Sustainable development has by now become an element deeply integrated in the everyday design. It has many shades and may be found under many names. We speak about resiliency in design and procurement of passive, ecologic, plus energy, or nZEB buildings. Nevertheless, if we look closely, we may distinguish certain characteristic ideas. First, sustainable development of societies and urbanization processes should be consistent on a deeper level than presently, and be included within design processes, organization, and planning, as well as modernization and redevelopment procedures of existing urban tissue. Secondly, urbanization should be perceived holistically, as an interaction and harmonious development of both natural and manmade environments, with solutions based on the best technical and technological standards available. Lastly, described ideas are achievable only, if we include continuous cooperation between urban planners, architects, specialist consultants, as well as energy-efficient interdisciplinary solutions to achieve high standard energy measures. One of the thresholds is economic feasibility; the other is health and well-being of the users which should always be discussed as a priority. This paper—outside a brief theoretical approach to initial procedures in design management—will dwell on transformation and modernization of an existing building belonging to the Warsaw University of Technology, one of the oldest universities in Poland, its founding dating back to the beginning of the twentieth century. In 2015, a Nordic Finance Mechanism grant dedicated to the nZEB technology transfer from Norway to Poland was awarded to a group of researchers from Warsaw University of Technology and NTNU Trondheim. The main aim of the project is implementation of nZEB knowledge in Poland, as well as preparation of two integrated concept designs for public (University) buildings as exemplary case studies which could act as the benchmarks for other public buildings.

This paper deals with the adsorption of an anionic dye, Eriochrome Black T (EBT), from aqueous solutions onto sawdust, which is a natural, eco-friendly, widespread, and a low-cost bio sorbent. The aim of the work is to append values to the wood industry waste. Thus, sawdust was used as adsorbent in both batch reactor (BR) and fixed bed column (FBC), and various operating parameters influencing the adsorption process were investigated. The kinetic and the equilibrium adsorption results were found to agree with, respectively, the prediction of the pseudo-second-order equation and the Langmuir model. This latter allowed also the determination of the maximum EBT dye adsorbed amount, which was found to be about 40.96 mg EBT per gram of sawdust at pH = 4, corresponding to % dye removal of about 80%. In addition, the influence of various parameters on the dye adsorption, such as the adsorbent dose, the aqueous phase pH, and the initial dye concentration, was also examined. In batch experiments, The EBT adsorbed amount was found to increase either by increasing the amount of sawdust or by decreasing the aqueous phase pH, whereas, in the fixed bed column, the EBT retention was found to increase by decreasing the flow rate of the dye through the column. The overall data indicate that the EBT adsorption is mainly governed by the electrostatic interactions occurring between the adsorbent material and the dye.

Sunflower stalk–derived biochars (BC) were prepared at various temperatures (i.e., 500, 650, and 1000 °C) and demonstrated as a highly efficient catalyst in persulfate (PS) activation for the oxidation of p-nitrophenol (PNP) at 60 °C. The apparent PNP oxidation rate constant in the BC500 (0.1543 L mol⁻¹ S⁻¹), BC650 (0.6062 L mol⁻¹ S⁻¹), or BC1000 (2.1379 L mol⁻¹ S⁻¹) containing PS system was about 2, 8 and 28 times higher than that in PS/PNP (0.0751 L mol⁻¹ S⁻¹) system, respectively. The effect of reaction temperature on PNP oxidation was also investigated. Furthermore, the radical quenching tests and electron paramagnetic resonance spectroscopy (EPR) were employed to investigate the sulfate and hydroxyl radicals for PNP oxidation. The Raman results suggested that the defective sites on biochars possess vital role for oxidation of PNP in PS system. The possible activation pathway of PS/BC was proposed that the defective sites on BC were involved for weakening the O–O bond in PS and subsequently cleaving O–O bond by heat to generate sulfate radical. The oxidation of PNP at low concentration (below 100 μg L⁻¹) was completely removed in urban wastewater by PS/BC system within 30 min. This work would provide new insights into PS activation by BC catalyst and afford a promising method for organic pollutant removal in high-temperature wastewater.

