The concentrations of total petroleum hydrocarbons (TPH), n-alkanes (n-C₈ through n-C₄₀), and 16 polycyclic aromatic hydrocarbons (PAHs) in soils were determined to assess the level of organic contamination in soils from the Da-gang Petrochemical Industry Park with several big state-run enterprises, a recent rapid flourishing park in China. The results showed that the concentration of TPH in soil was high, up to 20 ng/g–12.8478 %; in particular, the content in most sites ranged from 1 to 2 %. Thus, it is clear that soil environment in the Da-gang Petrochemical Industry Park has been seriously polluted by TPH according to the Nemerow pollution index method. Furthermore, the average concentration of Σ(n-C>₁₆ through n-C₃₄) in 30 sampling sites was above the maximum limit set for F3 under all the conditions in the Canada-wide standards for petroleum hydrocarbons (PHC CWS) with 43.33–93.33 % soil samples exceeding F3 standards, and n-alkanes possessing higher concentrations were proved much abundant alkanes in this study. Besides, the predominance of even n-alkanes and lower carbon preference index (CPI) demonstrated that n-alkanes in surface soils were mainly caused by anthropogenic inputs, while the concentration of Σ₁₆-PAHs was in the range of 1652.5–8217.3 ng/g and the BaA/(BaA + Chr) and Flu/(Flu + Pyr) ratios indicated that pyrogenic PAHs may be the dominant PAHs in most soils with the contribution of petrogenic hydrocarbons in some sites.

The purpose of this work was to study the efficiency of different treatments, based on the combination of O₃, H₂O₂, and TiO₂, on fresh surface water samples fortified with wild strains of Escherichia coli. Moreover, an exhaustive assessment of the influence of the different agents involved in the treatment has been carried out by kinetic modeling of E. coli inactivation results. The treatments studied were (i) ozonation (O₃), (ii) the peroxone system (O₃/0.04 mM H₂O₂), (iii) catalytic ozonation (O₃/1 g/L TiO₂), and (iv) a combined treatment of O₃/1 g/L TiO₂/0.04 mM H₂O₂. It was observed that the peroxone system achieved the highest levels of inactivation of E. coli, around 6.80 log after 10 min of contact time. Catalytic ozonation also obtained high levels of inactivation in a short period of time, reaching 6.22 log in 10 min. Both treatments, the peroxone system (O₃/H₂O₂) and catalytic ozonation (O₃/TiO₂), produced a higher inactivation rate of E. coli than ozonation (4.97 log after 10 min). While the combination of ozone with hydrogen peroxide or titanium dioxide thus produces an increase in the inactivation yield of E. coli regarding ozonation, the O₃/TiO₂/H₂O₂ combination did not enhance the inactivation results. The fitting of experimental values to the corresponding equations through non-linear regression techniques was carried out with Microsoft® Excel GInaFiT software. The inactivation results of E. coli did not respond to linear functions, and it was necessary to use mathematical models able to describe certain deviations in the bacterial inactivation processes. In this case, the inactivation results fit with mathematical models based on the hypothesis that the bacteria population is divided into two different subgroups with different degrees of resistance to treatments, for instance biphasic and biphasic with shoulder models.

The investigation of arsenic (As) re-accumulation in an area previously remediated by soil dressing will help in sustainable controlling the risks of As to local ecosystems and should influence management decisions about remediation strategies. In this study, As content in an area remediated by soil dressing and the possible As accumulation risk in agricultural products were investigated. The results indicated that after 7 years of agricultural activities, the average As content (24.6 mg kg⁻¹) in surface soil of the investigated area increased by 83.6 % compared with that (13.4 mg kg⁻¹) in clean soil. Of the surface soil samples (n = 88), 21.6 % had As levels that exceeded the limits of the Environmental Quality Standard for Soils of China (GB 15618-1995) and 98.9 % of the surface soil samples with As contents exceeding that in clean soil was observed. Soil dressing might be not a remediation method once and for all in some contaminated areas, even though no significant difference in available As content was found between clean (0.18 mg kg⁻¹) and surface (0.22 mg kg⁻¹) soils. The foreign As in surface soil of the investigated area mainly specifically sorbed with soil colloid or associated with hydrous oxides of Fe and Al, or existed in residual fraction. The upward movement of contaminated soil from the deeper layers and the atmospheric deposition of slag particles might be responsible for the re-accumulation of As in the investigated area. Decreases in soil pH in the investigated soils and the fact that no plant samples had As levels exceeding the limits of the National Food Safety Standards for Contaminants of China (GB 2762-2012) were also observed.

