The concentrations of 21 potentially toxic elements (PTEs) were determined in the tissues of Octopus hubbsorum from three locations along the Gulf of California coast: two near Santa Rosalia (SR), a site with historical metal contamination, and one in La Paz Bay, a reference site. Concentrations of Cd, Co, Cr, Mn, Ni, Pb, and Zn in octopus from the two SR sites were higher than those from the reference site, reflecting the higher sediment concentrations at the mining-impacted locations. The highest bioaccumulation and biomagnification of elements was found in digestive gland and branchial hearts, while the lowest was observed in the mantle, where the mean concentration of PTEs did not exceed international standards for human consumption of octopus. This study found elevated PTEs in octopus from sites with high metal contamination, and presents the first data on these elements in octopus from the Gulf of California.

It has been shown that the current approach to the assessment of contamination in the sediments obtained during the dredging works in the Baltic countries indicates the presence of "non-contaminated" dredged material. The concentration limits of heavy metals, Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated Biphenyls (PCBs) have been exceeded only in 1% of the samples obtained during the dredging works (2005–2015) within the Polish coastal zone. After 2008, no contaminated sediments have been found. Also, in the remaining Baltic countries, sediments are very rarely contaminated. As a result of this assessment, the sediments can be stored in the sea or have a practical application. However, it has been questioned whether the large cost of determining the numerous chemical parameters is justified. It has been proposed to carry out simple screening tests. Following the preliminary screening, the decision on more detailed (and expensive) chemical tests of individual pollutants would be made.

Dredged sediments have different physical and chemical characteristics compared with the sediments in place, which generates multiple effects on the environment.In this study, we show that the sampling strategy used to monitor the effects of dredge spoil deposition on the surrounding environment can lead to different interpretations. It appears that sediment sample replicates may or may not be necessary, depending on the studied area, the prevailing environmental forcings before sediment sampling and the combination of these two factors. The proposed modus operandi allows us to optimize both the confidence on the obtained results and the cost of the sediment studies (sampling and laboratory analyses). The results are based on the sediment fine fraction, which is considered as a key environmental component due, for example, to its strong association with the structure of benthic faunal communities as well as its role in the build-up of pollutants.

Surface water samples from the environmental continuum spanning rivers (Petrohue, Cochamo, Puelo), fjord (Reloncaví), and the inner sea of Chiloé in Chilean Patagonia were analyzed to estimate concentration and distribution of dissolved Organochlorine pesticides (OCPs). High concentrations of HCHs, DDTs and endosulfan found in surface waters from rivers suggest that rivers are the major source of dissolved OCPs to coastal marine ecosystems. We interpret variations in the distribution and concentration as an apparent oscillation between rain and snow-scavenging processes that might determine the type of OCPs that can be preferentially deposited on mountains, glaciers, rivers, estuaries, and finally transferred to the marine realm. Predominance of α-HCH, γ-HCH, p,p′-DDE and α-endosulfan compounds suggest that the main deposition mechanism of OCPs to the Chilean Patagonia is rain scavenging. Snow and rain can be additional sources of OCPs that must be considered for future studies in fjord systems in Chilean Patagonia.

This study presents data on the marine litter occurrence in the stomachs of fish species living in different marine habitats for the Adriatic and NE Ionian Sea macro-region. “Macro-litter” was examined in 614 specimens belonging to 11 species, while micro-litter in 230 specimens belonging to 7 species. The study highlights for the first time the presence of litter in the stomachs of the fish species Citharus linguatula. The occurrence of “macro-litter” in the guts of fish was <3% in both the NE Ionian and N Adriatic but reached 26% in the S Adriatic Sea. Micro-litter occurrence was 40 for the NE Ionian and increased to 87% in the N Adriatic (Slovenian Sea). The ingested “macro” and micro-litter differed among the areas. The marine habitat was found to affect the “macro”-litter ingestion but not the micro-litter.

