In situ chemical oxidation using persulfate is one alternative to remediate polycyclic aromatic hydrocarbon-contaminated soil; however, oxidation can lead to the formation of toxic and persistent by-products, and treatment efficiency can be dependent on environmental conditions. Temperature and soil matrix properties can dictate reaction rates and pathways, promoting oxidant activation or scavenging the free radicals generated. This research investigated the ability of persulfate to degrade anthracene in tropical environmental conditions. Batch tests were conducted for various persulfate systems (naturally and chelated-iron-activated), with an Oxisol contaminated with anthracene. Electron paramagnetic resonance (EPR) was used to identify free radicals formed. Naturally activated persulfate degraded more than 96% of the anthracene and its by-product anthraquinone after 90 days, considered more toxic and persistent, while the chelated-iron-activated persulfate system used was able to remove 70% of the anthracene. EPR measurements showed the coexistence of SO₄·⁻ and ·OH radicals. Sulfate radicals were formed by thermal activation at ambient temperatures (mean of 23.7 °C), and ·OH was formed by propagation reactions and hydrolysis in acidic conditions that lead to peroxide formation. In the naturally activated system, anthracene degradation was observed and SO₄·⁻ radicals were abundant, indicating that this treatment system can be effective in a typical tropical soil environment.

The present study was carried out in order to investigate the removal of soluble Mn²⁺ from an aqueous solution using Bacillus cereus. A manganese aqueous solution at 50 mg L⁻¹ was treated, and the product was less than 1 mg L⁻¹ of residual concentration, which complied with environmental regulations. Before the optimization, B. cereus was able to remove Mn²⁺ ions from an aqueous solution; however, the residual content was around 2.5 mg L⁻¹. Screening experiments aiming at defining the effects of the growth medium composition indicated that both casamino acid-peptone and yeast extract contributed to manganese removal. These experiments also showed the interaction between these two components of the culture media, nevertheless the use of glucose did not prove significant. Considering these observations, the Doehlert design was used to generate a response surface. The model was significant with the p value lower than 0.05 and the lack-of-fit not significant (p > 0.05). The optimized composition of the growth medium was defined as 0.5 g L⁻¹ of casamino acid-peptone and 0.25 g L⁻¹ of yeast extract, whereas glucose could be removed from the original growth medium. When the optimized condition of the growth medium was used, the time required for manganese removal was reduced from 21 to 8 days. After optimization, B. cereus was capable of producing high manganese removal, reducing the residual concentration to levels below 1.0 mg L⁻¹.

Greenhouse gas emissions from paddy soils respond differently to different combinations of crop root residues and N forms. An incubation experiment was carried out to explore the effect of four crop residues (milk vetch, ryegrass, winter wheat, and rape) and four nitrogen treatments (without fertilizer, urea, (NH₄)₂SO₄, and KNO₃) on CH₄, CO₂, and N₂O emissions in a paddy soil. Except in KNO₃ application treatments, CH₄ emissions of milk vetch residue treatments were significantly higher than those of the rest residue treatments. In the presence of milk vetch and ryegrass residues, urea application significantly increased CH₄ emissions in comparison to treatments without fertilizer. Urea significantly promoted CO₂ emissions, whereas (NH₄)₂SO₄ and KNO₃ significantly inhibited CO₂ emissions at all root residue treatments. Urea did not increase N₂O emissions, but (NH₄)₂SO₄ and KNO₃ promoted N₂O emissions at all residue treatments. In addition, KNO₃ had more effects on the increase of N₂O emissions than (NH₄)₂SO₄ in milk vetch-amended soils. Urea addition had no effect on global warming potentials, and (NH₄)₂SO₄ and KNO₃ addition significantly increased global warming potentials at all residue treatments except KNO₃ + winter wheat residue combination. Our results indicated that urea application had no additive effect on global warming when root residues were left in paddy soils, whereas (NH₄)₂SO₄ and KNO₃ application could increase the risk of global warming.

