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Exposure methodologies for dissolved individual hydrocarbons, dissolved oil, water oil dispersions, water accommodated fraction and chemically enhanced water accommodated fraction of fresh and weathered oil
2022
Wade, Terry L. | Driscoll, Susan Kane | McGrath, Joy | Coolbaugh, Thomas | Liu, Zhanfei | Buskey, Edward J.
Characterizing the nature and effects of oil released into the marine environment is very challenging. It is generally recognized that “environmentally relevant” conditions for exposure involve a range of temporal and spatial conditions, a range of exposure pathways (e.g., dissolved, emulsions, sorbed onto particulates matter), and a multitude of organisms, populations, and ecosystems. Various exposure methodologies have been used to study the effects of oil on aquatic organisms, and uniform protocols and exposure methods have been developed for the purposes of regulatory toxicological assessments. Ultimately, all exposure methods have drawbacks, it is impossible to totally mimic field conditions, and the choice of exposure methodology depends on the specific regulatory, toxicological, or other research questions to be addressed. The aim of this paper is to provide a concise review of the state of knowledge to identify gaps in that knowledge and summarize challenges for the future.
Show more [+] Less [-]Baseline marine litter abundance and distribution on Saint Martin Island, Bay of Bengal, Bangladesh
2022
Al Nahian, Sultan | Rakib, Md Refat Jahan | Haider, Sayeed Mahmood Belal | Kumar, Rakesh | Walker, Tony R. | Khandaker, Mayeen Uddin | Idris, Abubakr M.
Baseline marine litter abundance and distribution on Saint Martin Island, Bay of Bengal, were assessed. Seventy-two transects (100–150 m) along 12 km of coastline were surveyed for litter items every two weeks for two months. The most abundant items were polythene bags, food wrappers, plastic bottles/caps, straws, styrofoam, plastic cups, plastic fragments, fishing nets, clothes, and rubber buoys. Tourism, local markets, hotels, domestic waste, and fishing activities were primary sources of marine litter. According to the mean clean coast index (CCI), all transects were clean, of which 11.3 % and 14.1 % of sandy beaches and rocky shores with sandy beaches were reported dirty, respectively. Northern Saint Martin Island comprised sandy beaches (2.8 %) and was extremely dirty. In addition, plastic abundance index (PAI) analysis showed that 24 % of sites, out of 72 sites, were under “very high abundance”, 33 % were “high abundance”, 33 % showed “moderate abundance”, and 4 % were classified as “low abundance”. Establishing baseline results of marine litter abundance and distribution on Saint Martin Island may help improve island conservation and mitigation strategies (e.g., improved waste management, beach cleaning activities to raise public awareness, local government litter reduction policies, and increase local pro-environmental behavioral change).
Show more [+] Less [-]An assessment of floating marine debris within the breakwaters of the University of the South Pacific, Marine Studies Campus at Laucala Bay
2022
Paris, Andrew | Kwaoga, Alex | Hewavitharane, Chinthaka
Contributions of Pacific Islands countries to marine plastic debris are disproportionate to the effects on people's connections to the ocean. Plastic waste management initiatives face challenges in containing waste and consequently plastics plague coastal environments. The Seabin, a floating trash skimmer, presents a novel and replicable approach to collecting and cataloguing marine plastics. The objectives of the study were to conduct an audit of marine plastic debris within the breakwaters of the University of the South Pacific, Marine Campus at Laucala Bay while simultaneously gauging the effectiveness of the Seabin and providing recommendations to enhance its utility. Inorganic debris was comprised entirely of plastics while the majority of debris collected was organic. This study provides the first assessment of floating marine plastic debris in an inshore environment of a Pacific Island country. Plastic debris assessments have the potential to inform policy and pivot management efforts to mitigate plastic waste pollution.
