The copper pots with an inner coating layer of tin have been remarkably used in many countries for a long time. In this study, leaching of some metals from tin-lined copper pots into food simulators at different pHs (4, 5.5, 7, and 8.5) during boiling processing (95 °C for 1, 2, and 3 h) or refrigerated storage (4 °C for 1, 2, and 3 days) was investigated. Citric acid and sodium hydroxide were used to adjust the pH of food simulators. The leaching concentrations of metals were analyzed by inductively coupled plasma optical emission spectrometers (ICP-OES). Scanning electron microscopy (SEM) was used to indicate the surface morphological properties of cookware. Based on the preliminary experiments, metals including Al, Sn, Cu, Mn, Fe, Ca, Na, Cr, Mg, and Zn were selected to analyze in acidic treatments. Furthermore, Al, Cu, Sn, Na, and Ca were analyzed for neutral and alkaline ones. Results showed that the boiling temperature for 3 h resulted in a much higher migration of metals compared with cold storage for 3 days. Mn and Cr showed the lowest metal concentration during cooking and cold storage, respectively. The concentration of Sn in acidic simulators was remarkably higher than the other metals during both cooking and refrigerated storage. However, Ca during cold storage, as well as Na during both cooking and cold storage, showed the most migration in alkaline solutions, among the other pHs. An acidic simulator with pH 4 showed the most considerable release of metals from copper pots. SEM results indicated more intense surface corrosion by acidic solution (pH 4) than alkaline one. In general, longer cooking and cold storage durations led to increasing metals release. The migration of the studied metals demonstrates the impurities of the tin layer of these cookwares that may lead to acute and/or chronic diseases.

The outbreak of COVID-19 in Daegu, South Korea, early in 2020 has led this metropolitan city to become one of the major hotspots in the world. This study investigates the association of meteorology and the new daily COVID-19 confirmed cases and the effects of the city lockdown on the variation in criteria air pollutants (CAPs) in Daegu. Ambient temperature and relative humidity were negatively correlated to the new daily cases and played an important role in the spread of COVID-19. Wind speed could enhance the virus transmission through the inhalation of aerosols and/or droplets and contact with fomites. The lockdown has directly decreased the concentrations of CAPs. In particular, reductions of 3.75% (PM₁₀), 30.9% (PM₂.₅), 36.7% (NO₂), 43.7% (CO), and 21.3% (SO₂) between the period before and during the outbreak were observed over the entire city. An increase in O₃ (71.1%) was affected by natural processes and photochemical formation other than the lockdown effects. The three central districts were the areas most affected by the virus and showed the highest reductions in CAPs (except for O₃) during the outbreak. Apart from the influence of the lockdown, the decreasing trend in CAPs may be a result of the actions taken by the government to mitigate air pollutants nationwide since 2019. The results of this study can be useful for government and medical organizations to understand the behavior of the virus in the atmosphere. Further studies are necessary to explore the detailed influences of the lockdown on the environment and public life.

The removal of Hg from contaminated aquatic media is of major importance, taking into consideration the highly toxic character of the element. One of the most promising water treatment technologies is adsorption by low cost adsorbents, such as activated carbon produced by agricultural byproducts. In this study, activated carbon in granular form (GAC) was produced using pistachio shells from Aegina Island (Greece). Two main GAC products have been synthesized. The first one was chemically activated using ZnCl₂. The second one was further treated with Na₂S in order to introduce S atoms on the functional groups. The effectiveness of synthesized GAC products for Hg removal was evaluated by conducting batch equilibrium and kinetic experiments. It was found that sulfurization was able to increase by a factor of more than 2 the adsorptive capacity of activated carbon. Namely the maximum adsorption capacity was 73 mg/g for the simple GAC and increased up to 166 mg/g for the S-modified product. The kinetics of adsorption was described with almost equivalent precision using the pseudo-first and the pseudo-second order models, a behavior which is often observed in adsorption experiments, depending on the experimental conditions. The value of activation energy EA was found to be negative (− 18.8 kJ/mol) in the case of simple GAC and positive (8.27 kJ/mol), in the case of S-modified GAC, suggesting that Hg adsorption on the modified carbon follows a different mechanism, closer to chemisorption processes.

