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Sustainable and efficient reduction of pollutants by immobilized PEG-P/Ag/Ag2O/Ag3PO4/TiO2 photocatalyst for purification of saline wastewater Full text
2022
Sharma, Aditya | Ming, Jie | Liu, Na | Sun, Xiang | Zhu, Yunxin | Yano, Minami | Chen, Guoping | Yang, Yingnan
In this study, we have reported an efficient and stable degradation of pollutants at salinity condition using newly developed solar-light-driven silicone-TiO₂ based photocatalytic immobilized system. The interfacial layer of Silicone-PEG-P/Ag/Ag₂O/Ag₃PO₄/TiO₂ (S-PEG/PAgT) photocatalyst exhibited higher surface roughness, hydrophobicity, better light absorption, and narrow band gap than S-TiO₂. The Rh B degradation by S-PEG/PAgT (91.2%) was 1.71 folds higher than S-TiO₂ (53.5%) under simulated solar light irradiation. The reduction rate was significantly higher in S-PEG/PAgT (0.0792 min⁻¹) than S-TiO₂ (0.0229 min⁻¹). The S-PEG/PAgT demonstrated high TOC removal (>80%), high repeatability (10 cycles) and excellent activity after 30 days of incubation in aqueous NaCl. The mechanism analysis revealed the synergistic effect of surface morphology with irregular chamfered edges and photoinduced reactive species (O₂⁻) with successive formation of free chlorine radicals (Cl) contributed to the removal of pollutants in saline wastewater. Therefore, considering the above advantages of high efficiency and effective elimination of organics illustrates the potential of newly developed S-PEG/PAgT immobilized system in long-term practical treatment real seawater and ballast water.
Show more [+] Less [-]Seagrass and green macroalgae Halimeda as biomonitoring tools for metal contamination in Chuuk, Micronesia: Pollution assessment and bioaccumulation Full text
2022
Jeong, Hyeryeong | Ra, Kongtae
In this study, we evaluated metal accumulation in different species and tissues of seagrasses and green macroalgae Halimeda and assessed metal pollution levels in Chuuk, Micronesia. In seagrass, the concentrations of Ni, Cu, Zn, Cd, Pb, and Hg were higher in leaves than in roots, whereas Cr and As concentrations were higher in roots. Halimeda had higher concentrations of Ni than of the other metals, and the mean Ni concentration was approximately 2.1 times higher in Halimeda than in seagrass leaves. The concentrations of Cr, As, Cu, Pb, and Hg in Halimeda were similar to those in seagrasses, whereas the Zn and Cd concentrations in Halimeda were very low. Significant correlations in metal concentrations between sediment and both seagrasses and Halimeda were observed for Cr, Ni, Cu, Zn, and Pb. This study suggests that seagrasses and Halimeda are useful indicators for monitoring metal pollution in coastal environments.
Show more [+] Less [-]Analyzing environmental factors that favor the growth of the invasive brown macroalga Rugulopteryx okamurae (Ochrophyta): The probable role of the nutrient excess Full text
2022
Mercado, Jesús M. | Gómez-Jakobsen, Francisco | Korbee, Nathalie | Aviles, Antonio | Bonomi-Barufi, José | Munoz, Maria | Reul, Andreas | Figueroa, Félix L.
Analyzing environmental factors that favor the growth of the invasive brown macroalga Rugulopteryx okamurae (Ochrophyta): The probable role of the nutrient excess Full text
2022
Mercado, Jesús M. | Gómez-Jakobsen, Francisco | Korbee, Nathalie | Aviles, Antonio | Bonomi-Barufi, José | Munoz, Maria | Reul, Andreas | Figueroa, Félix L.
Time series of temperature, salinity and nutrients in the Strait of Gibraltar (SoG) were researched to analyze which factors explain the invasive success of Rugulopteryx okamurare, which has colonized wide coastal areas at the Spanish and Moroccan coasts since 2016. Temperature and salinity were higher in the SoG compared to its native habitat, implying that the alga is active during the whole seasonal cycle and grows optimally at the high salinities occurring in the SoG. Nitrate removal experiments indicate that the alga is able to linearly increase its N uptake rates following boost in nitrate concentration. Furthermore, R. okamurae N content ranged from 1.4% to 4.5% suggesting that this species has high N storage capacity potentially usable when the external N concentration decreases. These physiological characteristics would explain sharp growth of the alga in the SoG where high N concentrations are registered occasionally.
