Refine search
Results 1631-1640 of 4,935
Assessment of the metal contamination evolution in the Loire estuary using Cu and Zn stable isotopes and geochemical data in sediments Full text
2019
Araújo, Daniel F. | Ponzevera, Emmanuel | Briant, Nicolas | Knoery, Joël | Sireau, Teddy | Mojtahid, Meryem | Metzger, Edouard | Brach-Papa, Christophe
Assessment of the metal contamination evolution in the Loire estuary using Cu and Zn stable isotopes and geochemical data in sediments Full text
2019
Araújo, Daniel F. | Ponzevera, Emmanuel | Briant, Nicolas | Knoery, Joël | Sireau, Teddy | Mojtahid, Meryem | Metzger, Edouard | Brach-Papa, Christophe
In this work, a multi-elemental approach combining Cu and Zn stable isotopes is used to assess the metal contamination evolution in the Loire estuary bulk sediments. Elemental geochemical data indicate an increase of metal concentrations from the beginning of the industrial period peaking in the 1990s, followed by an attenuation of metal contamination inputs to the estuary. Zinc isotope compositions suggest a binary mixing process between Zn derived from terrigenous material and multi-urban anthropogenic sources. Copper isotope systematics indicate a single natural dominant source represented by weathered silicate particles from soils and rocks. This work demonstrates the applicability of Zn isotopes to identify anthropogenic Zn sources in coastal systems, even under a low to moderate degree of contamination. Further studies are required to constrain Cu sources and to elucidate possible effects of grain-size and mineralogy in the Cu isotope composition of sediment in the Loire estuary.
Show more [+] Less [-]Assessment of the metal contamination evolution in the Loire estuary using Cu and Zn stable isotopes and geochemical data in sediments Full text
2019
Ferreira Araujo, Daniel | Ponzevera, Emmanuel | Briant, Nicolas | Knoery, Joel | Sireau, Teddy | Mojtahid, Meryem | Metzger, Edouard | Brach-papa, Christophe
In this work, a multi-elemental approach combining Cu and Zn stable isotopes is used to assess the metal contamination evolution in the Loire estuary bulk sediments. Elemental geochemical data indicate an increase of metal concentrations from the beginning of the industrial period peaking in the 1990s, followed by an attenuation of metal contamination inputs to the estuary. Zinc isotope compositions suggest a binary mixing process between Zn derived from terrigenous material and multi-urban anthropogenic sources. Copper isotope systematics indicate a single natural dominant source represented by weathered silicate particles from soils and rocks. This work demonstrates the applicability of Zn isotopes to identify anthropogenic Zn sources in coastal systems, even under a low to moderate degree of contamination. Further studies are required to constrain Cu sources and to elucidate possible effects of grain-size and mineralogy in the Cu isotope composition of sediment in the Loire estuary.
Show more [+] Less [-]Microplastic ingestion by Atlantic chub mackerel (Scomber colias) in the Canary Islands coast Full text
2019
Herrera, A. | Ŝtindlová, A. | Martínez, I. | Rapp, J. | Romero-Kutzner, V. | Samper, M.D. | Montoto, T. | Aguiar-González, B. | Packard, T. | Gomez, M.
In recent years, due to the increasing concerns about their negative impact on wildlife and possible toxicity to living organisms (including humans), microplastics have become the subject of intense investigations. In the ocean, microplastics can be easily ingested by numerous marine organisms because of their small size (<5 mm). The Northwest African upwelling system is an important fishery area, and the present study is the first one in the region to reveal the presence of microplastic particles in the digestive tract of Atlantic chub mackerel (Scomber colias). From the 120 examined fish gastrointestinal tracts, 78.3% contained some type of microplastics, 74.2% contained fibres, 17.5% plastic fragments, and 16.7% paint. More studies are needed on fish, but S. colias is a candidate for being a good indicator of microplastic contamination in the region.
