The main rivers (Aude, Orb, Herault) that discharge into the Gulf of Lions and the west bank tributaries of the Rhone River including the Gardon have former non-ferrous metal mines in their upper drainage basin. Using unpublished data and data from the literature, this study provides an integrated overview of the contamination of water and sediment along the continent-sea continuum and of its impacts on the biota and on human health. In the upper part of these basins, water and stream sediments are enriched in metal(-loids) compared to median European concentrations. Arsenic is the main contaminant in the rivers Aude and Gardon d’Anduze, Sb in the Orb and Gardon d’Alès, and Tl in the Herault river. A rapid reduction in dissolved and particulate concentrations was systematically observed along the river due to dilution and precipitation. The high concentrations of metal(-loid)s observed suggest that the former mining activity still represents a potential threat for the environment, but the lack of high temporal resolution monitoring, especially during Mediterranean floods, prevents accurate assessment of metal fluxes from these rivers to the Mediterranean Sea. Studies dedicated to the impacts on human health are too rare, given that studies have shown a higher rate of arsenic-specific cancer near Salsigne mine in the Aude River basin and cases of saturnism in children in the upper Herault River basin. These studies underline the need to take environmental health issues into consideration not only in these watersheds but around the entire Mediterranean basin, which harbors numerous metalliferous ores that have been mined for millennia.

In rural populations, the proximity to areas with intensive pesticide application represents a risk factor of xenobiotic exposure. Here, we investigated whether newborns born to mothers residing in an area with intensive pesticide application show alterations in placental and neonatal morphometric standards, umbilical cord blood (UCB) biochemical parameters, and/or biomarkers related to oxidative stress and oxidative damage. Samples were collected from 151 healthy pregnant women residing in a rural area (rural group; RG) during the pesticide spraying (SS) and nonspraying (NSS) seasons, as well as from women from an urban population (control group; CG), and grouped according to the delivery type (vaginal or cesarean). In the vaginal delivery group, the placental weight and placental index were higher in the RG groups than in the CG (p = 0.01), whereas in the cesarean delivery group, newborn weight was lower in the RG-SS group than in the CG. In the RG-SS group, UCB erythrocyte osmotic fragility and the DNA damage index (DI) were higher, and superoxide dismutase (SOD) activity was lower than in the RG-NSS group. Acetylcholinesterase and SOD activities were found to be inversely correlated with the DI.

The nitrate (NO₃ ⁻) pollution of aquatic systems in Northeast China is a severe problem. To identify NO₃ ⁻ sources and transformations in different zones with different land uses in the Taizi River Basin, ion-exchange methods were utilized to determine the concentrations and isotopic compositions (δ¹⁵N and δ¹⁸O) of NO₃ ⁻ and chloride (Cl⁻). Results showed that Cl⁻ concentrations ranged from 2.7 to 73.4 mg/L. Cl⁻ concentrations were the highest in zone 8 and the lowest in zone 1. NO₃ ⁻ concentrations ranged from 0.3 to 27.4 mg/L and were the highest in zone 1 and the lowest in zone 8. During the sampling period, δ¹⁵N–NO₃ ⁻ values varied from 3.8 to 37.2‰, and δ¹⁸O–NO₃ ⁻ values ranged from −0.5 to 10.4‰. δ¹⁵N–NO₃ ⁻ values were the highest in zone 9 and the lowest in zone 1. The differences in physicochemical parameters and NO₃ ⁻ isotopes may be affected by land use and biogeochemical nitrogen processes in different zones. The combined analysis of dual isotopes (δ¹⁵N–NO₃ ⁻ and δ¹⁸O–NO₃ ⁻) and NO₃ ⁻/Cl⁻ versus Cl⁻ showed that different sources contributed NO₃ ⁻ to different zones during the sampling period. Soil N, manure, and sewage were the main NO₃ ⁻ sources in the Taizi River Basin. In zones 1 to 6, the δ¹⁵N–NO₃ ⁻ values of almost all samples were more than 10‰, NO₃ ⁻/Cl⁻ values were high, and Cl⁻ molar concentration was low during the sampling period. These findings suggested that the volatilization and nitrification of soil NH₄ ⁺ might be related to NO₃ ⁻ sources in zones 1 to 6. A 1:1 to 2:1 linear relationship between δ¹⁵N–NO₃ ⁻ and δ¹⁸O–NO₃ ⁻ combined with the significantly negative relationship between ln (NO₃ ⁻) and δ¹⁸O–NO₃ ⁻ indicated that denitrification affected NO₃ ⁻ distribution in zones 8 to 9 during the sampling period. These results can provide useful information to control NO₃ ⁻ concentrations in different zones in Taizi River Basin.