An optics theory-based mechanistic model for Secchi disk depth (Z SD) is advanced, tested, and applied for Cayuga Lake, NY. Robust data sets supported the initiative, including for (1) Z SD, (2) multiple light attenuation metrics, most importantly the beam attenuation (c) and particulate scattering (b ₚ) coefficients, and (3) measures of constituents responsible for contributions to b ₚ by phytoplankton (b ₒ) and minerogenic particles (b ₘ). The model features two serially connected links. The first link supports predictions of b ₚ from those for b ₒ and b ₘ. The second link provides predictions of Z SD based on those for b ₚ, utilizing an earlier optical theory radiative transfer equation. Recent advancements in mechanistically strong estimates of b ₘ, empirical estimates of b ₒ, and more widely available bulk measurements of c and b ₚ have enabled a transformation from a theory-based conceptual to this implementable Z SD model for lacustrine waters. The successfully tested model was applied to quantify the contributions of phytoplankton biomass, and minerogenic particle groups, such as terrigenous clay minerals and autochthonously produced calcite, to recent b ₚ and Z SD levels and dynamics. Moreover, it has utility for integration as a submodel into larger water quality models to upgrade their predictive capabilities for Z SD.

China’s rapid industrialization and urbanization has come at a staggering cost to the environment. In recent years, urban air pollution has been a serious environmental issue in Chinese cities that often hits news headlines in China and abroad. Based on the most recent data available, this paper employs two indices to examine the spatial and temporal patterns of some major air pollutants, including sulfur dioxide (SO₂), nitrogen dioxide (NO₂), zone (O₃), inhalable particulate matter (PM₁₀), and fine particulate matter (PM₂.₅), in China’s major cities and city regions. The results show that these pollutants display distinct spatial and seasonal variations. Overall, air pollution is much more serious in northern parts of the country, especially in large cities and a few major urban agglomerations, but we also find concentrations of air pollutants in urban agglomerations in southern China. Seasonally, Chinese cities suffer from air pollution especially PM₂.₅ pollution most in winter while summer is the cleanest season for most cities. Regional variations exist in composition of leading air pollutants and in influencing factors. Meteorological factors, such as wind speed, precipitation, temperature, air pressure, and relative humidity, often have important impacts on PM₂.₅ concentration, though their specific contributions vary across different cities. We argue that effective air pollution control policies should be regional in nature, but cross-border cooperation between regional and local governments is essential in order to tackle the problem of air pollution more effectively.

Biological organisms, used as test objects in pollution tests may be as good, or even more so, in detecting soil contamination, than chemical analyses. In this study, we used five bioassay methods, together chemical and physical-chemical tests, for comprehensive environmental assessment of contaminated soils located at the industrial waste storage sites in North-West Russia. Examined soils have been contaminated with various toxic pollutants at various times in the past. The level of contamination by Hg, Pb, Cd, Zn, Со, As, Cr, Cu, Mn, V, and As in studied soils varied depending on a site type. The concentrations of these elements were 20 to 43 times higher than the regional geochemical baseline at all sites. The organic pollutants (3,4-benzo(a)pyrene and polychlorinated biphenyls) were found at some sites. Ecotoxicological studies were carried out using test organisms from different taxonomic groups: ciliates Paramecium caudatum Ehrenberg, green algae Scenedesmus quadricauda (Turp.) Brebisson, seeds of common oat Avena sativa L.,wheat Triticum aestivum L., and a natural community of microorganisms. All the employed bioassays revealed some of the aspects of contamination, supported or supplemented each other’s estimates, and gave excellent performance at the sampling sites.