High contents of azo dyes and heavy metals enter surface waters with the wastewater from dying and dye-manufacturing industries and pose serious threat to fish. In the present study, changes in the ultra-morphological features of the scale have been evaluated as indicators of the stress of lethal and sublethal concentrations of an azo dye Acid Black-1 (AB-1, CI 20470), zinc (Zn), and their mixture AB-1 + Zn to Labeo rohita. Fish were exposed for 96 h to lethal concentration (LC) causing 0–70% mortality, i.e., LC₀, LC₂₀, LC₅₀, and LC₇₀ of AB-1 (4, 6, 8, and 10 mg/L respectively) and Zn (25, 50, 55, and 60 mg/L respectively) and LC₀, LC₅₀, and LC₇₀ of AB-1 + Zn (2 + 15, 2 + 20, and 2 + 25 mg/L respectively). Subchronic exposures of 150 days were given to 1/12, 1/6, and 1/3 of 96 h LC₅₀ values of AB-1, Zn, and AB-1 + Zn. After each exposure, the fish were kept for a recovery period of 90 days. Breakage of circuli, erosion and breakage of lepidonts, uprooting of tubercles, and disappearance of intercircular teeth were observed in all the fish, after 96 h exposure to AB-1, Zn, and AB-1 + Zn. However, damage to focus and holes were common on the scales of Zn-exposed fish. The mixture AB-1 + Zn was more toxic than either of the two as loss of circuli, lepidonts, and intercircular teeth, and sloughing of surface were observed in the scales after 96 h exposure to 2 + 25 mg/L. Damage at this concentration was more than the damage at 8/10 mg/L AB-1 and 55/60 mg/L Zn. After 150 days of exposure, damage due to sublethal concentrations was more than the damage due to all the concentrations of 96 h exposure. Irregular and sloughed circuli were common at 2 + 1.79 and 2 + 3.59 mg/L AB-1 + Zn. Cracks all over the surface (2 + 7.18 mg/L), calcium projections (2 + 3.59 and 2 + 7.18 mg/L), and holes (2 + 7.18 mg/L) hint towards synergistic toxicity of the mixture. It seems that the present dye and metal formed complexes with collagen and osteoblastic cells of the scale that caused an increase in damage during the post-exposure period. Scales of 2 + 7.18 mg/L AB-1 + Zn exposed fish were completely devoid of the normal architectural pattern on the 90th day of the recovery period. Changes in the ultra-morphology of scales at LC₀ (0% mortality) and sublethal concentrations show that these are early indicators of the stress of minute quantities of dyes and metals in water. This is a first report on the cumulative toxicity of the two most abundant components of textile industry effluents.

Tibial dyschondroplasia (TD) is most the common tibiotarsal bone disease in rapidly growing birds throughout the world. There is accumulating evidence that COX-2 abnormal expression in tibia plays an important role in TD progression. So, the regulation of COX-2 is an ever more appealing target for therapeutic intervention in TD. Astragaloside IV has an indispensable role in maintaining COX-2 expression in many diseases. So, we designed this study to use Astragaloside IV (AST-IV) against TD-affected chickens. A total of 180 Arbor Acres chickens were randomly divided in the control group, TD group, and Astr (AST-IV-treated chickens) group. During the experiment, mortality, feed conversion ratio, physiological changes, biochemical criterion, liver antioxidant enzymes, and gene expression of COX-2 were examined in all the chicken groups at various days. The results showed that AST-IV administration restored the growth performance and tibia lesions and decreased the mortality as compared with TD chickens. The biochemical criterion (ALP, AST, and ALT) of serum and liver antioxidant enzymes (SOD, GSH-Px, MDA, and T-AOC) improved after the administration of AST-IV. The COX-2 gene was upregulated significantly (P < 0.05) in TD chickens. Whereas, AST-IV treatment downregulated both gene and protein expression of COX-2 significantly (P < 0.05) in TD-affected chickens. AST-IV recovered tibial dyschondroplasia chickens by increasing the growth performance, ameliorating tibial cartilage damage, and decreasing COX-2 expression. In conclusion, AST-IV can be used to prevent thiram-induced TD in chickens.

Cobalt (Co) adsorption onto saline soil was investigated in this study. The effect of pH, interaction time, and initial concentration of Co on adsorption were evaluated empirically to screen the appropriate operating conditions. Three biosurfactant products (i.e., surfactin, trehalose lipids, rhamnolipid) each at two concentrations (1 and 2 critical micelle concentrations (CMCs)) were applied during Co adsorption. The adsorption kinetic models were explored and results indicated that the pseudo-second-order kinetic model fit the experimental data the best. Four isotherms, including Langmuir, Freundlich, Temkin, and Redlich-Peterson were used for regulating the Co adsorption with and without the addition of each biosurfactant. The research results show that Co has low mobility even with the existence of a biosurfactant. The findings help to better understand the adsorption behaviour of Co in saline soil so as to develop applicable remediation options.