The individual and combined biochemical responses of erythromycin and ketoconazole have been examined in an organism representative of the aquatic environment, crucian carp (Carassius auratus). The possible interactions between erythromycin and ketoconazole were investigated on the bioaccumulation and the expression of biotransformation enzymes 7-ethoxyresorufin-O-deethylase (EROD) and glutathione S-transferase (GST), and an antioxidant defense enzyme superoxide dismutase (SOD) in fish tissues. After 14 days of combined exposure (erythromycin + ketoconazole), the addition of ketoconazole at nominal concentrations of 0.2, 2, and 20 μg/L significantly increased the accumulation of erythromycin in fish bile; however, elevated erythromycin accumulation levels were not observed in the other test tissues. The inductions of EROD and SOD activity to erythromycin were inhibited by the combined exposure of ketoconazole in most cases; however, the GST activity returned to normal with exposure time and concentration of combined administration. From the tested pharmaceutical mixtures, it indicated that certain specific combinations may pose some perturbations in biochemical responses in fish and also provide a better understanding of the effects of toxic mixtures.

Appropriate water-saving and nitrogen management strategies are critical for achieving sustainable agricultural development in dry sub-humid areas of the Chinese Loess Plateau. The present study was conducted in 2004, 2005, 2008, and 2012 based on a long-term field experiment and aimed to investigate the coupled impacts of mulching and N fertilization on maize yield, water use efficiency (WUE), and residual soil nitrate (RSN) accumulated in the soil profile (0–200 cm). The results demonstrated that mulch is conducive to increasing summer maize yield. The plastic film-mulched ridge and straw-mulched furrow (RF) treatment significantly increased maize yield across the studied period, while the straw mulch (SM) treatment did not significantly increase maize yield until the third experimental year. Compared with SM, the RF treatment showed more significant and positive effects on maize yield, WUE, and RSN accumulated in the 0–200 cm soil depth. N fertilization significantly increased maize yield and WUE, but no significant differences were observed when 120 and 240 kg N ha⁻¹ were applied. The N240 treatment was characterized by relatively high NO₃ ⁻-N accumulation in 0–200 cm soil depth and low ratios of soil nitrate in the upper to the lower soil layers, indicating a considerable potential for NO₃ ⁻-N leaching. Averaged across years, economic optimum N fertilizer rates (Nops) were 154, 148, and 150 kg N ha⁻¹ for the no mulch, RF, and SM treatments, respectively. This suggested that 25.8–51.2% of N rate can be reduced while maintaining an acceptably high maize yield. Additionally, understanding NO₃ ⁻-N depth distribution in 0–100 cm soil profile can adequately predict and represent the characteristics of NO₃ ⁻-N accumulated in the 100–200 cm and 0–200 cm soil layers because of their significant correlations, thus saving time and money. In conclusion, the practice of RF combined with properly reduced farmers’ N rate (~ 150 kg N ha⁻¹) is the preferred option for maize production in the Chinese Loess Plateau, and further research is required to investigate the effects of mulching on summer maize under Nop conditions.

The used electronic product (UEP) has attracted the worldwide attentions because part of e-waste may be exported from developed countries to developing countries in the name of UEP. On the basis of large foreign trade data of electronic products (e-products), this study adopted the trade data approach (TDA) to quantify the potential exports of UEP in Macau, taking a case study of personal computers (PCs). The results show that the desktop mainframes, LCD monitors, and CRT monitors have more low-unit-value trades with higher trade volumes in the past 10 years, while the laptop and tablet PCs, as the newer technologies, owned the higher ratios of the high-unit-value trades. During the period of 2005–2015, the total mean exports for used laptop and tablet PCs, desktop mainframes, and LCD monitors were approximately 18,592, 79,957, and 43,177 units, respectively, while the possible export volume of used CRT monitors was higher, up to 430,098 units in 2000–2010. Noticed that these potential export volumes could be the lower bound because not all used PCs may be shipped using the PC trade code. For all the four kinds of used PCs, the majority (61.6–98.82%) of the export volumes have gone to Hong Kong, followed by Mainland China and Taiwan. Since 2011, there was no CRT monitor export; however, the other kinds of used PC exports will still exist in Macau in the future. The outcomes are helpful to understand and manage the current export situations of used products in Macau, and can also provide a reference for other countries and regions.

