The current recovery of mountain lakes from atmospheric acidification is increasingly affected (both accelerated and/or delayed) by climate change. We evaluated long-term trends in the ionic composition of 30 lakes situated in the alpine zone of the Tatra Mountains, and compared the rates of their recovery with model (MAGIC) simulations done 20 years ago for the 2003–2020 period. The observed recovery was faster than the model forecast, due to greater reductions in acidic deposition than projected. Trends in water composition were further modified by climate change. Rising temperatures increased the length of the growing season and retention of inorganic N and SO₄²⁻ more in soil-rich compared with soil-poor catchments. In contrast, elevated precipitation and an increase in rainfall intensity reduced water residence time in soils, and consequently reduced N retention, especially in soil-poor catchments. It is likely that increases in rainfall intensity and annual number of days without snow, along with air temperatures fluctuating around the freezing point elevated the physical erosion of rocks, especially in high-elevation, steep, and scree-rich areas where rocks are not thermally insulated and stabilized by soils. Weathering of exposed accessory calcite in the eroded granodiorite bedrock was a source of Ca²⁺ and HCO₃⁻, while S-bearing minerals likely contributed to lake water SO₄²⁻ and partly mitigated its deposition-related decrease in scree-rich catchments. The extent of climate effects on changes in the water composition of alpine lakes recovering from acidic deposition thus depended on elevation and cover of soil and scree in catchments. Our results highlight the need for incorporating dominant climate-related process into existing process-based models to increase their reliability in predicting the future development of lake water composition.

Exposure to PM₂.₅ is associated with many adverse health effects, leading to additional social costs. The Blue Sky Protection Campaign (BSPC) has been implemented in 2018 in the Beijing-Tianjin-Hebei (BTH) area to control air pollution. This study assesses PM₂.₅-related health and economic benefits of the BSPC in the BTH region. Results show that by 2020, PM₂.₅ reduction can avoid 3561 thousand morbidity cases (equivalent to a 24% reduction in the 2020 baseline scenario) and 24 thousand premature deaths (12%) in the BTH region, with the majority benefit in Hebei. By 2030, the avoided morbidity and mortality cases will be 2943 (18%) thousand and 20 (9%) thousand, respectively. PM₂.₅ reductions are highly effective in reducing work time loss, which will decrease the total annual work time by 1.7 × 10⁸ h (24%) in the BTH region by 2020. From the economic aspect, the reduced PM₂.₅ concentration will save 30 million USD (25%) health expenditures and avoid 60 billion USD (13%) economic loss by using the value of statistical life (VSL) by 2020. In 2030, the health expenditures and economic loss will also decrease significantly, with 17 million USD (18%) and 63 billion USD (10%), respectively, in the BTH region. Besides, the economic benefits far exceed the policy costs of the BSPC, and the Δ benefit/Δ cost ratios of Beijing are significantly higher than those of Hebei. The BSPC in BTH has significant positive health and economic impacts. This study can provide a basis for future PM₂.₅-related health risk studies at an urban level in China.

The internal temperature of nests largely depends on the materials used in their construction because the characteristics of each material affect the isolation of nest walls. In urban environments, the availability of natural materials for nest building decreases, while the availability of artificial materials increases. Therefore, many urban bird species use more artificial materials for nest building inside cities, which may affect the thermal properties of the nest. We conducted an experiment to measure the effect of artificial materials included as part of the nest structure, on nest thermoregulation. We used as a model, nests of the clay-colored thrush (Turdus grayi), an urban bird species that have been reported using artificial nest materials. In our experiment, we measured how variation in artificial materials mass affects the nest cooling rate in a climate-controlled room. We found that artificial materials increased the cooling rate of clay-colored thrush nests, compared with nests with only natural materials. This result is especially relevant because showed a negative direct effect of the use of artificial material for nest building in birds. Considering that the availability of artificial material is increasing in urban areas, while natural material is decreasing, it is expected that the negative effect of using artificital material for nest construction would increase in the clay-colored thrush and other city bird species.

