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Isotopic evidence for the shift of nitrate sources and active biological transformation on the western coast of Guangdong Province, South China
2019
Lao, Qibin | Chen, Fajin | Liu, Guoqiang | Chen, Chunqing | Jin, Guangzhe | Zhu, Qingmei | Wei, Chunlei | Zhang, Chunhua
Dual isotope nitrate (NO₃⁻) analysis was performed on the western coast of Guangdong Province to investigate seasonal changes in the main nitrate sources and their biogeochemical processing, which are due to the rapid development of the local economy. In the nearshore area, significant seasonal variations of nitrate sources occurred. The dominant nitrate sources, originating from manure and sewage, suggested that the nitrate along the west coast of Guangdong Province was mainly influenced by local cities despite the westward flow of diluted Pearl River water. In the offshore area, the nitrate loss in the upper and mid water during both two seasons mainly caused by phytoplankton assimilation, whereas coupled nitrification-denitrification could be responsible for the nitrate loss in the bottom waters during summer. Our results suggest that, with the rapid development of local economy, the nitrate sources in the coastal area have shifted to manure and sewage from the local cities.
Show more [+] Less [-]Is this your glitter? An overlooked but potentially environmentally-valuable microplastic
2019
Tagg, Alexander S. | Ivar do Sul, Juliana A.
As microplastic pollution evolved to a well-established research field, microplastic scientists started to explore new avenues in the field. Yet, while a multitude of different types of microplastics (microbeads, fibres, fragments) have been well-documented in microplastic literature, our analysis of this literature shows that glitter particles have been overlooked by the field. However, due to the presence of glitter-based research in forensic science, we explore the idea that glitter may have the potential to act as “flag items” - or markers – of a likely source, due to the often complex and individual composition of glitter particles compared to traditional microplastics, such as microbeads. As such, this article demonstrates glitter has insofar been overlooked as a microplastic particle, and demonstrates that glitter may have an important role in explaining microplastic pollution dynamics from source to sink.
Show more [+] Less [-]Microplastic pollution in the sediments of Sidi Mansour Harbor in Southeast Tunisia
2019
Chouchene, Khawla | da Costa, João Pinto | Wali, A. | Girão, Ana V. | Hentati, Olfa | Duarte, Armando C. | Rocha-Santos, Teresa | Ksibi, Mohamed
Despite the increasing interest in microplastic (MP) research, the accurate prevalence, distribution and fate of these materials in the environment is yet poorly known and, consequently, a focus of debate. Hence, to better ascertain the presence of microplastics in specific environments, samples from 35 random sites distributed across a 4200-meter long section from the area of Sidi Mansour, Sfax-Tunisia, were collected and analyzed. MPs were extracted, digested with potassium hydroxide and dyed with Eosin B, for visual microscopy counting and sorting. Polymer composition and surface morphology were identified by FTIR-ATR spectroscopy and SEM microscopy. Total abundances ranged from 252 to-5332 particles per m² where fragments and granules were the most frequent types of microplastics. These findings highlight the considerable presence of these materials in the studied harbor region and underscore the density dependence on the distribution and occurrence of MPs and how these tend to accumulate in the sandy sediments.
Show more [+] Less [-]What nutrient sources support anomalous growth and the recent sargassum mass stranding on Caribbean beaches? A review
2019
Oviatt, Candace A. | Huizenga, Kristin | Rogers, Caroline S. | Miller, W Jeff
Since 2011, tropical beaches from Africa to Brazil, Central America, and the Caribbean have been inundated by tons of sargassum seaweed from a new equatorial source of pelagic sargassum in the Atlantic. In recent years the extraordinary accumulations of sargassum make this a nuisance algal bloom for tropical coasts. In 2018 satellite data indicated floating mats of sargassum that extended throughout the Caribbean to the northeast coast of Brazil with the highest percent coverage over the water yet recorded. A literature review suggests that Atlantic equatorial recirculation of seaweed mats combined with nutrients from several possible sources may be stimulating the growth and accumulations of sargassum. In the western equatorial recirculation area, new nutrient sources may include Amazon River floods and hurricanes; in the eastern equatorial recirculation area, nutrient sources that could sustain the sargassum blooms include coastal upwelling and Congo River freshwater and nutrients.
Show more [+] Less [-]Long term monitoring of metal pollution in sediments as a tool to investigate the effects of engineering works in estuaries. A case study, the Nerbioi-Ibaizabal estuary (Bilbao, Basque Country)
2019
Garmendia, Marina | Fdez-Ortiz de Vallejuelo, Silvia | Liñero, Olaia | Gredilla, Ainara | Arana, Gorka | Soto, Manuel | de Diego, Alberto
The Nerbioi-Ibaizabal estuary (Bilbao, Basque Country) suffered an important input of contaminants, including metals and metalloids, between 1875 and 1975. We collected sediments in the tidal part of the river in January 2018 and measured the concentrations of 27 elements in them. At that time, two important construction works were taking place in the area: the extension of the commercial port and the opening of long semi-closed channel. Comparing the current metallic hotspots with the geographical distribution of elements in previous years (2009, 2010 and 2014) showed us that these works seem to have significantly influenced the distribution of toxic elements in the estuary, even if the critical point of the second one is still to arrive with the inundation of the connection to the mainland. Long term pollution monitoring reveals as a powerful tool to check the effects of ongoing engineering works in estuarine environments.
