A soil multi-species, SMS, experimental test system consisting of the natural microbial community, five collembolan species and a predatory mite along with either Enchytraeus crypticus or the earthworm Eisenia fetida were exposed to α-cypermethrin. A comparison of the performance of these two types of SMSs is given to aid the development of a standard test system. E. fetida had a positive effect on the majority of the species, reducing the negative insecticide effect. E. fetida affected the species sensitivity and decreased the degradation of the insecticide due to the organic matter incorporation of earthworm food. After 8 weeks, the EC50 was 0.76 mg kg−1 for enchytraeids and ranged between 2.7 and 18.9 mg kg−1 for collembolans, more sensitive than previously observed with single species. Changes observed in the community structure and function illustrates the strength of a multi-species test system as an ecotoxicological tool compared to single species tests.

Persistent organic pollutants (POPs) and stable isotopes were measured in muscle from fledglings of two arctic seabird species, Northern fulmar (Fulmarus glacialis) and Black-legged kittiwakes (Rissa tridactyla). The purpose was to compare POP concentrations between species, in an age class that is highly vulnerable to POPs but little studied, relate to diet using stable isotopes, and quantify differences across life stages (egg to adult). Northern fulmar fledglings had significantly higher POP concentrations than kittiwake, consistent with results reported for adults of these species. Surprisingly, carbon and nitrogen stable isotopes did not differ between species, which does not match data for, or the known feeding ecology, of the adults. Fulmar/kittiwake POP concentration ratios varied across life stages indicating variable POP exposure and accumulation with age in seabirds, indicating that of the use of avian species-specific thresholds should only be done with caution in ecosystem-based POP risk management.

We investigated effects of arsenate (AsV), chromate (CrVI) and sulfate on As and Cr uptake and translocation by arsenic hyperaccumulator Pteris vittata (PV), which was exposed to AsV, CrVI and sulfate at 0, 0.05, 0.25 or 1.25 mM for 2-wk in hydroponic system. PV was effective in accumulating large amounts of As (4598 and 1160 mg/kg in the fronds and roots at 0.05 mM AsV) and Cr (234 and 12,630 mg/kg in the fronds and roots at 0.05 mM CrVI). However, when co-present, AsV and CrVI acted as inhibitors, negatively impacting their accumulation in PV. Arsenic accumulation in the fronds was reduced by 92% and Cr by 26%, indicating reduced As and Cr translocation. However, addition of sulfate increased uptake and translocation of As by 26–28% and Cr by 1.63 fold. This experiment demonstrated that As and Cr inhibited each other in uptake and translocation by PV but sulfate enhanced As and Cr uptake and translocation by PV.

Particle reactive organic contaminants in estuarine sediments can lead to various environmental problems affecting ecosystem and public health. In this study, the occurrence and homologous distribution pattern of quaternary ammonium compounds (QACs) in the surficial sediments collected from the Pearl River Estuary (PRE), China were examined along with polychlorinated biphenyls (PCBs) and polybrominated diphenylethers (PBDEs). The composition pattern of the QACs was found to be uniform in most of the sediments analyzed throughout the PRE, and the average composition pattern was identical to that determined in the sewage sludge from Guangzhou, the biggest city in the PRE. Dialkyldimethylammonium compounds, the most abundant type of QACs, positively correlated to the total concentrations of PCBs and PBDEs in most of the sediments with similar composition patterns. Therefore, the QACs are proposed as potential tracers to evaluate the transport of sewage-derived pollution in estuarine environments.

Perfluorinated chemicals (PFCs) have been recognised as environmental pollutants that require monitoring. A modified polar organic chemical integrative sampler (POCIS) is able to quantify aqueous PFCs. However, with varying external water velocity, PFC sampling rates (Rs) may change, affecting accuracy of derived water concentrations. To facilitate field deployment of this sampler, two methods of in-situ calibration were investigated: performance reference compounds (PRCs) and passive flow monitors (PFMs). Increased Rs's (by factors of 1.2–1.9) with PFM loss rate (g d−1) were observed for some PFCs. Results indicate PFMs can be used to correct PFC specific Rs's for more reliable estimates of environmental concentrations with a precision of about 0.01 L d−1. Empirical models presented provide an improved means for aquatic monitoring of PFCs. The PRC approach was unsuccessful, confirming concern as to its applicability with such samplers.

