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Levels and trends of polycyclic aromatic hydrocarbons in the Indo-Pacific humpback dolphins from the Pearl River Estuary (2012–2017) Full text
2018
Gui, Duan | Zhang, Lingli | Zhan, Fengping | Liu, Wen | Yu, Xinjian | Chen, Laiguo | Wu, Yuping
We investigated the levels and trends of the 16 USEPA priority PAHs in the blubber of 37 Indo-Pacific humpback dolphins sampled during the period 2012–2017 from the Pearl River Estuary (PRE), China. Σ16PAHs concentrations (17.6–6080 ng g−1 wet weight) were at median level compared to dolphin species worldwide. Humpback dolphins affiliated with the hotspots of PAHs, had significantly higher levels of Σ16PAHs than individuals from the other areas in the PRE. Moreover, dolphins stranded on the coast of Lingdingyang are significantly more contaminated by Σ16PAHs than those in the West-four region of the PRE, which appears to reflect the heterogeneous distribution of PAHs in the environment. A marked decline in blubber Σ16PAHs levels is observed over the studied period, with the control of a range of confounding factors. The trend is strongly and statistically significant (p < 0.0001), indicating that the loading of PAHs are gradually being reduced.
Show more [+] Less [-]Bioavailable dissolved organic matter and its spatio-temporal variation in a river dominated tropical brackish water Lagoon, India Full text
2018
Kanuri, Vishnu Vardhan | Muduli, Pradipta R. | R.S., Robin | B., Charan Kumar | A., Lova Raju | Patra, Sivaji | Gupta, G.V.M. | Nageswara Rao, G. | A.V., Raman | B.R., Subramanian
Bioavailable dissolved organic carbon (BDOC), nitrogen (BDON) and their degradation rate constants were measured for the Chilika Lagoon, India. Long-term laboratory incubation experiments (90 days) were conducted at a constant temperature (25 °C) to quantify the bioavailable dissolved organic matter (DOM) and the possible degradation rate coefficients. The results showed that 41 ± 12% of dissolved organic carbon (DOC) and 47 ± 17% of dissolved organic nitrogen (DON) were BDOC and BDON respectively, with their stoichiometry found to be higher than the Redfield ratio. A first order exponential non-linear fitting routine was used to estimate pool sizes. The degradation rate constant (k) for the BDOC varied from 0.127–0.329 d−1 and BDON from 0.043–0.306 d−1 during the study period. Half-lives of the BDOC and BDON ranged from 2.1–5.4 and 2.2–15.9 days, respectively. Overall, the results showed that a fraction of the labile DON was transported from the lagoon to the adjacent coastal sea.
Show more [+] Less [-]Temporal metal concentration in coastal sediment at the north region of Persian Gulf Full text
2018
Maghrebi, Mohsen | Karbassi, Abdolreza | Lak, Raziyeh | Noori, Roohollah | Sadrinasab, Masoud
The purpose of this article is to study, result of metal concentration in two-sediment cores from Persian Gulf. Age of sediment is determined by C14 isotope method and bulk concentration is determined by ICP. This research output shows that, age of BandareAbbas core back to 9660 and Bushehr core to 15,600 years ago. Also,concentration in BandareAbbas and Bushehr cores respectively change as, As (1.08–11.76 Vs 5.2–13.09), Ba (15.03–129.5 Vs 73.9–120.4), Cd (0.09–0.46 Vs 0.09–0.18), Li (5.66–58.5 Vs 15.3–33.4), Mo (0.3–0.75 Vs 0.3–0.8), Mg (7928.4–15,503.9 Vs 13,102.8–17,227.8), Mn (110.6–566.4 Vs 279.3–429.1), Na (8905.47–27,993.3 Vs 9357.7–27,541.4), Ni (13.3–110.3 Vs 37.1–88.4), Pb (0.5–42.5 Vs 2.5–13.6), Sr (407.5–1773.2 Vs 440.3–1596.9), Zn (13.05–71.2Vs22.4–50.5), Fe (0.46–4.07 Vs 1.7–3.18), Ca (9.25–23.3 Vs 13.8–19.2) and Al (0.62–8.15 Vs 2.48–4.65). Moreover different pollution index investigation represent that except Ca, the rest of the metal elements do not show pollution.
