In view of the toxic nature of Beryllium and its compounds the disposal of waste materials containing beryllium needs prior evaluation. The present study was undertaken to obtain information on the leachability and immobilisation of beryllium from solid waste red-mud generated in processing Beryl at the Beryllium Metal Plant at Vashi, New Bombay. The studies showed that 62% of the total beryllium in red-mud can be extracted by water by repeated leaching over a period of 445 d. The mixing of the waste material with cement and casting into cement blocks reduced the leachability of beryllium to 0.11% which got further reduced to 0.02% by thermal curing of cement blocks.

A ten year survey of water quality in 330 Massachusetts streams was conducted to examine the rate and pattern of recovery from acidification. Meta-analysis was used to combine the results of the 330 non-parametric trend tests into an overall test for trend in a variety of water quality variables including pH, acid neutralizing capacity (ANC), and major inorganic ions. Analysis of trends in the raw data indicates both pH and ANC are increasing. After detrending for variations in stream runoff, we estimate the streams are recovering from acidification at a rate of +0.021 pH units/year and +2.4μeq/L/year, for pH and ANC respectively. These trends appear to be related to declines in sulfate (−1.8μeq/L/year), while base cation trends were mixed. Meta-analysis reveals the trends are not always homogeneous between seasons or between sites.While it is commonly assumed that the low ANC systems are most ‘sensitive’ to changes in acid or base inputs, we found the greatest rates of change in ANC were associated with the high ANC systems. The greatest increases in pH were seen in the low ANC streams as expected. The results also suggest streams respond quickly to changes in precipitation inputs and stream monitoring networks may be valuable as an early detection technique for changes in environmental quality.

The effectiveness of ammonia stripping at different air flow rates (0, 1 and 5 L min⁻¹) and lime dosages (0 and 10 000 mg L⁻¹ calcium hydroxide) was investigated in aeration tanks in a laboratory as a pretreatment to remove ammoniacal-nitrogen and organic load (COD) in landfill leachate. Ammoniacal-nitrogen removal at 20 °C after one day was 70% for 0 L min⁻¹, 81% for 1 L min⁻¹ and 90% for 5 L min⁻¹ regardless of the origin of leachate. Ammonia loss was mainly due to desorption through water surface. The levels of phosphorus and COD were only reduced by lime precipitation, with 85% and 93% phosphorus removal and 24% and 47% COD removed for leachate from the Junk Bay Landfill (JB) and Gin Drinkers' Bay Landfill (GDB) respectively. The highly significant difference (P<0.05) of COD removal between JB and GDB might be due to the different age of the two landfills studied. Leachate quality and configuration of the treatment reactor were important factors affecting the efficiency of ammonia removal by stripping processes.

The Pb content in orchard soils at Mission Peninsula, Michigan was determined to assess the impact of historical lead arsenate applications. Soil samples at 72 sites located in five orchards were collected at depths of 2−, 20-, 50−, and 100 cm. Atomic absorption spectroscopy was used to quantify Pb levels (jig g⁻¹). Mean surface Pb levels at individual orchards ranged from <1–136 pg g⁻¹ and rapidly decreased with depth, to < 1-5 μg g⁻¹ at 100 cm. The impact of textural class and slope angle on Pb levels was also analyzed. Correlation coefficients linking Pb levels with textural class were weak, ranging from 0.21 to −0.07. Varying slope steepness and slope position within orchards failed to affect the spatial pattern of soil Pb.Soil Pb levels were also compared at 5 sites along local roads with varying levels of automobile traffic. Samples were collected 1 m from the roadside at the same depth intervals studied in orchards. Average daily traffic along the busiest roadsites ranged from 8200 to 16 000; these sites had Pb levels of 90–210 μg g⁻¹. Such locales had Pb levels similar to the more intensively sprayed orchards.

A new plastic-lined high-pressure squeezing device has been developed for the extraction of soil pore solutions. At a maximum pressure of 1100 kg cm⁻² the water recovery ranged between 30 and 55% of the total water content. Pressure dependent squeezing experiments showed a general increase in Si, Mn, Mg, Ca, K, Na, Al, Fe, Cd, and Zn concentrations with progressive pore water extraction and increasing pressure, indicating that micro pore solutes have the highest concentrations of solutes. Soil samples with moisture contents of more than about 15% generally provided enough water for major and trace element analyses. The data do not reveal any contamination of the pore fluids from the squeezing device. An advantage of this method is that the solution could be closely related to a specific soil horizon on a cm scale and also to the time of sampling. A further application of this squeezing method is the possibility of pressure dependent sequential squeezing to obtain fluids from different pore spaces.

