Fuzzy Cognitive Mapping (FCM) is a participatory modelling tool used to explore complex systems by facilitating interdisciplinary cooperation and integrating a variety of knowledge systems. Here FCM was used to explore marine microfiber pollution. Through individual interviews with representatives from the research, industry, water and environmental sectors, five stakeholder FCMs were developed and used to produce an aggregated community FCM in a stakeholder workshop. Stakeholder FCMs and the revised community FCM were used to compute how the modelled system reacted to changes under two scenarios developed during the stakeholder workshop; (i) Green Shift and (ii) increased textile consumption and production. Significant differences were observed in scenario results from the stakeholder-based models and the community-based model. For societal challenges characterized by unknowns around the problem and potential solutions, inclusion of a variety of knowledge systems through FCM and deliberation processes contribute to a more holistic picture of the system and its uncertainties.

Fuzzy Cognitive Mapping (FCM) is a participatory modelling tool used to explore complex systems by facilitating interdisciplinary cooperation and integrating a variety of knowledge systems. Here FCM was used to explore marine microfiber pollution. Through individual interviews with representatives from the research, industry, water and environmental sectors, five stakeholder FCMs were developed and used to produce an aggregated community FCM in a stakeholder workshop. Stakeholder FCMs and the revised community FCM were used to compute how the modelled system reacted to changes under two scenarios developed during the stakeholder workshop; (i) Green Shift and (ii) increased textile consumption and production. Significant differences were observed in scenario results from the stakeholder-based models and the community-based model. For societal challenges characterized by unknowns around the problem and potential solutions, inclusion of a variety of knowledge systems through FCM and deliberation processes contribute to a more holistic picture of the system and its uncertainties. | publishedVersion

The advent of Multicollector ICP-MS inaugurated the analysis of new metal isotope systems, the so-called “non-traditional” isotopes. They are now available tools to study geochemical and ecotoxicological aspects of marine metal contamination and hence, to push the frontiers of our knowledge. However, such applications are still in their infancy, and an accessible state-of-the-art describing main applications, obstacles, gaps, and directions for further development was missing from the literature. This paper fills this gap and aims to encourage the marine scientific community to explore the contributions of this newly available information for the fields of chemical risk assessment, biomonitoring, and trophic transfer of metal contaminants. In the current “Anthropocene” epoch, metal contamination will continue to threaten marine aquatic ecosystems, and “non-traditional” isotopes can be a valuable tool to detect human-induced changes across time-space involving metal contaminants, and their interaction with marine biota.

The advent of Multicollector ICP-MS advent inaugurated the analysis of new metal isotope systems, the so-called “non-traditional” isotopes. They are now available tools to study geochemical and ecotoxicological aspects of marine metal contamination and hence, to push the frontiers of our knowledge. However, such applications are still in their infancy, and an accessible state-of-the-art describing main applications, obstacles, gaps, and directions for further development was missing from the literature. This paper fills this gap and aims to encourage the marine scientific community to explore the contributions of this newly available information for the fields of chemical risk assessment, biomonitoring, and trophic transfer of metal contaminants. In the current “Anthropocene” epoch, metal contamination will continue to threaten marine aquatic ecosystems, and “non-traditional” isotopes can be a valuable tool to detect human-induced changes across time-space involving metal contaminants, and their interaction with marine biota.

Estimated natural background levels (NBLs) are needed to assess groundwater chemical status according to the EU Groundwater Directive. They are commonly derived for different substances by applying statistical methodologies. Due to the complexity of the sea water intrusion process, some of those methods do not always provide appropriate assessment of chloride NBLs. This paper analyzes the applicability of different NBL estimation methods in five EU coastal aquifers with significant differences in available datasets and hydrogeological settings. A sensitivity analysis of results to different constraints was performed to remove samples with anthropogenic impacts. A novel statistical approach combining different methods to identify the range of chloride NBLs is proposed. In all pilots the estimated NBLs were below 85 mg/L and fitted well with previous studies and expert judgment, except Campina del Faro aquifer (the maximum being 167.5 mg/L). Although this approach is more time consuming, it provides a more robust solution.