Show more [+] Less [-]A portable thermal system for reactive treatment of biofouled internal pipework on recreational vessels Full text
2019
Cahill, Patrick | Tait, Leigh | Floerl, Oliver | Bates, Tracey | Growcott, Abraham | Georgiades, Eugene
Biofouled commercial and recreational vessels are primary vectors for the introduction and spread of marine non-indigenous species (NIS). This study designed and assessed a portable system to reactively treat biofouling in the internal pipework of recreational vessels – a high-risk ‘niche area’ for NIS that is difficult to access and manage. A novel thermal treatment apparatus was optimised in a series of laboratory experiments performed using scale models of vessel pipework configurations. Treatment effectiveness was validated using the Pacific oyster Magallana gigas, a marine NIS with known resilience to heat. In subsequent field validations on actual recreational vessels, treatment was successfully delivered to high-risk portions of pipework when an effective seal between delivery unit and targeted pipework was achieved and ambient heat loss was minimised. In addition to demonstrating the feasibility of in-water treatment of vessel pipework, the study highlights the importance of robust optimisation and validation of any treatment system intended for biosecurity purposes.
Show more [+] Less [-]Examining the physical processes of corn oil (medium crude oil surrogate) in sea ice and its resultant effect on complex permittivity and normalized radar cross-section Full text
2019
Desmond, Durell S. | Neusitzer, Thomas D. | Firoozy, Nariman | Isleifson, Dustin | Lemes, Marcos | Barber, David G. | Stern, Gary A.
Due to the effects of heightened warming in the Arctic, there has been an urgency to develop methods for detecting oil in (or under) sea ice, owing to increasing potential for oil exploration and ship traffic in the more accessible Arctic regions. To test the potential for radar utilizing the normalized radar cross section (NRCS) of the sea ice, an oil-in-ice mesocosm experiment was performed. Throughout the experiment, corn oil was used as a surrogate for medium crude oil, to assess oil movement tendencies in sea ice, and the resultant impact on the complex permittivity through measurement and modelling techniques. We performed a modelling study to establish the effects of corn oil on the NRCS of sea ice. The oil presence in the sea ice increased the temperature and reduced the salinity of the sea ice, thereby lowering its complex permittivity and modeled NRCS when compared to control sea ice.
Show more [+] Less [-]PAHs and PCBs residues and consumption risk assessment in farmed yellow croaker (Larimichthys crocea) from the East China Sea, China Full text
2019
Wang, Xiaoyan | Celander, Malin C. | Yin, Xiaolong | Zhang, Zhichao | Chen, Yongjiu | Xu, Huanzhi | Yu, Xinwei | Xu, Kaida | Zhang, Xiumei | Kanchanopas-Barnette, Praparsiri
Large yellow croaker (Larimichthys crocea) purchased from five different farming sites in Zhoushan Archipelago and Xiangshan Harbor in the East China Sea, China were analyzed for polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). Concentrations of PAHs and PCBs in the edible muscle of L. crocea ranged from 83.14 to 174.68 ng/g wet weight (or 266.89 to 695.24 ng/g dry weight) and 3.89 to 17.40 ng/g wet weight (or 15.50 to 54.25 ng/g dry weight), respectively. Incremental lifetime cancer risk (ILCR) associated with the dietary intake of PAHs and PCBs in L. crocea was assessed. Results showed that levels of PAHs in L. crocea were high enough to cause potential carcinogenic risks for human consumption, while, levels of PCBs in fish samples were of low significant carcinogenic risk.
Show more [+] Less [-]When the levee breaks: Effects of flood on offshore water contamination and benthic community in the Mediterranean (Ionian Sea) Full text
2019
Mistri, Michele | Pitacco, Valentina | Granata, Tommaso | Moruzzi, Letizia | Munari, Cristina
In the last few years extreme weather events, including changes to storm frequency and intensity, have increased across all continents. In this note we assessed, for the first time in the Mediterranean Sea, the impact of a violent storm and consequent flood on offshore water contamination and benthic community along the Calabrian coast (Ionian Sea). Three sites (at 500, 1000, and 2000 m off the coast) were sampled along three parallel transects in 2013, 2014 (before), and 2015 (after the flood). After the flood, metals (especially Al, CrVI, Ni, Cu, Zn) in the water column increased in concentration. The flood affected the structure of the benthic community, causing a decrease of diversity, the dominance of few opportunistic species, and the decrease of M-AMBI values.
Show more [+] Less [-]Sinking velocity of sub-millimeter microplastic Full text
2019
Kaiser, David | Estelmann, Arne | Kowalski, Nicole | Glockzin, Michael | Waniek, J. J. (Joanna J.)