The plasma electrolytic oxidation (PEO) technique was used to prepare photocatalytic S-TiO₂ coatings on Ti sheets; the incorporation of the S ions was possible from the electrolyte for modifying the structural and optics characteristics of the material. In this work, substrates of Ti (ASME SB-265 of 20 × 20 × 1 mm) were used in a PEO process in 10 min, using constant voltage pulses of 340 V with frequency of 1 kHz and duty cycles of 10% and of 30%. Solutions with H₂SO₄ (0.1 M) and CH₄N₂S (52 and 79 mM) were used as electrolytes. X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy (EDS) were utilized to analyze the surface morphology, crystalline phase, and chemical composition of the samples. According to the results, the catalyst coatings had microporous structure and contained anatase-rutile TiO₂ nanocrystalline mixture, until 73.2% rutile and 26.8% anatase in the samples grown with 30% duty cycle and the lowest concentration of CH₄N₂S. From the EDS measurements, the incorporation of sulfur ions to the coatings was 0.08 wt%. 99.5% reduction efficiency of Cr(VI)-EDTA with sunlight was observed after 2 h; it was determined by diphenyl carbazide spectrophotometric method. These coatings have potential for effective sunlight heterogeneous photoreduction of this toxic, cumulative, and non-biodegradable heavy metal that contaminates the soil and water and is a serious risk to sustainability, ecosystems, and human health.

Ester-functionalized pyridinium ionic liquids (ILs), 1-decyloxycarbonylmethylpyridinium chloride (PyrСOOC₁₀-Cl), and 1-dodecyloxycarbonylmethylpyridinium chloride (PyrСOOC₁₂-Cl) have been synthesized and studied for their environmental toxicity. Simple long-chain pyridinium ILs, 1-dodecylpyridinium chloride (PyrC₁₂-Cl), and commercial disinfectant cetylpyridinium chloride (CPC) were used as reference compounds. Both ester-functionalized ILs and CPC showed significantly reduced antibacterial activity compared to PyrC₁₂-Cl. However, ester-functionalized ILs were found to have excellent antifungal activity towards Candida albicans fungus strains, similar to PyrC₁₂-Cl and much higher than for CPC. The molecular docking of ILs in the active site of the known antifungal target N-myristoyltransferase (Nmt) C. albicans has been conducted. The obtained results indicate the possibility of ILs binding into the Nmt pocket. The high stability of the complexes, especially for PyrCOOC₁₀-Cl, is ensured by hydrogen bonding, electrostatic anion-pi interactions, as well as hydrophobic pi-alkyl and alkyl interactions that was confirmed by calculated binding energy values. The acute toxicity studies of ester-functionalized ILs on D. rerio (zebrafish) hydrobiont have shown their dramatically reduced ecotoxicity compared to PyrC₁₂-Cl and CPC. Thus, LD₅₀ values of 15.2 mg/L and 16.8 mg/L were obtained for PyrCOOC₁₀-Cl and PyrCOOC₁₂-Cl, respectively, whereas CPC had LD₅₀ value of 0.018 mg/L. The primary biodegradation test CEC L-33-A93 of ILs indicated an improved biodegradability of ester-functionalized compounds compared to simple long-chain ILs. Based on the obtained results, PyrCOOC₁₀-Cl may be considered as very promising cationic biocide due to the combination of soft antimicrobial activity and reduced ecotoxicity, as well as improved biodegradability.

A range of different studies has been performed in order to design and develop photocatalysts that work efficiently under visible (and near-infrared) irradiation as well as to improve photons absorption with improved reactor design. While there is consensus on the importance of photocatalysis for environmental applications and the necessity to utilized solar irradiation (or visible-light) as driving force for these processes, it is not yet clear how to get there. Discussion on the future steps towards visible-light photocatalysis for environmental application is of great interest to scientific and industrial communities and the present paper reviews and discusses the two main approaches, band-gap engineering for efficient solar-activated catalysts and reactor designs for improved photons absorption. Common misconceptions and drawbacks of each technology are also examined together with insights for future progress.