We investigated dioxin formation and removal in a commercial thermal waste treatment plant employing a gasification and melting process that has become widespread in the last decade in Japan. The aim was to clarify the possibility of dioxin formation in a process operation at high temperatures and the applicability of catalytic decomposition of dioxins. Also, the possible use of dioxin surrogate compounds for plant monitoring was further evaluated. The main test parameter was the influence of changes in the amount and type of municipal solid waste (MSW) supplied to the thermal waste treatment plant which from day to day operation is a relevant parameter also from commercial perspective. Here especially, the plastic content on dioxin release was assessed. The following conclusions were reached: (1) disturbance of combustion by adding plastic waste above the capability of the system resulted in a considerable increase in dioxin content of the flue gas at the inlet of the bag house and (2) bag filter equipment incorporating a catalytic filter effectively reduced the gaseous dioxin content below the standard of 0.1 ng toxic equivalency (TEQ)/m³ N, by decomposition and partly adsorption, as was revealed by total dioxin mass balance and an increased levels in the fly ash. Also, the possible use of organohalogen compounds as dioxin surrogate compounds for plant monitoring was further evaluated. The levels of these surrogates did not exceed values corresponding to 0.1 ng TEQ/m³ N dioxins established from former tests. This further substantiated that surrogate measurement therefore can well reflect dioxin levels.

Anaerobic digestion (AD) is one of the few sustainable technologies that both produce energy and treat waste streams. Driven by a complex and diverse community of microbes, AD may be affected by different factors, many of which also influence the composition and activity of the microbial community. In this study, the biodiversity of microbial populations in innovative mesophilic/thermophilic temperature-phased AD of sludge was evaluated by means of fluorescence in situ hybridization (FISH). The increase of digestion temperature drastically affected the microbial composition and selected specialized biomass. Hydrogenotrophic Methanobacteriales and the protein fermentative bacterium Coprothermobacter spp. were identified in the thermophilic anaerobic biomass. Shannon–Weaver diversity (H′) and evenness (E) indices were calculated using FISH data. Species richness was lower under thermophilic conditions compared with the values estimated in mesophilic samples, and it was flanked by similar trend of the evenness indicating that thermophilic communities may be therefore more susceptible to sudden changes and less prompt to adapting to operative variations.

In order to meet the environmental legislative framework in force in Europe and reduce sludge processing and disposal costs, several sludge treatment technologies and management strategies have been proposed in the last two decades. The evaluation of their technical and economic suitability, case by case, may be a challenge, since many aspects are involved, so that a robust decision support system should be used. Within the ROUTES project (founded within the EU Seventh Framework Programme), the authors have developed an assessment procedure which allows rating several technical factors (such as system reliability, complexity, safety aspects, modularity, etc.) and estimating capital and operating costs, in case a plant is being upgraded. The comparison between the original (reference) plant and the modified configuration informs about technical hot spots (which are expressed by a traffic light-type colour code) and cost gaps resulting from the implementation of the new solution.

Dioxin-like compounds (DLCs) have been classified by the World Health Organization (WHO) as one of the most persistent toxic chemical substances in the environment, and they are associated with several occupational activities and industrial accidents around the world. Since the end of the 1970s, these toxic chemicals have been banned because of their human toxicity potential, long half-life, wide dispersion, and they bioaccumulate in the food web. This review serves as a primer for environmental health professionals to provide guidance on short-term risk assessment of dioxin and to identify key findings for health and exposure assessment based on policies of different agencies. It also presents possible health effects of dioxins, mechanisms of action, toxic equivalency factors (TEFs), and dose–response characterization. Key studies related to toxicity values of dioxin-like compounds and their possible human health risk were identified through PubMed and supplemented with relevant studies characterized by reviewing the reference lists in the review articles and primary literature. Existing data decreases the scope of analyses and models in relevant studies to a manageable size by focusing on the set of important studies related to the perspective of developing toxicity values of DLCs.