Show more [+] Less [-]Pre- and post-industrial levels of polycyclic aromatic hydrocarbons in sediments from the Estuary and Gulf of St. Lawrence (eastern Canada)
2022
Corminboeuf, Anne | Montero-Serrano, Jean-Carlos | St-Louis, Richard | Dalpé, Allyson | Gélinas, Yves
The concentrations of 23 polycyclic aromatic hydrocarbons (PAHs; 16 parent PAHs and 7 alkyl-PAHs) were determined in 45 surface sediment and 7 basal sediment box core samples retrieved from the Estuary and Gulf of St. Lawrence in eastern Canada. The concentration sums of 16 priority PAHs (Σ₁₆PAHs) in the surface sediments (representing modern times or at least younger than the last decade) ranged from 71 to 5672 ng g⁻¹. Σ₁₆PAHs in the basal sediments ranged from 93 to 172 ng g⁻¹ among the pre-industrial samples (pre-1900 common era or CE) and from 1216 to 1621 ng g⁻¹ among the early post-industrial samples (~1930s and ~1940s CE). The highest Σ₁₆PAH values occurred in samples retrieved from the Baie-Comeau-Matane area, an area affected by intense industrial anthropogenic activities. Source-diagnostic PAH ratios suggest a predominance of pyrogenic sources via atmospheric deposition, with a minor contribution of petrogenic seabed pockmark sources. The PAH concentrations in the sediments from the study areas reveal low ecological risks to benthic or other organisms living near the water-sediment interface.
Show more [+] Less [-]Assessment of chloride natural background levels by applying statistical approaches. Analyses of European coastal aquifers in different environments
2022
Pulido-Velazquez, D. | Baena-Ruiz, L. | Fernandes, J. | Arnó, G. | Hinsby, K. | Voutchkova, D.D. | Hansen, B. | Retike, I. | Bikše, J. | Collados-Lara, A.J. | Camps, V. | Morel, I. | Grima-Olmedo, J. | Luque-Espinar, J.A.
Estimated natural background levels (NBLs) are needed to assess groundwater chemical status according to the EU Groundwater Directive. They are commonly derived for different substances by applying statistical methodologies. Due to the complexity of the sea water intrusion process, some of those methods do not always provide appropriate assessment of chloride NBLs. This paper analyzes the applicability of different NBL estimation methods in five EU coastal aquifers with significant differences in available datasets and hydrogeological settings. A sensitivity analysis of results to different constraints was performed to remove samples with anthropogenic impacts. A novel statistical approach combining different methods to identify the range of chloride NBLs is proposed. In all pilots the estimated NBLs were below 85 mg/L and fitted well with previous studies and expert judgment, except Campina del Faro aquifer (the maximum being 167.5 mg/L). Although this approach is more time consuming, it provides a more robust solution.
Show more [+] Less [-]Trends of banned pesticides and PCBs in different tissues of striped dolphins (Stenella coeruleoalba) stranded in the Northwestern Mediterranean reflect changing contamination patterns
2022
Dron, Julien | Wafo, Emmanuel | Boissery, Pierre | Dhermain, Frank | Bouchoucha, Marc | Chamaret, Philippe | Lafitte, Daniel
Although banned for years, organochlorine pesticides and PCBs continue to affect aquatic life, dolphins being particularly exposed. The concentrations of 31 PCB congeners, and 15 banned pesticides or metabolites were measured in 5 tissues of 68 striped dolphins stranded in the Northwestern Mediterranean coast in 2010–16. The results were compared to historical data (1988–2009) and, even though there is a slow decreasing trend, the levels in the 2010–2016 samples were still elevated based on common cetacean toxicological thresholds. A transition period in 2007–08, probably caused by a morbillivirus epizootic amplified the stranding, espacially of highly contaminated specimens. From 2010, higher proportions in parent compounds towards metabolites were observed yet again. These changing patterns were likely reflect the exposure of dolphins to the remobilization of pollutants from contaminated soils and sediments, with a prominent role of rivers. This should lead to an even slower decline of these contaminants that could last for decades, requiring new efforts to reduce their dispersal to aquatic ecosystems.
Show more [+] Less [-]Impact of plastic bags on the benthic system of a tropical estuary: An experimental study
2022
Clemente, Caroline C.C. | Paresque, Karla | Santos, Paulo J.P.