The main objective of the present study is to determine the kinetics, thermodynamics, and adsorption mechanism of the oxytetracycline (OTC) on rice husk ash (RHA). The adsorbent was characterized by scanning electronic microscopy, Fourier transform infrared spectroscopy, and nitrogen physisorption. Batch studies were carried out to evaluate the influence of the adsorbent dose, initial concentration, contact time, temperature, and initial pH. RHA was characterized as having heterogeneous, fibrous, and porous particles, consisting predominantly of silica. The removal of OTC depends on the pH of the medium, which is favored at acid pH values. The kinetic data followed the Bangham model, which indicated an OTC diffusion in the pores of RHA, although this was not the only process, as demonstrated through the use of the Weber-Morris model (IPD model). The Sips isotherm best represents the experimental results of the equilibrium study. It was found that the adsorption process was spontaneous and endothermic. The highest adsorption capacity was found at a pH in the range of 4–6, when the OTC is in its zwitterion form and the surface of the RHA is positively charged, thus permitting electrostatic interactions and the formation of hydrogen bonds between the adsorbent and adsorbate molecules. These findings demonstrate the potential of rice husk ash to remove oxytetracycline from water.

In this paper, we are reporting a simple hydrothermal technique for preparation of MoSe₂ nanostructures (nanourchins and nanosheets) using selenium and sodium molybdate as precursors. Samples are characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Raman spectroscopy, UV-Vis spectroscopy, Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The FESEM revealed that the morphology of materials was varying significantly by changing pH value during synthesis. Photocatalytic degradation of anionic dye (MO), cationic dye (MB), and reduction of Cr(VI) into Cr(III) were performed. Nanosheets and nanourchins showed higher photocatalytic activity, enhanced photocatalytic degradation efficiency is correlated with the higher •OH radical concentration, crystallinity of material, and large surface area as evident through XPS, XRD, and BET, respectively. Photocatalysis mechanism along with role of reactive species (•OH and holes) were explained using trapping experiments. Identification of degraded products was carried out using high-performance liquid chromatography (HPLC). Reaction kinetics and reusability of materials were also studied; wherein, it was observed that the materials have reusable properties.

Maternal smoking during pregnancy has detrimental effects on fetal development. The current review examined the differences in offspring’s bone mineral density (BMD) between mothers smoked during pregnancy and those who did not. A systematic review and meta-analysis on the studies investigating the influence of maternal smoking during pregnancy on children or neonates’ bone measures published up to October 30, 2018, was performed. BMD results measured at different body sites were pooled and then fixed or random effect models were used based on the presence of heterogeneity. The desired pooled effect size was the offspring’s BMD mean difference with 95% confidence interval between smoker and non-smoker mothers. Sensitivity analysis was performed for birth weight and current weight, two important mediator/confounders causing heterogeneity. Overall, eight studies consisting of 17,931 participants aged from infancy to 18 years were included. According to the fixed effect model, the mean of BMD in offspring whose mothers smoked during pregnancy was 0.01 g/cm² lower than those with non-smoker mothers (95% CI = − 0.02 to − 0.002). However, subgroup meta-analysis adjusted for birth weight and current weight demonstrated no significant mean difference between BMD of children with smoker and non-smoker mothers (d = 0.06, 95% CI = −0.04 to 0.16, p value = 0.25 and d = − 0.005, 95% CI = − 0.01 to 0.004, p value = 0.28, respectively). According to available studies, it is suggested that maternal smoking during pregnancy does not have direct effect on the offspring’s BMD. Instead, this association might be confounded by other factors such as placental weight, birth weight, and current body size of children.