Removal of toxic Cr(VI) by activated sludge and DOM derived from activated sludge was investigated in this study. A rapid increase in TOC concentration from 50.93 to 127.40 mg L⁻¹ is observed during the Cr(VI) removal process by activated sludge in the pH range of 2–9. Removal efficiencies of Cr(VI) by either activated sludge or DOM greatly decreased with the increasing initial pH. Kinetics of Cr(VI) removal by activated sludge indicate that both biosorption and bioreduction are involved in the Cr(VI) removal. Cr(VI) removal by DOM is slow in dark, but it is greatly enhanced when UV light is applied. The first-order constant increases from 0.0033 (in dark) to 0.079 min⁻¹ (UV illumination) at pH 2.0 and 1068 mg L⁻¹ DOM. The enhancement of Cr(VI) reduction is due to the generation of the reactive intermediates such as O₂ ●_ and DOM* as DOM absorbed light energy, which plays important roles in the reduction of Cr(VI).

With the rapid economic development, energy consumption of China has been the second place in the world next to the USA. Usually, measuring energy consumption intensity or efficiency applies heat unit which is joule per gross domestic production (GDP) or coal equivalent per GDP. However, this measuring approach is only oriented by the conversion coefficient of heat combustion which does not match the real value of the materials during their formation in the ecological system. This study applied emergy analysis to evaluate the energy consumption intensity to fill this gap. Emergy analysis is considered as a bridge between ecological system and economic system, which can evaluate the contribution of ecological products and services as well as the load placed on environmental systems. In this study, emergy indicator for performing energy consumption intensity of primary energy was proposed. Industrial production is assumed as the main contributor of energy consumption compared to primary and tertiary industries. Therefore, this study validated this method by investigating the two industrial case studies which were Dalian Economic Development Area (DEDA) and Fuzhou economic and technological area (FETA), to comparatively study on their energy consumption intensity between the different kinds of industrial systems and investigate the reasons behind the differences. The results show that primary energy consumption (PEC) of DEDA was much higher than that of FETA during 2006 to 2010 and its primary energy consumption ratio (PECR) to total emergy involvement had a dramatically decline from year 2006 to 2010. In the same time, nonrenewable energy of PEC in DEDA was also much higher than that in FETA. The reason was that industrial structure of DEDA was mainly formed by heavy industries like petro-chemistry industry, manufacturing industries, and high energy-intensive industries. However, FETA was formed by electronic business, food industry, and light industries. Although the GDP of DEDA was much higher than that of FETA, its energy intensity was higher as well. Through the 5-year development, energy consumption intensity in DEDA made a significant reduction from 3.90E+16 seJ/$ to 1.84E+16 seJ/$, which was attributed by the improvement of industrial structure, construction of eco-industrial park and circular economic industrial park. The proposed emergy indicator for demonstrating energy consumption intensity overcame the weakness that the indicator was only transformed from the heat burning. Therefore, this study shows an optional way to measure energy consumption intensity from the perspective of material ecological contribution.

The photocatalytic degradation of three neonicotinoid insecticides (NIs), thiamethoxam (TH), imidacloprid (IM) and acetamiprid (AC), in pure water has been studied using zinc oxide (ZnO) and titanium dioxide (TiO₂) as photocatalysts under natural sunlight and artificial light irradiation. Photocatalytic experiments showed that the addition of these chalcogenide oxides in tandem with the electron acceptor (Na₂S₂O₈) strongly enhances the degradation rate of these compounds in comparison with those carried out with ZnO and TiO₂ alone and photolytic tests. Comparison of catalysts showed that ZnO is the most efficient for the removal of such insecticides in optimal conditions and at constant volumetric rate of photon absorption. Thus, the complete disappearance of all the studied compounds was achieved after 10 and 30 min of artificial light irradiation, in the ZnO/Na₂S₂O₈ and TiO₂/Na₂S₂O₈ systems, respectively. The highest degradation rate was noticed for IM, while the lowest rate constant was obtained for AC under artificial light irradiation. In addition, solar irradiation was more efficient compared to artificial light for the removal of these insecticides from water. The main photocatalytic intermediates detected during the degradation of NIs were identified.