Estrogenic pollution has aroused great concern for its adverse effects on marine organisms. This study aimed to establish biomarker-based methods for detecting environmental estrogens using vitellogenin (Vtg) of teleost fishes inhabiting coastal areas of China. Firstly, Vtgs in marbled flounder (Pseudopleuronectes yokohamae), black rockfish (Sebastes schlegelii) and fat greenling (Hexagrammos otakii) were purified, characterized and used to prepare antibodies. Then, Vtg ELISA for each species was developed using purified Vtg and its antibody. Marbled flounder Vtg ELISA had a working range of 3.9–500 ng/mL and a detection limit of 2.1 ng/mL, and black rockfish Vtg ELISA had strong cross-reactivity with marbled flounder Vtg. Furthermore, Vtg induction in male marbled flounder exposed to pentadecafluorooctanoic acid (PFOA) was measured by developed ELISA. Plasma Vtg concentrations were significantly increased with PFOA concentrations in seawater and fish muscle. Therefore, Vtg ELISAs for these species might be useful tools for monitoring marine environmental estrogens.

This study highlights an efficient sample pre-treatment method for preconcentration and detection of chloramphenicol in marine water using molecularly imprinted solid-phase extraction (MISPE). Chloramphenicol molecularly imprinted microspheres were prepared and evaluated on the base of morphology, capacity and selectivity. The imprinted microspheres exhibited specific recognition and high retention capability to chloramphenicol and were applied as special solid-phase extraction adsorbents. An off-line MISPE protocol has been optimized and a creative analytical method coupled to HPLC-DAD was successfully developed for the cleanup and determination of chloramphenicol in seawater samples. Method performance was satisfactory with recoveries ranging from 81 to 90% and relative standard deviation (RSD) was <4.93% (n = 3). Accuracy of the method was assessed at three spiking concentration levels and the limit of detection was 5 ng L⁻¹. Finally, five seawater samples from Jiaozhou Bay of China were determined and the results showed that there was no chloramphenicol detected.

Monitoring efforts are required to understand the sources, distribution and abundance of microplastic pollution. To verify the abundance of microplastics along the Tuscan coastal waters (Italy), water-column and surface samples were collected in two seasons across four transects at different distances to the coast (0.5, 5, 10 and 20 km), within the implementation of the European Marine Strategy Framework Directive. The results show an average concentration of 0.26 items/m³ in the water-column samples and 41.1 g/km² and 69,161.3 items/km² of floating microplastics, with an increase with the distance to the coast The seasonality and the sampling area do not affect the abundance of microplastics. The most abundant size class is 1–2.5 mm as fragments and sheets suggesting that fragmentation of larger polyethylene and polypropylene items could be the main source of microplastics. These data represent the application of a harmonized protocol to make the data on microplastics comparable and reliable.

Research science used to inform public policy decisions, herein defined as “Policy-Science”, is rarely subjected to rigorous checking, testing and replication. Studies of biomedical and other sciences indicate that a considerable fraction of published peer-reviewed scientific literature, perhaps half, has significant flaws. To demonstrate the potential failings of the present approaches to scientific Quality Control (QC), we describe examples of science associated with perceived threats to the Great Barrier Reef (GBR), Australia. There appears a serious risk of efforts to improve the health of the GBR being directed inefficiently and/or away from the more serious threats. We suggest the need for a new organisation to undertake quality reviews and audits of important scientific results that underpin government spending decisions on the environment. Logically, such a body could also examine policy science in other key areas where governments rely heavily upon scientific results, such as education, health and criminology.

Antifouling paints are environmentally risk assessed based on their biocidal release rates to the water phase. In situ release rates of copper (Cu) and zinc (Zn) were derived for five commercial paints in two recreational marinas with different salinities (5 and 14 PSU) using an X-Ray Fluorescence spectrometer (XRF). Salinity was found to significantly affect the Cu release, with twice the amount of Cu released at the higher salinity, while its influence on the Zn release was paint-specific. Site-specific release rates for water bodies with salinity gradients, e.g. the Baltic Sea, are therefore necessary for more realistic risk assessments of antifouling paints. Furthermore, the in situ release rates were up to 8 times higher than those generated using standardized laboratory or calculation methods. The environmental risk assessment repeated with the field release rates concludes that it is questionable whether the studied products should be allowed on the Swedish market.