Show more [+] Less [-]Microbial communities in seawater from an Arctic and a temperate Norwegian fjord and their potentials for biodegradation of chemically dispersed oil at low seawater temperatures Full text
2018
Ribicic, Deni | Netzer, Roman | Winkler, Anika | Brakstad, Odd Gunnar
Microbial communities in seawater from an Arctic and a temperate Norwegian fjord and their potentials for biodegradation of chemically dispersed oil at low seawater temperatures Full text
2018
Ribicic, Deni | Netzer, Roman | Winkler, Anika | Brakstad, Odd Gunnar
Biodegradation of chemically dispersed oil at low temperature (0–2 °C) was compared in natural seawater from Arctic (Svalbard) and a temperate (Norway) fjords. The oil was premixed with a dispersant (Corexit 9500) and small-droplet oil dispersions prepared. Faster biotransformation of n-alkanes in the Arctic than in the temperate seawater were associated with the initially higher abundance of the alkane-degrading genus Oleispira in the Arctic than the temperate seawater. Comparable transformation of aromatic hydrocarbons was further associated with the late emergences Cycloclasticus in both seawater sources. The results showed that chemically dispersed oil may be rapidly biodegraded by microbial communities in Arctic seawater. Compared to oil biodegradation studies at higher seawater temperatures, longer lag-periods were experienced here, and may be attributed to both microbial and oil properties at these low seawater temperatures.
Show more [+] Less [-]Microbial communities in seawater from an Arctic and a temperate Norwegian fjord and their potentials for biodegradation of chemically dispersed oil at low seawater temperatures | Microbial communities in seawater from an Arctic and a temperate Norwegian fjord and their potentials for biodegradation of chemically dispersed oil at low seawater temperatures Full text
2018
Ribicic, Deni | Netzer, Roman | Winkler, Anika | Brakstad, Odd Gunnar
Biodegradation of chemically dispersed oil at low temperature (0–2 °C) was compared in natural seawater from Arctic (Svalbard) and a temperate (Norway) fjords. The oil was premixed with a dispersant (Corexit 9500) and small-droplet oil dispersions prepared. Faster biotransformation of n-alkanes in the Arctic than in the temperate seawater were associated with the initially higher abundance of the alkane-degrading genus Oleispira in the Arctic than the temperate seawater. Comparable transformation of aromatic hydrocarbons was further associated with the late emergences Cycloclasticus in both seawater sources. The results showed that chemically dispersed oil may be rapidly biodegraded by microbial communities in Arctic seawater. Compared to oil biodegradation studies at higher seawater temperatures, longer lag-periods were experienced here, and may be attributed to both microbial and oil properties at these low seawater temperatures. | acceptedVersion
Show more [+] Less [-]Modeling for the allocation of oil spill recovery capacity considering environmental and economic factors Full text
2018
Ha, Min-Jae
This study presents a regional oil spill risk assessment and capacities for marine oil spill response in Korea. The risk assessment of oil spill is carried out using both causal factors and environmental/economic factors. The weight of each parameter is calculated using the Analytic Hierarchy Process (AHP). Final regional risk degrees of oil spill are estimated by combining the degree and weight of each existing parameter. From these estimated risk levels, oil recovery capacities were determined with reference to the recovery target of 7500kl specified in existing standards. The estimates were deemed feasible, and provided a more balanced distribution of resources than existing capacities set according to current standards.
Show more [+] Less [-]Spatial distribution and ecological risk assessment of the coastal surface sediments from the Red Sea, northwest Saudi Arabia Full text
2018
Kahal, Ali Y. | El-Sorogy, Abdelbaset S. | Alfaifi, Hussain J. | Almadani, Sattam | Ghrefat, Habes A.
