased reactive oxygen species (ROS) were likely responsible for the growth inhibition. Further investigation showed that MC caused damage to photosynthesis of residual algae, indicated by decreased maximal photochemical efficiency (Fᵥ/Fₘ) and performance index (PIABS). The density of reaction center (RC) decreased, indicating that MC induced partially inactivated RCs, then caused residual activated RCs to be over-excited. The electron transport chain was also blocked, indicated by increased WK and VJ, and decreased Sₘ. These effects of photosystem II (PSII) were supposed to be the main contributors to ROS over-accumulation during photosynthesis. Overall, treatment with MC is an appropriate method for controlling K. mikimotoi blooms.

Microplastics (MPs) are generated from plastic and have negative impact to our environment due to high level of fragmentation. They can be originated from various sources in different forms such as fragment, fiber, foam and so on. For detection of MPs, many techniques have been developed with different functions such as microscopic observation, density separation, Raman and FTIR analysis. Besides, due to ingestion of MPs by wide range of marine species, research on the effect of this pollution on biota as well as human is vital. Therefore, we comprehensively reviewed the occurrence and distribution of MPs pollution in both marine and freshwater environments, including rivers, lakes and wastewater treatment plants (WWTPs). For future studies, we propose the development of new techniques for sampling MPs in aquatic environments and biota and recommend more research regarding MPs release by WWTPs.