Oil spills over seawater and dye pollutants in water cause economic and environmental damage every year. Among various methods to deal oil spill problems, the use of porous materials has been proven as an effective strategy. In recent years, graphene-based porous sorbents have been synthesized to address the shortcomings associated with conventional sorbents such as their low uptake capacity, slow sorption rate, and non-recyclability. This article reviews the research undertaken to control oil spillage using three-dimensional (3D) graphene-based materials. The use of these materials for removal of dyes and miscellaneous environmental pollutants from water is explored and the application of various multifunctional 3D oil sorbents synthesized by surface modification technique is presented. The future prospects and limitations of these materials as sorbents are also discussed.

Oxygenated polycyclic aromatic hydrocarbons (oxyPAHs) are directly discharged into the atmosphere with exhaust gas from diesel engine automobiles and industry and are also generated by photo-oxidation and/or microbial metabolism of parent polycyclic aromatic hydrocarbons (PAHs). They are widely distributed in environment, especially around urban areas. We evaluated the effects of exposure to oxyPAHs as acenaphthenequinone (ANQ), 7,12-benz(a)anthracenequinone (BAQ), 1,4-naphthoquinone (NAQ), and 9,10-phenanethrenequinone (PHQ) in Japanese medaka (Oryzias latipes) embryos. ANQ (>2720 μg/L) caused caving in the yolk sac, and BAQ (>22.4 μg/L) caused tanning of the oil droplet. Additionally, NAQ (>314 μg/L) and PHQ (>734 μg/L) stopped development of medaka embryos beginning 2 days after the start of exposure. The hatched larvae from embryos exposed to ANQ, BAQ, NAQ, or PHQ at 518, 9.86, 36.5, or 80.7 μg/L, respectively, exhibited incomplete development of the cephalic region, incomplete palate, unabsorbed and hypertrophied yolk sac, tubular heart, altered axial curvature, and poor swimming ability. These symptoms were similar to those observed in blue sac disease, which is caused by exposure to PAHs.

In this study, a modeling framework based on the theory of SPAtially Referenced Regression On Watershed attributes (SPARROW) model was developed to identify impaired river reaches with respect to total nitrogen (TN) and estimate the TN sources in the Xin’anjiang River basin, which had limited monitoring sites. A Bayesian approach was applied to estimate the mean values and uncertainties of parameters, including land use export coefficients and in-stream attention rates. Based on the parameters, the midranges (25–75 %) of annual TN concentrations were assessed by the model and 4.5 % of river reaches in the basin were found to be with higher impaired probabilities (namely [TN] > 1.5 mg/l) than other reaches. The amount and yields of TN discharged from diffuse sources were estimated for each county in the basin. The results suggested that Tunxi City had the highest TN yields from farm land and population, while the highest TN yields in Huangshan City were from tea plantations. The outcomes of this study will guide the implementation of practical management measures to reduce TN loads.

Toxic cyanobacterial blooms are often observed in freshwaters and may reflect the increased eutrophication of these environments and alterations in climate. Cyanotoxins, such as microcystins (MCs), are an effective threat to many life forms, ranging from plants to humans. Despite the research conducted to date on cyanotoxins, the risks associated to the use of contaminated water in agriculture require further elucidation. To tackle this aim, a research was conducted with the root-vegetable Daucus carota. The specific aims of this work were the following: (i) to evaluate the effects of MC-LR on the plant growth and photosynthesis; (ii) to evaluate the nutritional quality of carrot roots; and (iii) to measure bioaccumulation. To this purpose, young carrots were grown in soil during 1 month in natural conditions and exposed to Mycrocystis aeruginosa aqueous extracts containing environmentally realistic concentrations of MC-LR (10 and 50 MC-LR μg/L). The results showed that MC-LR may decrease root growth after 28 days of exposure to 50 μg/L and increase photosynthetic efficiency. We also observed changes in mineral and vitamin content in carrots as a result of the exposure to contaminated water. Moreover, MC-LR was detected in carrot roots by ELISA at very low concentration 5.23 ± 0.47 ng MC eq./g FW. The soil retained 52.7 % of the toxin potentially available for plants. This result could be attributed to MC-LR adsorption by soil particles or due to microbial degradation of the toxin. We conclude that the prolonged use of MC-LR-contaminated water may affect crop growth, alter the nutritional value of vegetable products, and potentiate contamination.