Show more [+] Less [-]Establishment of a NORM baseline for selected seafood in the Gulf of Mexico
2019
Wilson, Charles A. | Hamideh, Amin M. | Wang, Wei-Hsung
Naturally occurring radioactive material was characterized in selected seafood samples from three areas in the Gulf of Mexico. Relatively desirable and abundant fish such as Red Snapper, Red Drum, Northern Whiting, and Spotted Trout as well as oysters were collected and analyzed using gamma spectroscopy to determine the concentration of ²²⁸Ra, ²²⁶Ra, and ⁴⁰ K. Average total activity concentration from these radionuclides were 0.9 ± 0.6, 1.6 ± 1.2, and 132 ± 57 Bq kg⁻¹ respectively, in the edible portion of wet weight samples. The results were consistent with previous studies for other bodies of water. A small but statistically significant increase in ²²⁶Ra was found in comparison to similar research performed 20 years prior. These measurements provide a reasonable baseline for the examined species from the Gulf of Mexico.
Show more [+] Less [-]Bioturbation potential of a macrofaunal community in Bohai Bay, northern China
2019
Zhang, Qingtian | Li, Jing | Hu, Guikun | Zhang, Zhe
The bioturbation potential of macrobenthos communities (BPc) is an important parameter in marine ecology. Based on macrobenthos field surveys, BPc values were estimated in Bohai Bay, China. The horizontal distribution of BPc values changed across seasons while showing a certain level of continuity over time. The maximum BPc value was recorded in summer while the minimum occurred in winter. Although only a few environmental variables showed a statistically significant (p < 0.05) correlation with BPc, about 20 environmental variables exhibited a moderate correlation with BPc (0.3 < r < 0.5). The depth of the redox potential discontinuity (RPD) measured in situ changed across seasons, and the biogenic mixing depth values derived from the BPc index exhibited a relationship with the lowest RPD depth measurements. Our results suggest that the RPD depth can be predicted from BPc values, thereby showcasing a useful application of the BPc index in marine benthic pollution and environmental management research.
Show more [+] Less [-]137Cs and 239+240Pu in the Bohai Sea of China: Comparison in distribution and source identification between the inner bay and the tidal flat
2019
Zhuang, Qifan | Li, Guosheng | Wang, Fu | Tian, Lizhu | Jiang, Xingyu | Zhang, Kexing | Liu, Geng | Pan, Shaoming | Liu, Zhiyong
We investigated artificial radionuclides (²³⁹⁺²⁴⁰Pu and ¹³⁷Cs) in surface sediments and sediment cores collected from the Bohai Bay and the tidal flat of the Liaodong Bay, China. Increasing trends for ²³⁹⁺²⁴⁰Pu activities and ²⁴⁰Pu/²³⁹Pu atom ratios (˃0.18) were observed from land to sea and from north to south in the Bohai Bay. This spatial pattern implied that the scavenging process between riverine sediments and Pacific Proving Ground (PPG) source Pu transported by the currents such as Yellow Sea Warm Current had occurred in the Bohai Bay. In contrast, relatively lower ²⁴⁰Pu/²³⁹Pu atom ratios in the tidal flat of Liaodong Bay were due to the mixing process between more global out and less PPG source Pu. The riverine Pu contributions to the total global fallout Pu in the Haihe River (32.8%) were much lower than those in the Yangtze River estuary (77%–80%), indicating better soil conservation in the Haihe River Catchment.
Show more [+] Less [-]Are Mediterranean Marine Protected Areas sheltered from plastic pollution?
2019
Liubartseva, S. | Coppini, G. | Lecci, R.
Comparisons of six selected Mediterranean MPAs were conducted to find similarities and site-specific differences in coastline fluxes and sources of plastic marine litter. Output from the recently developed 2D Lagrangian model for the Mediterranean was post-processed to study (1) the National Park of ses Salines d’Eivissa i Formentera, (2) Nature Reserve of Bouches de Bonifacio, (3) North-East Malta MPA, (4) Specially Protected Area of Porto Cesareo, (5) Community Importance Site of Torre Guaceto, and (6) Ethniko Thalassio Parko Alonnisou Voreion Sporadon. Model coastline fluxes of plastic ranged from 0.4 to3.6 kg (km day)−1, which is relatively low compared to the average flux of 6.2 ± 0.8 kg (km day)−1 calculated over the Mediterranean 2013–2017. Shipping was identified as a major source of plastic litter in all MPAs studied, contributing 55%–88% of total plastic. Site-specific rankings of the top 5 land-based plastic sources revealed that sea surface kinematics control plastic drift.
Show more [+] Less [-]Anthropogenic spherules in Zuari estuary, south west coast of India
2019
Shetye, Suhas S. | Rudraswami, N.G. | Nandakumar̄, Ke. | Manjrekar, Saiprasad
In this study we report silica rich anthropogenic spherules from the marine environment. We found spherical, dumbbell, teardrop and fused spherules in Zuari estuary (near the Dona paula jetty), south west coast of India. The spherules were composed of SiO2 (69.8%), Na2O (13.2%), CaO (8.8%), MgO (3.8%), and traces of Al2O3, and FeO. Their high Na and Ca contents rules out the possibility of being an impact spherule or microtektite, or anthropogenic spherules coming from fly ash. Their elemental composition suggests that these are glass micro beads that have many applications including production of road and pavement marking materials, such as traffic paints. Considering that the glass micro beads are known to have high concentrations of Pb, As, and Sb that can leach into the marine environment, this study also raises questions regarding the impact of such spherules on marine biota, and highlights the need for further detailed study.
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