It has been established from previous studies that chlorophyll-a surface concentration has been declining in the eastern English Channel. This decline has been attributed to a decrease in nutrient concentrations in the rivers. However, the decrease in river discharge could also be a cause. In our study, rivers outflows and in-situ data have been compared to time series of satellite-derived chlorophyll-a concentrations. Dynamic Linear Model has been used to extract the dynamic and seasonally adjusted trends of several environmental variables. The results showed that, for the 1998–2019 period, chlorophyll-a levels stayed significantly lower than average and satellite images revealed a coast to offshore gradient. Chlorophyll-a concentration of coastal stations appeared to be related to the declining fluxes of phosphate while offshore stations were more related to nitrate-nitrite. Therefore, we can exclude that the climate variability, through river flows alone, has a dominant effect on the decline of chlorophyll-a concentration.

We report the first empirical confirmation of the co-occurrence of organophosphate esters (OPEs) additives and microplastics (MPs) in benthic compartments from the Loire estuary. Higher median concentrations of MPs (3387 items/kg dw), ∑13tri-OPEs (12.0 ng/g dw) and ∑4di-OPEs (0.7 ng/g dw) were measured in intertidal sediments with predominance of fine particles, and under higher anthropogenic pressures, with a general lack of seasonality. Contrarily, Scrobicularia plana showed up to 4-fold higher ∑tri-OPE concentrations in summer (reaching 37.0 ng/g dw), and similar spatial distribution. Polyethylene predominated in both compartments. Tris(2-ethylhexyl) phosphate (TEHP), its degradation metabolite (BEHP) and tris-(2-chloro, 1-methylethyl) phosphate (TCIPP) were the most abundant OPEs in sediments, while TCIPP predominated in S. plana. The biota-sediment accumulation factors suggest bioaccumulation potential for chlorinated-OPEs, with higher exposure in summer. No significant correlations were generally found between OPEs and MPs in sediments suggesting a limited role of MPs as in-situ source of OPEs.

Marinas are central hubs of global maritime leisure and transport, yet their operations can deteriorate the environmental quality of sediments. In response, this study investigated the metal contamination history associated with antifouling paint uses in a sediment core collected from Bracuhy marina (Southeast Brazil). Analysis target major and trace elements (Cu, Zn, Pb, Cd and Sn), rare earth elements (REEs), and Pb isotopes. The modification in Pb isotopic ratios and REEs pattern unequivocally revealed sediment provenance disruption following the marina construction. Metal distribution in the sediment core demonstrates that concentrations of Cu and Zn increased by up to 15 and 5 times, respectively, compared to the local background. This severe Cu and Zn contamination coincides with the onset of marina operations and can be attributed to the use of antifouling paints.

The St. Lawrence River, one of the world's largest estuaries, drains >25 % of the world's freshwater reserves and is affected by various anthropogenic effluents. Although previous studies reported micro- and nanoplastics contamination in the Estuary and Gulf of St. Lawrence (EGSL), this study provides a first evaluation of macroplastic pollution along the north and south shores of the EGSL. Plastic debris categorization was performed according to the OSPAR protocol completed by polymer identification using Fourier-transform infrared spectroscopy. The EGSL appeared ubiquitously contaminated by plastic debris, dominated by single-use plastics primarily made of polypropylene (28 %), polyethylene (25 %) and polystyrene (17 %). The EGSL shores exhibited a mean contamination level of 0.17 ± 0.11 items/m2 and distance to Montreal significantly influenced the distribution of plastic debris. This study provides an essential baseline for implementing local waste reduction and management actions in the St. Lawrence watershed to reduce plastic pollution.

Green tides occurrence has increased in coral reefs, yet few reference values have been documented to support bloom management in these ecosystems. Here, we took advantage of recent Ulva green tides that occurred in New Caledonia to (i) identify the elements limiting the growth of Ulva spp. during these blooms; and (ii) validate the use of isotopic markers for identifying sources of nutrients that generated blooms. N/P ratios highlighted a stronger limitation of algae by phosphorus than by nitrogen on sites under oceanic influence, while the proportions of N and P were optimal for algal growth at sites where green tides occurred. Macroalgae highly exposed to sewage water was characterized by higher δ15N than macroalgae collected in areas exposed to synthetic inorganic fertilizers. From these results, we established a new set of threshold values for using δ15N in Ulva species as an indicator of nitrogen source type in coral reefs.