In the present study, the daily dose in terms of particle surface area received by citizens living in different low- and middle-income countries, characterized by different lifestyles, habits, and climates, was evaluated. The level of exposure to submicron particles and the dose received by the populations of Accra (Ghana), Cairo (Egypt), Florianopolis (Brazil), and Nur-Sultan (Kazakhstan) were analyzed. A direct exposure assessment approach was adopted to measure the submicron particle concentration levels of volunteers at a personal scale during their daily activities. Non-smoking adult volunteers performing non-industrial jobs were considered. Exposure data were combined with time-activity pattern data (characteristic of each population) and the inhalation rates to estimate the daily dose in terms of particle surface area.The received dose of the populations under investigation varied from 450 mm² (Florianopolis, Brazil) to 1300 mm² (Cairo, Egypt). This work highlights the different contributions of the microenvironments to the daily dose with respect to high-income western populations. It was evident that the contribution of the Cooking & Eating microenvironment to the total exposure (which was previously proven to be one of the main exposure routes for western populations) was only 8%–14% for low- and middle-income populations. In contrast, significant contributions were estimated for Outdoor day and Transport microenvironments (up to 20% for Cairo, Egypt) and the Sleeping & Resting microenvironment (up to 28% for Accra, Ghana), highlighting the effects of different site-specific lifestyles (e.g. time-activity patterns), habits, socioeconomic conditions, climates, and outdoor air quality.

Evidence on the relationship between lifestyle, socio-economic factors and pesticide exposure and urinary concentrations of organophosphate (OP) pesticide metabolites among children is generally incomplete. This study investigated the relationship between socio-economic factors and reported pesticide exposures and the sum of three urinary concentrations of dialkyl phosphate metabolites (DAP) among boys living in the rural areas of the Western Cape, South Africa. Data was collected during a cross-sectional study of 183 boys from three agricultural intense areas. Measurements included a questionnaire on socio-economic and pesticide exposures and urinary DAP concentrations. Most boys (70%) lived on farms with a median age of 12 years (range: 5.0–19.5 years). Children aged >14 years had lower DAP urine concentrations (median = 39.9 ng/ml; β = −68.1 ng/ml; 95% CI: −136.8, 0.6) than children aged 9 years and younger (median = 107.0 ng/ml). DAP concentrations also varied significantly with area, with concentrations in the grape farming area, Hex River Valley (median = 61.8 ng/ml; β = −52.1; 95% CI: −97.9, −6.3 ng/ml) and the wheat farming area, Piketberg (median = 72.4 ng/ml; β = −54.2; 95% CI: 98.8, −9.7 ng/ml) lower than those in the pome farming area, Grabouw (median = 79.9 ng/ml). Other weaker and non-significant associations with increased DAP levels were found with increased household income, member of household working with pesticides, living on a farm, drinking water from an open water source and eating crops from the vineyard and or garden. The study found younger age and living in and around apple and grape farms to be associated with increased urinary DAP concentrations. Additionally, there were other pesticide exposures and socio-economic and lifestyle factors that were weakly associated with elevated urinary DAP levels requiring further study. The study provided more evidence on factors associated to urinary DAP concentrations especially in developing country settings.

Nanotechnology provides a wide range of benefits in the food industry in improving food tastes, textures, sensations, quality, shelf life, and food safety. Recently, potential adverse effects such as toxicity and safety concerns have been associated with the increasing use of engineered nanoparticles in food industry. Additionally, very limited information is known concerning the behavior, properties and effects of food nano-materials in the gastrointestinal tract. There is explores the current advances and provides insights of the potential risks of nanoparticles in the food industry. Specifically, characteristics of food nanoparticles and their absorption in the gastrointestinal tract, the effects of food nanoparticles against the gastrointestinal microflora, and the potential toxicity mechanisms in different organs and body systems are discussed. This review would provide references for further investigation of nano-materials toxicity effect in foods and their molecular mechanisms. It will help to develop safer foods and expand nano-materials applications in safe manner.

Recently, the adsorption-based environmental remediation techniques have gained a considerable attention, due to their economic viability and simplicity over other methods. Hence, detailed presentation and analysis were herein focused on describing the role of biochar in oil spill removal. Oil removal by utilizing biochar is assumed as a green-oriented concept. Biochar is a carbon-rich low-cost material with high porosity and specific surface chemistry, with a tremendous potentiality for oil removal from aqueous solutions. Oil sorption properties of biochar mainly depend on the biochar production/synthesis method, and the biomass feedstock type. In order to preserve the stability of functional groups in the structure, biochar needs to be produced/activated at low temperatures (<700 ᵒC). In general, biochar derived from biomass containing high lignin content via slow pyrolysis is more favorable for oil removal. Exceptional characteristics of biochar which intensify the oil removal capability such as hydrophobicity, oleophilicity or/and specific contaminant-surface interaction of biochar can be enhanced and be tuned by chemical and physical activation methods. Considering all the presented results, future perspectives such as the examination of biochar efficacy on oil removal efficiency in multi-element contaminated aqueous solutions to identify the best biomass feedstocks, the production protocols and large-scale field trials, are also discussed.