Show more [+] Less [-]Analyzing environmental factors that favor the growth of the invasive brown macroalga Rugulopteryx okamurae (Ochrophyta): The probable role of the nutrient excess Full text
2022
Mercado-Carmona, Jesús Mariano | Gómez-Jakobsen, Francisco José | korbee, Nathalie | Avilés, A. | Bonomi-Barufi, J. | Muñoz, M. | Reul, A. | Figueroa, F.L. | Ministerio para la Transición Ecológica y el Reto Demográfico (España) | Ministerio de Ciencia e Innovación (España) | Junta de Andalucía
Time series of temperature, salinity and nutrients in the Strait of Gibraltar (SoG) were researched to analyze which factors explain the invasive success of Rugulopteryx okamurare, which has colonized wide coastal areas at the Spanish and Moroccan coasts since 2016. Temperature and salinity were higher in the SoG compared to its native habitat, implying that the alga is active during the whole seasonal cycle and grows optimally at the high salinities occurring in the SoG. Nitrate removal experiments indicate that the alga is able to linearly increase its N uptake rates following boost in nitrate concentration. Furthermore, R. okamurae N content ranged from 1.4% to 4.5% suggesting that this species has high N storage capacity potentially usable when the external N concentration decreases. These physiological characteristics would explain sharp growth of the alga in the SoG where high N concentrations are registered occasionally. | The analyses were supported by the project 10-ESMARES2-C4A2 (financed by Spanish Ministry of Ecological Transition and Demographic Challenge), the project UMA18-FEDERJA162 (financed by FEDER Andalucía 2014–2020), Project Blue Maro PID2020-116136RB-I00 financed by the Ministry of Science and Innovation of Spanish Government and the research groups RNM295 and RNM338 (Junta de Andalucía). BB acknowledges funding from a fellowship of CAPES/PRINT Program, Process n. 88887.374403/2019-00. We thank the Spanish Meteorological Agency (AEMET) for providing data. | Peer reviewed
Show more [+] Less [-]Pollution has negative effects on macrozoobenthic trait diversity in a large subtropical estuary Full text
2022
Pedelacq, María Eugenia | Garaffo, Griselda | Llanos, Elizabeth | Venturini, Natalia | Muniz, Pablo
Changes in species composition and relative abundance caused by pollution might have an impact on the community dynamics and ecosystem functioning. Macrobenthos are widely used as indicators of marine environmental health due to their sensitive to disturbance. The present study aims to evaluate spatial and temporal variability of functional diversity of macrobenthos of the Montevideo and Canelones coastal zone along a pre-established pollution gradient, based on Biological Traits Analysis, and functional diversity indices. Body-size”, “Feeding-mode”, “Habitat”, and “Indicator-role” were useful proxies to detect changes in environmental conditions in organically enriched habitats. FRic, FEve and FDis detected temporal variations but only FRic registered spatial variations. Differences among surveys would mainly reflect environmental variability caused by the 2009–2010 El Niño-Southern Oscillation event. Finally, negative correlations between FEve and FDis with AMBI suggest both indices as useful proxies of benthic environmental health, with potential to be used in monitoring and quality assessment programs.
Show more [+] Less [-]The application of the DAPSI(W)R(M) framework to the plastic pellets chain Full text
2022
Izar, G.M. | Choueri, R.B. | Martinez, S.T. | da Rocha, G.O. | Albergaria-Barbosa, A.C.R.
Single-use plastic, few global engagement and lack of policies contribute to the global challenge about plastic marine litter. This form of contamination can cause injury and death of marine wildlife. Microplastics (>5 mm) represent an important fraction of plastic litter. They include the plastic pellets that are used as raw material within plastic industry that can be unintentionally spilled into the environment during the industrial processes. In an initiative in order to facilitate the understanding and communication of plastic pellets as a social and environmental problem, we applied the Drivers-Activities-Pressures-State changes-Impacts (on Welfare)-Responses (as Measures) (DAPSI[W]R[M]) framework to plastic pellets chain. We also analyzed possible mitigating measures and their actions along the plastic pellets chain. This DAPSI(W)R(M) framework aim to show an overview of the plastic pellets chain and solutions for politicians and decision makers to help solve this socio-environmental problem that needs the engagement of all stakeholders involved.
Show more [+] Less [-]Challenges and opportunities for the future of recreational boat scrapping: The Spanish case Full text
2022
Martínez-Vázquez, Rosa María | Milán-García, Juan | De Pablo Valenciano, Jaime
Recreational boating is a leisure and sports activity that has aroused growing interest among users, tourists, and the general public. However, in the last decade, a problem has arisen concerning the abandonment of recreational boats. It is a problem that has become even more acute in times of economic recession. It is, therefore, necessary to find an urgent solution in order to reduce potential environmental risks. This work aims to analyze the state of the question through bibliometrics to know which topics are trending and contrast these findings with a Delphi analysis. The main results focus on the need for greater agility in the court adjudication process and the need for a specific legal framework for the scrapping of recreational craft. In conclusion, it is vital to integrate the circular economy into shipbuilding and scrapping processes to ensure the sustainability of the sector and the environment.