The presence of 10 anticancer drugs was studied along the entire urban water cycle -from hospital effluents through urban wastewater treatment plant till surface waters- and their potential environmental risk was assessed. Azathioprine, etoposide, docetaxel, paclitaxel, methotrexate, cyclophosphamide, tamoxifen and ciprofloxacin were detected in hospital effluent and in the urban influent of the sewage treatment plant although most of them were totally eliminated after WWTP. Only cyclophosphamide, tamoxifen and ciprofloxacin were found in both WWTP effluent and in the receiving river at a concentration range between nd-20 ng L−1, 25–38 ng L−1 and 7–103 ng L−1 respectively. Tamoxifen and ciprofloxacin, commonly used for veterinary practices, were also detected in the river upstream the sewage discharge. In addition, they both were considered to pose a potential risk to the environment based on the levels found in the WWTP effluent together with their ecotoxicological impact in selected organisms.

Occurrence and removal of 81 representative Pharmaceutical Active Compounds (PhACs) were assessed in a municipal WWTP located in a highly industrialized area, with partial water reuse after UV tertiary treatment and discharge to a Mediterranean river. Water monitoring was performed in an integrated way at different points in the WWTP and river along three seasons.Consistent differences between therapeutic classes were observed in terms of influent concentration, removal efficiencies and seasonal variation. Conventional (primary and secondary) treatment was unable to completely remove numerous compounds and UV-based tertiary treatment played a complementary role for some of them. Industrial activity influence was highlighted in terms of PhACs presence and seasonal distribution.Even if global WWTP effluent impact on the studied river appeared to be minor, PhACs resulted widespread pollutants in river waters. Contamination can be particularly critical in summer in water scarcity areas, when water flow decreases considerably.

Complex toxicant mixtures present in estuarine sediments often render contaminant screening unfeasible and compromise determining causation. HepG2 cells were subjected to bioassays with sediment extracts obtained with a series of progressively polar solvents plus a crude extract. The sediments were collected from an impacted area of an estuary otherwise regarded as pristine, whose stressors result mostly from aquaculture effluents and hydrodynamic shifts that enhance particle deposition. Compared to a reference scenario, the most polar extracts yielded highest cytotoxicity while higher genotoxicity (including oxidative damage) was elicited by non-polar solvents. While the former caused effects similar to those expected from biocides, the latter triggered effects compatible with known pro-mutagens like PAHs, even though the overall levels of toxicants were considered of low risk. The results indicate that the approach may constitute an effective line-of-evidence to infer on the predominant set of hazardous contaminants present in complex environmental mixtures.

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) belong to the group of persistent organic pollutants, highly toxic environmental pollutants that include hydrophobic compounds with the tendency to bioaccumulate. Earthworms (Eisenia andrei) were exposed to PCDD/Fs-contaminated soil, and changes in their lipophilic structures and the gene expression of their defense molecules were followed. Damage to the intestinal wall and adjacent chloragogenous tissue was observed. Further, the up-regulation of the expression of several genes was detected. On the basis of these results, the mechanism of the impact of PCDD/Fs on earthworms has been proposed. Dioxins that accumulate in the lipophilic structures cause an increase in reactive oxidative species that triggers oxidative stress followed by the gene expression of two molecules that play a role in protection against oxidant toxicity, calreticulin (CRT) and Hsp70. Moreover, the effect of microbial biomass on the expression of coelomic cytolytic factor (CCF), a pattern recognition receptor, was also observed.

In Asia, the evaluation of black carbon (BC) using global aerosol-transport models has been incomplete due to a lack of available measurements. Recently, new measurements and datasets at various Asian sites have become available for use in model validation. In this study, we compared the BC mass concentrations obtained by an aerosol-coupled global nonhydrostatic model adopting a uniform-grid system with in-situ measurements and other models over Asia. The results revealed that our model, as well as other global models, was unable to reproduce the observed BC values at most sites in China and India, most likely due to strong local hotspots. To overcome the inconsistency between the models and measurements, we developed a new aerosol-transport model using a stretched-grid system for high-resolution simulations with up to approximately 10 km grids. Our model can be used as a global-to-regional seamless aerosol-transport model for low to high horizontal resolution simulations.