Artificial light at night (ALAN) is considered one of the most pervasive forms of environmental pollution. It is an emerging threat to freshwater biodiversity and can influence ecologically important behaviours of fish. The European eel (Anguilla anguilla) is a critically endangered catadromous species that migrates downstream to the ocean to spawn in the Sargasso Sea. Given the pervasive nature of ALAN, many eel will navigate through artificially lit routes during their seaward migration, and although considered negatively phototactic, their response has yet to be quantified. We investigated the response of downstream moving European eel to simulated ALAN using a Light Emitting Diode unit in an experimental flume. We presented two routes of passage under: (1) a dark control (both channels unlit), (2) low ALAN (treatment channel lit to ca. 5 lx), or (3) high ALAN (treatment channel lit to ca. 20 lx). Eel were: (i) more likely to reject an illuminated route when exposed to high levels of ALAN; (ii) less likely to select the illuminated channel when given a choice; and (iii) passed downstream more rapidly when the illuminated route was selected. This study quantified the response of the critically endangered European eel to ALAN under an experimental setting, providing the foundations for future field based research to validate these findings, and offering insight on the ecological impacts of this major environmental pollutant and driver of global change.

Due to the complex sources and fate of perfluoroalkyl substance (PFAS), their source apportionment in the environment remains a challenge. A data set of 11 straight-chain PFAS in 139 samples of fish in the Great Lakes was analyzed using positive matrix factorization (PMF) to investigate their primary sources, whose spatial variations were examined against the surrounding environmental factors. PMF analysis produced five fingerprints. Factor 1 (72% of Σ₁₁PFAS, dominated by PFOS) probably represented emissions from primary sources (such as consumer products) and secondary sources (precursors), and increased in average abundance from west to east across the Great Lakes. Factor 2 (13% of Σ₁₁PFAS) and factor 3 (7% of Σ₁₁PFAS), highly loaded with long-chain PFAS and PFNA, respectively, were thought to represent PVDF manufacture or processing in metal plating. They showed higher contributions in sparsely populated Lakes Superior and Huron. Factor 4 (5% of Σ₁₁PFAS, highly loaded with PFOS and PFHxS) presented hot spots near current and former air force bases, suggesting it was related to aqueous film-forming foams (AFFFs). Factor 5 (4% of Σ₁₁PFAS) contained primarily PFOS and PFOSA, which may imply metabolism of precursors (PFOSA) to PFOS in vivo. Unexpectedly, the spatial trends of the five sources all showed abnormally low values near the more urbanized Chicago and Milwaukee in Lake Michigan, which may be due to their unique wastewater and stormwater infrastructure or may arise from atmospheric transport of precursors. Our study indicated that PMF was an effective tool to identify sources of PFAS in fish despite absorption, distribution, metabolism, and excretion (ADME) processes which might alter fingerprints in fish relative to their surrounding environment.

Volatile organic compounds (VOCs) are easily degraded by oxidants during atmospheric transport. Therefore, the contribution of VOCs to ozone (O₃) and secondary organic aerosol (SOA) formation at a receptor site is different from that in a source area. In this study, hourly concentrations of VOCs and other pollutants, such as O₃, NOx, HONO, CO, and PM₂.₅, were measured in the suburbs (Daxing district) of Beijing in August 2019. The photochemical initial concentrations (PICs), in which the photochemical losses of VOCs were accounted for, were calculated to evaluate the contribution of the VOCs to O₃ and SOA formation. The mean (±standard deviation) measured VOC concentrations and the PICs were 11.2 ± 5.7 and 14.6 ± 8.4 ppbv, respectively, which correspond to O₃ formation potentials (OFP) of 57.8 ± 26.3 and 103.9 ± 109.4 ppbv and SOA formation potentials (SOAP) of 8.4 ± 4.1 and 10.3 ± 7.4 μg m⁻³, respectively. Alkenes contributed 80.5% of the consumed VOCs, followed by aromatics (13.3%) and alkanes (6.2%). The contributions of the alkenes and aromatics to the OFPPICₛ were 56.8% and 30.3%, respectively; while their corresponding contributions to the SOAPPICₛ were 1.9% and 97.3%, respectively. The OFPPICₛ was linearly correlated with the observed O₃ concentrations (OFPPICₛ = 41.5 + 1.40 × cO₃, R² = 0.87). The O₃ formation was associated with a VOC-limited regime at the receptor site based on the measured VOCs and changed to a transition regime and a NOx sensitive regime based on the PIC. Our results suggest that more attention should be paid to biogenic VOCs when studying O₃ formation in summer in Beijing, while the control of anthropogenic aromatic compounds should be given priority in terms of SOA formation.