To assess the spatial distribution and ecological risk assessment along the Red Sea coast, Saudi Arabia, 30 samples were collected for aluminum, chromium, copper, zinc, cadmium, lead, mercury, iron, cobalt, nickel and organic matter analysis. The descending order of metal concentrations was Al > Fe > Cr > Cu > Zn > Ni > Co > Pb > Hg > Cd. Average values of enrichment factor of Hg, Cd, Cu, Co, Cr, Ni, Pb and Zn were higher than 2 (209.50, 25.52, 20.36, 9.62, 7.28, 6.52, 6.21 and 6.07 respectively), which means anthropogenic sources of these metals. The average levels most of the studied metals were lower than those of the background shale and the earth crust and those recorded along most worldwide coasts, while the average values of zinc, copper, cobalt and nickel were higher than the values recorded from the Red Sea coast, the Gulf of Aqaba and some Caspian Sea coasts. The Duba bulk plant-Saudi Aramco, Duba refinery station and the tourist resort were the possible anthropogenic sources of pollutants in the southern part of the study area; and the landfilling, cement factory and Duba port and shipment operations in the central part, while the landfilling resulting from construction of the green Duba power plant and crowded fish boats were the possible sources in the northern part.
Show more [+] Less [-]Polychlorinated biphenyls (PCBs) in recreational marina sediments of San Diego Bay, southern California Full text
2018
Neira, Carlos | Vales, Melissa | Mendoza, Guillermo | Hoh, Eunha | Levin, Lisa A.
Polychlorinated biphenyl (PCB) concentrations were determined in surface sediments from three recreational marinas in San Diego Bay, California. Total PCB concentrations ranged from 23 to 153, 31–294, and 151–1387ngg−1 for Shelter Island Yacht Basin (SIYB), Harbor Island West (HW) and Harbor Island East (HE), respectively. PCB concentrations were significantly higher in HE and PCB group composition differed relative to HW and SIYB, which were not significantly different from each other in concentration or group composition. In marina sediments there was a predominance (82–85%) of heavier molecular weight PCBs with homologous groups (6CL-7CL) comprising 59% of the total. In HE 75% of the sites exceeded the effect range median (ERM), and toxicity equivalence (TEQ dioxin-like PCBs) values were higher relative to those of HW and SIYB, suggesting a potential ecotoxicological risk.
Show more [+] Less [-]Screening of human and veterinary pharmaceuticals in estuarine waters: A baseline assessment for the Tejo estuary Full text
2018
Reis-Santos, Patrick | Pais, Miguel | Duarte, Bernardo | Caçador, Isabel | Freitas, Andreia | Vila Pouca, Ana S. | Barbosa, Jorge | Leston, Sara | Rosa, João | Ramos, Fernando | Cabral, Henrique N. | Gillanders, Bronwyn M. | Fonseca, Vanessa F.
Screening of human and veterinary pharmaceuticals in estuarine waters: A baseline assessment for the Tejo estuary Full text
2018
Reis-Santos, Patrick | Pais, Miguel | Duarte, Bernardo | Caçador, Isabel | Freitas, Andreia | Vila Pouca, Ana S. | Barbosa, Jorge | Leston, Sara | Rosa, João | Ramos, Fernando | Cabral, Henrique N. | Gillanders, Bronwyn M. | Fonseca, Vanessa F.
We investigated the presence of 66 human and veterinary pharmaceuticals from seven therapeutic groups in surface waters of the Tejo estuary. Collection sites covered the entire estuary and included areas near main river inflows and wastewater treatment outfalls, traversing urban, agriculture, aquaculture, and nature reserve areas. Detection of pharmaceuticals was performed via UHPLC-TOF-MS. Pharmaceuticals were found in all sites (32 different compounds in total). Antibiotics, β-blockers, antihypertensives and anti-inflammatories were the most frequently detected (>90%), with variation in concentrations reflecting the multifaceted nature of estuarine surroundings (accumulated site contamination between 15 and 351 ng L−1). Higher concentrations of antidepressant Sertraline (304 ng L−1), non-steroidal anti-inflammatory Diclofenac (51.8 ng L−1), lipid regulator Gemfibrozil (77.0 ng L−1), antihypertensive Ibersartan (161.9 ng L−1) or antibiotic Doxycycline (128.0 ng L−1), among others, though localized may potentially impact key estuarine functions or services. Ultimately, results provide a baseline for regulatory information and future biota evaluations.