Estimated natural background levels (NBLs) are needed to assess groundwater chemical status according to the EU Groundwater Directive. They are commonly derived for different substances by applying statistical methodologies. Due to the complexity of the sea water intrusion process, some of those methods do not always provide appropriate assessment of chloride NBLs. This paper analyzes the applicability of different NBL estimation methods in five EU coastal aquifers with significant differences in available datasets and hydrogeological settings. A sensitivity analysis of results to different constraints was performed to remove samples with anthropogenic impacts. A novel statistical approach combining different methods to identify the range of chloride NBLs is proposed. In all pilots the estimated NBLs were below 85 mg/L and fitted well with previous studies and expert judgment, except Campina del Faro aquifer (the maximum being 167.5 mg/L). Although this approach is more time consuming, it provides a more robust solution.

A number of trace elements (Mn, Fe, Co, Ni, Cu, Zn, As, Nb, Mo, Ag, Cd, Pb, U and the rare earth elements – REE) were analyzed in the dissolved phase, suspended particulate matter and in different organs (gills, hepatopancreas, and the rest of soft tissue) in mussels of the native Mytilus galloprovincialis and invasive Xenostrobus securis species in the Vigo Ria (NW Iberian Peninsula) in order to assess potential differences in their bioaccumulation patterns. Results obtained do not show significant differences in the bioaccumulation of trace elements by M. galloprovincialis and X. securis, except for Zn and Ag. In the case of Zn, a 4-fold enrichment in M. galloprovincialis compared to X. securis was found. The most important differences between species were observed for Ag, with approximately 40-fold higher concentrations in X. securis. Such elevated Ag bioaccumulation by X. securis can be useful for Ag biomonitoring using these invasive species in this area.

7 pages, 3 tables, 5 figures.-- Under a Creative Commons license | A number of trace elements (Mn, Fe, Co, Ni, Cu, Zn, As, Nb, Mo, Ag, Cd, Pb, U and the rare earth elements – REE) were analyzed in the dissolved phase, suspended particulate matter and in different organs (gills, hepatopancreas, and the rest of soft tissue) in mussels of the native Mytilus galloprovincialis and invasive Xenostrobus securis species in the Vigo Ria (NW Iberian Peninsula) in order to assess potential differences in their bioaccumulation patterns. Results obtained do not show significant differences in the bioaccumulation of trace elements by M. galloprovincialis and X. securis, except for Zn and Ag. In the case of Zn, a 4-fold enrichment in M. galloprovincialis compared to X. securis was found. The most important differences between species were observed for Ag, with approximately 40-fold higher concentrations in X. securis. Such elevated Ag bioaccumulation by X. securis can be useful for Ag biomonitoring using these invasive species in this area | Funding was provided by the Spanish Government including European FEDER funds (project Ref. CTM2016-76146-C3-2-R) | Peer reviewed

3 pages.-- File includes 2 tables, 1 figure | Table S1. Results obtained (n=3) for the certified reference materials DORM-2 (fish muscle) and BCR-CRM668 (mussel tissue) (NRC, Canada). Values in brackets represent one standard deviation.-- Table S2. Results obtained (n=3) for the certified reference materials CASS-6 (coastal seawater), SLEW-3 (estuarine water) and SLRS-6 (river water) (NRC, Canada). Values in brackets represent one standard deviation. Values for REE in SLEW-3 are not certified; concentrations given were reported by Bayon et al. (2001). Value for Nb in SLRS-6 is not certified; value given was reported by Babechuk et al. (2020).-- Figure S1. Concentrations (µg g-1) of the trace elements analyzed in the hepatopancreas, gills and rest of soft tissue for M. galloprovincialis at Station 3 and X. securis at Station 1 | Peer reviewed