Show more [+] Less [-]Sources and spatiotemporal variations of nitrogen and phosphorus in Liaodong Bay, China Full text
2022
Hou, Wanli | Chen, Xi | Wu, Jinhao | Zhang, Chong | Yu, Jianghua | Bai, Jie | Chen, Tiantian
Excessive discharge of N and P pollutants results in deterioration of marine environment quality and reduction of sustainability and safety of marine ecology. Spatiotemporal variations characteristics and sources of N and P pollutants were determined based on the long-term monitoring data in Liaodong Bay. Results indicated that an evident spatiotemporal variation was investigated for nutrients. The highest concentrations of NH₃-N, NO₂-N, NO₃-N and PO₄-P were in spring (25.32 μg/L), summer (20.67 μg/L) and autumn (222.07 μg/L, 11.08 μg/L), respectively. The hot-spots of pollutants were mainly concentrated in estuarine and aquaculture areas. The hot spot of PO₄-P gradually extended to the middle of Liaodong Bay in autumn. In addition, pollution sources in each marine functional zone were different, the main pollution source was aquaculture wastewater, river input, domestic sewage. This study provided reasonable suggestions for effectively reducing N and P pollution in Liaodong Bay, and elsewhere.
Show more [+] Less [-]Occurrence of quinolones in cultured fish from Shandong Province, China and their health risk assessment Full text
2022
Wang, Xiaolin | Jiao, Yanni | Wang, Guoling | Li, Fenghua | Shao, Lijun | Zheng, Fengjia | Wang, Lin | Chen, Fangfang | Yang, Luping
The residue levels of 6 quinolones in 160 cultured fish samples from Shandong Province, China were investigated using UPLC-MS/MS. The detection rate was 43.1% and enrofloxacin had the highest detection rate as well as the highest residue concentration. The violation rates were 2.50% for the sum of enrofloxacin and ciprofloxacin and 1.25% for ofloxacin. Among the 9 fish species, quinolone contamination problems should receive more attention in Carp, Grass carp, Crucian and Catfish. The health risk assessment showed that when calculated by the maximum concentration, the estimated daily intakes (EDIs) of Carp, Grass carp and Crucian for the high consumption group accounted for more than 10% of the acceptable daily intakes (ADIs), indicating that a large intake of these fish species might pose a potential health risk and health risk monitoring of quinolones in cultured fish should be continually performed.
Show more [+] Less [-]Heavy metal concentrations in the Pacific sharpnose shark Rhizoprionodon longurio from the Santa Rosalia mining zone, Baja California Sur, Mexico Full text
2022
Martínez-Ayala, Julio Cesar | Galván-Magaña, Felipe | Tripp-Valdez, Arturo | Marmolejo-Rodríguez, Ana Judith | Piñón-Gimate, Alejandra | Huerta-Diaz, Miguel Angel | Sánchez-González, Alberto
Rhizoprionodon longurio is an important commercial species captured in an area with heavy metal presence due to the mining waste from Santa Rosalia, Gulf of California, and levels of heavy metals in its muscle remain unknown. This study aimed to investigate whether contamination levels are below the limits allowed for human consumption and to prevent health damage. Concentrations of essential (Cu, Fe, Mn, and Zn) and non-essential (Ag, Cd, and Pb) trace elements were determined in fifty-seven muscle samples of R. longurio. The average concentrations of Fe > Zn > Cu > Mn > Cd > Ag did not exceed the permissible limits for human consumption established by the Mexican norm, WHO, and FAO. The mineral daily ingestion was 0.10 to 0.53 % × 100 g of muscle, and the percentage of weekly consumption was 2.5 % to <12 % concerning corporal weight. The meat from this shark can be consumed due to its low toxic potential for human health.
Show more [+] Less [-]Baseline occurrence, distribution and sources of PAHs, TPH, and OCPs in surface sediments in Gorgan Bay, Iran Full text
2022
Zafarani, Ghasem Ghorbanzadeh | Karbalaei, Samaneh | Golshani, Reza | Pustokhina, Inna | Walker, Tony R.
Baseline polycyclic aromatic hydrocarbons (PAHs), total petroleum hydrocarbons (TPH) and organochlorine pesticides (OCPs) in surface sediments were measured in Gorgan Bay, Iran. Total PAHs, TPH, and OCPs concentrations ranged between 13.70 and 23.68 ng g⁻¹, 2.97 to 11.51 μg g⁻¹ dry weight, and below detection to 1.41 ng g⁻¹, respectively. Benzo [k] fluoranthene and anthracene had the highest (BkF; 19.77 ± 0.08 ng g⁻¹), and lowest (Ant; 4.38 ± 1.72 ng g⁻¹) individual PAH concentrations, respectively. The most abundant OCPs were β-Endosulfan, followed by methoxychlor and endrin. PAH isomeric ratios in sediments revealed that contamination originated from mixed sources, with a strong indication of pyrogenic sources. Ecological risk assessments based on sediment quality guidelines (SQGs) suggested that individual PAHs and OCPs posed low ecological risks in Gorgan Bay.
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