Show more [+] Less [-]Screening of human and veterinary pharmaceuticals in estuarine waters: A baseline assessment for the Tejo estuary Full text
2018
Reis Santos, Patrick | Pais, Miguel Pessanha | Duarte, Bernardo | Caçador, Isabel | Freitas, Andreia | Vila Pouca, Ana S. | Barbosa, Jorge | Leston, Sara | Rosa, João | Ramos, Fernando | Cabral, Henrique | Gillanders, Bronwyn M. | Fonseca, Vanessa
We investigated the presence of 66 human and veterinary pharmaceuticals from seven therapeutic groups in surface waters of the Tejo estuary. Collection sites covered the entire estuary and included areas near main river inflows and wastewater treatment outfalls, traversing urban, agriculture, aquaculture, and nature reserve areas. Detection of pharmaceuticals was performed via UHPLC-TOF-MS. Pharmaceuticals were found in all sites (32 different compounds in total). Antibiotics, β-blockers, antihypertensives and anti-inflammatories were the most frequently detected (>90%), with variation in concentrations reflecting the multifaceted nature of estuarine surroundings (accumulated site contamination between 15 and 351 ng L-1). Higher concentrations of antidepressant Sertraline (304 ng L-1), non-steroidal anti-inflammatory Diclofenac (51.8 ng L-1), lipid regulator Gemfibrozil (77.0 ng L-1), antihypertensive Ibersartan (161.9 ng L-1) or antibiotic Doxycycline (128.0 ng L-1), among others, though localized may potentially impact key estuarine functions or services. Ultimately, results provide a baseline for regulatory information and future biota evaluations. | info:eu-repo/semantics/publishedVersion
Show more [+] Less [-]Long term development of Bathing Water Quality at the German Baltic coast: spatial patterns, problems and model simulations Full text
2018
Buer, Anna-Lucia | Gyraite, Greta | Wegener, Patrick | Lange, Xaver | Katarzyte, Marija | Hauk, Gerhard | Schernewski, Gerald
Bathing water quality plays a key role for public health, is highly important for recreational tourism and therefore monitored in the EU-Directive 2006/7/EC. To identify pollution hot spots, sources and impacts of the directive-change in 2006, including a change of indicator organisms, we evaluated monitoring data of the past 15 years, collected own data, determined survival rates of indicator organisms and applied hydrodynamic modelling in a micro-tidal-system.Due to higher survival rates under turbid conditions and restricted water exchange, shallow, eutrophic bays and lagoons are hot spots of microbial pollution. Rain events cause high microbial emission and distribution. Based on different decay rates, the ratio of E. coli to Enterococci can hint towards a pollution source. Including rain predictions, currents and winds, hydrodynamic models can then assess the daily risk of microbial pollution at each bathing site. They are an important tool to modify beach management and event-based monitoring.
Show more [+] Less [-]Sorption and desorption of selected pharmaceuticals by polyethylene microplastics Full text
2018
Razanajatovo, Roger Mamitiana | Ding, Jiannan | Zhang, Shanshan | Jiang, Hang | Zou, Hua
The aim of the present study was to evaluate the sorption and desorption of sulfamethoxazole (SMX), propranolol (PRP) and sertraline (SER) by polyethylene (PE) microplastics in water. After the 96 h mixture, the sorption percentages of pharmaceuticals on PE microplastics decreased according to the following order: SER (28.61%) > PRP (21.61%) > SMX (15.31%). The sorption kinetics were fitted well with the pseudo-second-order model. Both linear and Freundlich models were able to describe the sorption isotherm. The results suggest that the sorption process of the pharmaceuticals may be adequately described by their hydrophobicity and electrostatic interactions. The desorption results showed that 8% and 4% of PRP and SER, respectively, were released from the microplastics within 48 h, but the sorption of SMX was irreversible. The results indicate the potential risks of PRP and SER for bioaccumulation in aquatic organisms via ingestion of the microplastics in aquatic environments.
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