Total mercury (Hg) and methylmercury (MeHg) concentrations were determined in sediments and in the polychaete wormNereis diversicolor at 13 stations of a brackish water intertidal mudflat of the Scheldt estuary. Hg and MeHg concentrations in sediments ranged from 144 to 1192 ng g⁻¹ dw and from 0.8 to 6 ng g⁻¹ dw, respectively. Both Hg and MeHg concentrations increased with an increase of organic matter (OM) content and fine grain fraction. In contrast, Hg accumulation byN. diversicolor was significantly (p<0.05) higher at stations with sandy sediments (mean value: 125 ng g⁻¹ dw) than at stations with muddy sediments (mean value, 80 ng g⁻¹), probably because Hg availability for bioaccumulation at muddy stations was reduced by high OM content of the muddy sediments. MeHg accounted for an average of 0.7% of the total Hg in sediments and 18% of the total Hg inN. diversicolor. Seasonal variations significantly affected Hg concentrations in sediments and MeHg inN. diversicolor. Total Hg concentrations in sediments were significantly (p<0.05) higher in autumn and winter than in spring and summer whereas MeHg concentrations were lowest in winter compared to the other seasons. On the other hand, total Hg concentrations in the worms were lowest in spring whereas MeHg concentrations were significantly (p<0.01) higher in spring and summer than in autumn and winter.

Atmospheric transparency over Qena/Egypt has been studied for direct solar radiation values, which were calculated from global and diffuse solar radiation measurements. The monthly mean of the instantaneously transparency coefficient has been analyzed in clear-, cloudy-, and mixed days. In general, the value of the transparency coefficient was found to decrease towards the sunset hours, owing to the high aerosol content expected in the afternoon time. The clouds deplete significantly the solar energy passed through them and then lead to an obvious decreasing in the transparency coefficient. A try to calculate the transparency coefficient has been done with the aid of the more available global solar radiation measurements. The results are in a good agreement with those obtained for direct solar radiation. The relation between the daily average of the transparency coefficient and the corresponding mean diffuse fraction has been investigated. High correlations were found between them in all months and empirical formulae were obtained.

Allium test has already been used to determine cytotoxicity of waste drilling fluids. In the present work the cytotoxicity of four pure chemicals (Defoamex, Idthin 400, Magco Thin and Slick Pipe) was investigated. Those chemicals are components of drilling fluids, therefore, they are usually constituents of oil and gas industry waste waters. The tested chemicals were prepared in 1:9 dilution and cytotoxic effects on root-tip meristem ofAllium ascalonicum were analysed after 24-, 48- and 72-hour-treatments. All samples showed cytotoxicity which was proved by cytogenetic parameters such as inhibition of mitotic activity and increase of mitotic abnormalities and chromosomal aberrations in comparison with the control. Almost all mitotic abnormalities induced by four chemicals tested were the result of disturbed spindle mechanisms accompanied with stickiness. Slick Pipe revealed the most prominent mitodepressive effect and induced a high number of abnormalities. It caused a significant decrease of mitotic activity and increase of mitotic abnormalities after all three treatment durations, while chemicals Defoamex and Magco Thin showed a significant decrease of mitotic activity only after 72-hour-treatment. Chemicals Defoamex, Idthin 400 and Magco Thin revealed a significant increase of mitotic abnormalities after 48- and 72-hour-treatments.

A study was carried out recently to determine the pollution level of waters in the Karachi harbour and adjoining backwaters. Nine locations were selected, four in the backwaters, two on the seaside, and three in the main navigable channel. Four of these locations were deliberately selected to coincide with those of a previous study conducted in 1982 by Pakistan Council of Scientific and Industrial Research (PCSIR) so that the values for the concentration of different pollutants could be compared. Analysis was conducted for pH, bicarbonates, Total Solids, Volatile matter in Total Solids, Chlorides, Sulphates, Calcium, Magnesium, Sodium and Potassium.The results indicate that the composition of sea water as far as the concentration of above constituents is concerned has not changed much since the time of the PCSIR study, viz 1982, except that the organic matter concentration has increased. The reasons for this increase in organic loading and its possible impact are discussed in this paper.