Sinking experiments were conducted using irregularly shaped polyamide (PA), polymethyl methacrylate (PMMA), and polyethylene terephthalate (PET) particles sized 6 to 251 μm. Certified PS spheres were used to validate experiments and showed that the effect of particle size on terminal sinking velocity is well reproduced by the method. As expected sinking velocities of irregularly shaped particles were considerably lower than theoretical values for spheres of the same size range calculated via several approximations available in the literature. Despite the influence of particle shape, the dependence of terminal sinking velocity on particle size can reasonably well be described by a quadratic linear regression, with an average determination of 63%. To generalize results we present a model that predicts terminal sinking velocity as a function of particle size and particle excess density over the fluid. Improving the predictive power of this model requires further experiments with a range of particle characteristics.
Show more [+] Less [-]Microplastics are ubiquitous on California beaches and enter the coastal food web through consumption by Pacific mole crabs Full text
2019
Horn, Dorothy | Miller, Michaela | Anderson, Sean | Steele, Clare
Microplastics are commonly found in marine ecosystems, but their distribution, prevalence, and impacts on resident fauna are still not well understood. Microplastics in coastal sediments expose invertebrate infauna to the risk of ingestion of plastic debris and associated toxicants. We assessed the prevalence of microplastics in beach sediments and ingested by Pacific mole crabs (Emerita analoga) at sandy beaches spanning >900 km of the California coast. Microplastics were present in sediments of every one of 51 beaches sampled. At a subset of 38 beaches Pacific mole crabs were collected and crabs at every beach had ingested microplastics. Across all beaches sampled, an average of 35% of Pacific mole crabs examined had microplastics in their guts. Our study demonstrates that microplastics are ubiquitous in sediments on California beaches and they are frequently consumed by a filter-feeding crustacean that is a common prey item in the diet of a wide variety of taxa, including fishes and birds.
Show more [+] Less [-]Beach litter distribution along the western Mediterranean coast of Spain Full text
2019
Asensio-Montesinos, F. | Anfuso, G. | Williams, A.T.
The amount and composition of beach litter was assessed, during spring 2018, at 56 sites along the coast of Alicante Province, on the western Mediterranean Sea. Selected sites covered “natural” (19), “village” (17) and “urban” (20) bathing areas and a total of 10,101 litter items was counted in an area of 201,686 m2. Plastic represented the dominant material with 8345 items, i.e. 82.6% of all debris; paper and cardboard numbered 566 items (i.e. 5.6%); pottery and ceramics 348 (3.4%); metal 325 (3.2%); cloth 231 (2.3%); glass 147 (1.5%); rubber 64 (0.6%); wood 46 (0.5%) and other materials summed 29 items, i.e. 0.3% of all debris. Cigarette butts, 45.6% of total items, were observed at different coastal sites: i.e. 1028 units at natural, 1148 at village and 2431 at urban sites. Despite the efforts of local administrations, which enforced cleaning operations at most sites, litter items were essentially related to beachgoers followed by wastewater discharges and fishing activities.
Show more [+] Less [-]Source of metal contamination in sediment, their ecological risk, and phytoremediation ability of the studied mangrove plants in ship breaking area, Bangladesh Full text
2019
Rahman, M Safiur | Hossain, M Belal | Babu, S.M Omar Faruque | Moshiur Rahman, | Ahmed, A.S Shafiuddin | Jolly, Y.N. | Choudhury, T.R. | Begum, B.A. | Kabir, J. | Akter, S.
Samples for sediment and two species of native mangrove plants were collected from seven sampling sites for assessing the level of metal contamination. Results of the studied metals displayed the order of pollution as Fe > Ti > Zr > Rb > Zn > Sr > Pb > Y > Cu > Cr > As accordingly. Geoaccumulation index and contamination factor revealed that the sediment samples were unpolluted to moderately polluted by Zn, Fe, Ti, Rb, Y, and Zr. Ecological risk factor depicted a pollution-free condition in the study areas. PCA, CA, and correlation coefficient indicated that the source of the metals in the environment was anthropogenic. Bioconcentration factor values were found to be below 1 in both plant species. Conversely, transfer factor values for most heavy metals were found to be >1 in both plant species, which reflects the phytoremediation ability of plants.
Show more [+] Less [-]