In this paper, quaternized β-cyclodextrin–montmorillonite composite (QCD-MMT) was obtained and absorption properties of Cr(VI), methyl orange and p-nitrophenol were studied. QCD was prepared by 2,3-epoxypropyltrimethylammonium chloride and β-cyclodextrin (β-CD). QCD-MMT was obtained by reaction between QCD and montmorillonite suspensions, which could be attributed to the montmorillonite cation ion exchange properties. β-CD cavities of this composite were expected to capture organic molecules through inclusion, while montmorillonite units acted as the adsorption sites for metals. QCD-MMT was characterized by FT-IR, elemental analysis, XRD, SEM-EDX, and TGA. Adsorptions of Cr(VI), methyl orange, and p-nitrophenol were highly dependent on adsorbent dose, initial concentration, temperature, contact time, and pH. Adsorption kinetics of Cr(VI), methyl orange, and p-nitrophenol followed the pseudo-second-order model. Meanwhile, adsorption of Cr(VI) fit better in the Freundlich model, inferring a multilayer adsorption, while the adsorption of methyl orange and p-nitrophenol fit better in Langmuir model, inferring a monolayer adsorption. Thermodynamic analysis showed that the adsorptions were all endothermic process and could be spontaneous at given temperature range, except for Cr(VI), of which adsorption should be at much higher temperature. Overall, QCD-MMT exhibited potential for practical applications in the treatment of both metal ions and organic pollutants.

On November 5, 2015, after the collapse of the Fundão tailings dam, a massive amount of iron mine waste was released into the Doce River system in southeast Brazil. The aim of our study was to determine the mass fractions of potentially toxic elements in soil affected by the deposition of material by the waste wave. A preliminary screening was performed with portable X-ray fluorescence spectrometry (PXRF) and principal component analysis (PCA). The EPA 3050B method was further applied to digest the samples for quantitative determination of As, Ba, Cr, Cu, Mn, Ni, Pb, V, and Zn by inductively coupled plasma mass spectrometry. PCA was useful to classify the mine waste samples based on the Fe signal from the PXRF spectra, in spite of the heterogeneous nature of the material discharged into the Doce River system. The anomalous levels of As (up to 164 mg kg⁻¹) and Mn (as high as 2410 mg kg⁻¹) found in some mine waste and affected soil samples are within the background ranges typically observed in the soils of the Iron Quadrangle region. The toxicity characteristic leaching procedure shows no evidence of hazards regarding As, but a high natural background level of Mn was found in the mobile fraction. This preliminary environmental assessment highlights the importance of evaluation of long-term effects on soil directly impacted, as well as on the aquatic biota of the Doce River system and adjacent coastal environment given the large affected area, which includes regions with varying background levels of toxic elements.

In this study, the optimum conditions for the ammonia removal from aqueous solution by microwave-assisted air stripping have been investigated at pH 11. Ammonia solution with five different initial ammonia concentrations was prepared synthetically. The Taguchi method was applied to optimize the ammonia removal conditions. Initial ammonia concentration, air flow rate, temperature, stirring speed, microwave radiation power, and radiation time were defined as the optimization parameters. Experiments were carried out at five different levels for each operational parameter. The results of the experiments revealed that 1800 ppm of initial ammonia concentration, 7.5 L min⁻¹ of air flow rate, 60 °C of temperature, 500 rpm of stirring speed, and 500 W of microwave radiation power for 180 min. of microwave radiation time are optimum conditions for complete ammonia removal. In addition to present experimental data, the optimum operational conditions predicted by the balanced characteristics of orthogonal array were confirmed experimentally. Finally, the effect of optimization parameters was discussed in detail. Graphical Abstract ᅟ

Actual problems of water ecosystem pollution require the ecological classification and the identification of the most influential parameters on the variability of water quality, stressing the importance of both in the realization of the sustainable water management principles according to the Water Framework Directive European Union (WFD EU), and the preservation of the quality of the environment. The aim of this paper was the assessment of the ecological status of water quality and calculating water pollution index (WPI) of the Danube River in Serbia. For all surface waters, the WFD requires “good ecological status,” i.e., low level changes of the natural state that occur as a result of human activities by 2015. The assessment was based on the data obtained from ten hydrological measuring stations on the Danube River in Serbia for 2014. It was ascertained that the ecological status of the Danube River water quality was class III, corresponding to “moderate ecological status” and deviating from the required “good ecological status.” According to the calculated WPI = 1.352, the water pollution of the Danube River in Serbia was characterized as moderately polluted and corresponded to class III of surface water. The ecosystem approach clearly indicated that the concentration of physico-chemical parameters of the watercourse deviated from the target values. Therefore, there is an urgent need to take some measures to prevent pollution and improve the water quality of the Danube River as an integral part of the environment in Serbia.