Plastic bags are among the most discarded waste items as they are generally only used once and are often improperly eliminated and transported by rivers and estuaries to the ocean. We developed an experimental design to mimic the effect of plastic bag deposition in a tropical estuary and investigated its short-term impact on benthic community structure. We observed a significant influence of the presence of plastic bags on the abundance, richness and diversity of benthic fauna after an eight-week exposure period. Plastic bags acted as a barrier and interfered in processes that occur at the water-sediment interface, such as organic matter and silt-clay deposition. Our results indicate that plastic bags, in addition to directly affecting benthic fauna, may alter processes such as carbon burying, known as “blue carbon”, thus making its storage in the sediment more difficult.
Show more [+] Less [-]Anchored bulk carriers have substantial impacts on the underwater soundscape in Cowichan Bay, British Columbia
2022
Murchy, Kelsie A. | Vagle, Svein | Juanes, Francis
In recent decades shipping traffic has increased, leading to elevated underwater ambient noise levels. Research has been conducted on the noise generated by ships underway, however little is known about potential noise from ships at anchor. In coastal regions, commercial vessels can seek anchorages prior to entering port, leading to concern regarding the impacts on the soundscape and marine ecosystems. Cowichan Bay, British Columbia, a coastal region (800 Ha) 70 km away from the Port of Vancouver, was examined as a case study to understand the possible soundscape contribution from anchored bulk carriers. When a carrier anchored, sound pressure levels (SPL: 20–24,000 Hz) were elevated 2–8 dB re: 1 μPa throughout the bay. These results demonstrate the change anchored carriers can have on underwater soundscapes and is an important step in understanding the potential impact these vessels may have on marine organisms and important ecosystems.
Show more [+] Less [-]Quantitative assessment of microplastic in sandy beaches of Gujarat state, India
2022
Rabari, Vasantkumar | Patel, Krupal | Patel, Heris | Trivedi, Jigneshkumar
The present study was carried out to quantify microplastic prevalence among 20 sandy beaches on the Gujarat coast. Beaches were categorised into three different classes, viz. low-impacted sites, moderately impacted sites, and highly impacted sites based on anthropogenic pressure. Microplastic (MP) (≤ 5 mm) contamination on the beaches varied with an average of 1.4 MPs/kg to 26 MPs/kg sediment. Sutrapada site-1 and Porbandar showed the highest and lowest mean abundance of microplastics, respectively, among 20 selected beaches. Out of the total assessed microplastics, threads were the maximum (89.98%), followed by the films (4.75%), fragments (3.36%) and foam (1.89%). In terms of colour and size, different microplastics were recorded in this study. The chemical composition of microplastics was identified by ATR-FTIR as polypropylene (47.5%), polyethylene (26%), and polystyrene (25%). Tourism and fishing activities are the possible sources of higher microplastic contamination at highly impacted sites.
Show more [+] Less [-]Source-specific ecological risk assessment and quantitative source apportionment of heavy metals in surface sediments of Pearl River Estuary, China
2022
Xiao, He | Shahab, Asfandyar | Ye, Feng | Wei, Gangjian | Li, Jieyue | Deng, Liming
In this study, surface sediments of the Pearl River Estuary were collected from 29 stations and investigated the spatial distribution, pollution level, quantitative source apportionment, and source-specific ecological risk of 10 heavy metals. The mean concentrations followed the order of Mn > Zn > Cr > Cu > Ni > Pb > As > Co > Cd > Hg. In terms of spatial distribution, it showed that the heavy metals were enriched in the inner Pearl River Estuary with ‘extremely high’ level of Hg, whereas, Cd and Zn posed ‘moderate to high’ contamination potential. We apportioned four main sources using positive matrix factorization model, in which natural geogenic and industrial manufacturing sources accounted for 36.84% and 27.11% of the total, respectively. However, the source-specific risk assessment suggested that mixed anthropogenic sources were the main contributors, and ecological risks were strongly affected by anthropogenic imports from the surrounding cities.
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