An intercomparison exercise on “microplastics in sediment” was carried out by five laboratories using samples collected in the Bay of Marseille in September 2021. The results from different extraction and identification methods varied depending on the type and size classes of MPs, and was better than 80 % for the size class >300 μm and for the fragments. The variability in recovery rates can be attributed to the choice of reagents and extraction protocols. Recovery rates per laboratory were between 47 % and 113 % and the use of ZnCl2 and NaI increased recovery rates by an average of 70 %. The lowest recovery rates (47 and 53 %) were attributed to the reference methods (FTIR and LDIR), conversely the highest (80 and 87 %) were attributed to identification by Nile Red. The average ranged between 23 and 53 items /50 g d.w. with decreases offshore and at greater depth.

The Western Mediterranean coast is under the influence of anthropogenic pressures, including land use, increasing amounts of dangerous waste and habitat destruction. In 2021, the French RINBIO network (http://www.ifremer.fr/envlit/) originally dedicated to assess chemical contamination in the region, focused on biological effects produced by contaminants and the interaction with natural variability in mussels using an active caging strategy. Cell and tissue level biomarkers were applied for 17 sampling sites divided in three sub-regions categorized by different environmental conditions. Results provide critical information for ecosystem health assessment using mussels as sentinel species in the Western Mediterranean Sea. The influence of natural and confounding factors (trophic condition, reproductive cycle, caging strategy), on biological responses to mild chemical contamination, was discussed and discriminated for health status assessment. Results provide valuable data available as reference values for the assessment of biomarkers and histopathological alterations for large-scale active biomonitoring campaigns in the Western Mediterranean Sea.

The mid-20th century industrial peak caused severe global lead (Pb) marine contamination. Although Europe initiated Pb emission reduction regulations in the 1980s, the short- and long-term impacts remain unclear. This study investigates the evolution of Pb contamination on the French coast through elemental and isotope analysis in oysters and mussels from the French “Mussel Watch” Program. Observations at 114 monitoring stations over four decades have shown decreasing Pb levels in these bivalve mollusks. In 1988, 95 % exceeded the background reference values; this level had dropped to 39 % by 2021. The Pb isotope ratios in bivalves from eight target sites revealed a reduction in bioaccumulated anthropogenic Pb, albeit without complete elimination. The long residence time of legacy Pb combined with inputs from diffuse urban sources likely explains the persistent presence of anthropogenic Pb on the French coast. This study endorses the importance of continuous biomonitoring to evaluate environmental regulations and policies.

Akanda National Park (ANP) is composed of mangrove ecosystems bordering Libreville, Gabon's capital. The contamination of aquatic resources from the ANP by persistent organic pollutants (POPs) and trace metals (TMs) was never evaluated. To provide a basis for their monitoring in the ANP, five species (two fish, two mollusks, and one crustacean) were analyzed from three sampling sites in 2017. Contamination levels for POPs and TMs were below maximum acceptable limits for seafood, including Cd and Pb. No DDT was found in any sample. Inter-specific differences were more obvious than the differences among sites, although the results may be biased by an unbalanced sampling design. The oyster Crassostrea gasar was the most contaminated species, making this species a good candidate to assess environmental contamination in the area. The studied species also contained essential elements, such as Fe, Zn and Mn at interesting levels in a nutritional point of view.

The relationship between economic growth, governance, and environmental outcomes, particularly mismanaged plastic waste (MPW) leaking out to the ocean, has been a focal point of policy and academic debates. This study aims to understand the dynamics of income and control of corruption across different levels of MPW. Utilizing Quantile Regression models, we explore the generalized and quantile-specific relationships between the variables. The findings confirm the validity of the Environmental Kuznets Curve (EKC), revealing an initial increase in MPW with economic growth, followed by a decline after surpassing a specific economic threshold. However, the EKC is not validated for all quantiles and the shifting point may vary across the distribution. Moreover, control of corruption emerged as a significant factor in determining MPW levels, emphasizing its moderating role at the highest levels of mismanagement. This study underscores the need for synergizing economic strategies with robust environmental policies, guided by strong governance mechanisms.