The palm (Elaeis guineensis), known as dendê, is an important oleaginous Brazilian plant with a high performance of oil production. In this work, a 2³ full experimental design was performed and the response surface method (RSM) was used to indicate the optimum parameter of caffeine adsorption on Elaeis guineensis endocarp activated carbon, since the endocarp is the main by-product from dendê oil production. It was set the adsorbent point of zero charge (pHₚzc), and the material was characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). The RSM results indicate removal efficiency (%) at the optimal conditions, 0.20 g of adsorbent, and caffeine initial concentration of 20 mg/L, and acidic medium was about 95%. Based on ANOVA and F test (Fcₐₗcᵤₗₐₜₑd > Fₛₜₐₙdₐᵣd), the mathematical/statistical model obtained fits well to the experimental data. The overall kinetic studies showed time was achieved after 5 h and caffeine adsorption followed the pseudo-second-order model suggesting chemisorption is a predominant mechanism. Redlich-Peterson and Sips models best represented the experimental data (0.967 < R² < 0.993). Thermodynamic revealed that caffeine adsorption was spontaneous at all temperatures studied, exothermic, and probably with changes in the adsorbate-adsorbent complex during the process. The tests conducted in different water matrixes corroborate the suitability of this adsorbent to be used in caffeine removal even in a complex solution.

Resource management should follow a circular flow so that important substances such as phosphorus are not wasted in the form of water bodies’ pollutants. Therefore, the objective of this study was to investigate innovations focussing on the recovery of phosphorus in constructed wetland (CW) treatment systems, as well as related removal mechanisms and the more recent development and application of new substrates with high removal efficiency and potential for phosphorous recovery. Using bibliometric analysis, the most important P removal pathways were identified and investigated, concluding that substrate choice is one of the main aspects to be considered when aiming for phosphorous removal, and many improvements were obtained through the application of materials from either natural or artificial origins as well as construction waste and by-products of industrial processes. Thus, it is important that the chosen materials for a wetland substrate must present affinity with phosphorous, recycling possibility, low cost and local availability, in order to approach the concepts of circular economy and sustainable development.

Dust particles suspended in the atmosphere have been a big headache for electric power transmission industry in China. As transmission lines pass through dusty or air-polluted areas, dust contaminants are likely to deposit and accumulate on line insulators, which is one of the greatest causes of flashover and failure of power transmission. To study the statistical characteristics of this type of contamination, dust samples were collected and measured, and a physical model was set up to explain the deposition and accumulation mechanism of the particles. The trajectories of particles were tracked using fluid mechanics and contact mechanics, and an adhesion criterion was proposed. Simulation software was then applied to validate the model; further different environmental factors were studied that would affect the particle size distribution. The results show that under natural contamination conditions, the particle size distribution on the surface of the insulator shows a certain concentration at size ranges 1~100 μm and basically obeys a log-normal distribution. In addition, relative humidity, air velocity, and the charge accumulated on the surface all have significant influences on particle size distribution characteristics, while the effect of the electric field is mainly reflected in the difference in the number concentration of particle adhesion.

Lithium (Li) exploitation for industrial and domestic use is resulting in a buildup of the element in various environmental components that results in potential toxicity to living systems. Therefore, a soil culture experiment was conducted to evaluate the effects of increasing concentration of Li (0, 20, 40, 60, and 80 mg kg⁻¹ soil) on spinach growth, the effects of Li uptake, and its effects on various physiological attributes of the crop. The results showed that lower levels of Li in soil (20 mg Li kg⁻¹) improve the growth of spinach plants, while a higher concentration of applied Li enhanced the pigment contents. Higher concentrations of Li in soil interfered with potassium and calcium uptake in plants. Moreover, increasing Li concentration resulted in higher activities of antioxidant enzymes activity in spinach shoots. From these results, it is concluded that spinach shoot accumulated higher concentrations of Li without showing any visual toxicity symptoms. Therefore, the study concludes that Li ion was mostly deposited in leaves rather than in roots which may cause potential human health risk on the consumption of Li-contaminated plants. Therefore, the cultivation of leafy vegetables in Li-affected soils should be avoided to reduce the potential human health risks.