Concentrations of ozone and nitrogen oxides, together with air temperature and solar radiation intensity, were measured at several heights on a tower standing through the canopy of a red pine forest in summer and in autumn. In the summer observation, the diurnal variation patterns of ozone concentration both above and below the canopy were all similar and parallel to the solar radiation intensity. Using the data collected immediately above the canopy, deviation from the Leighton relationship and variations of concentration sums [O₃] + [NO] and [NO₂] + [NO] were examined, and as a result, it was supposedthat ozone was photochemically formed there in the daytime, probably because hydrocarbons emitted from pine trees broke the photostationary state among ozone and nitrogen oxides. The vertical temperature profile exhibited an inversion at the leaf-layer, which must have hindered vertical mixing of the air and made the trunk space more or less isolated from the upper atmosphere. These observations led to an idea that the similarity of the ozone variation pattern at every height was caused by the photochemical formation that proceeded simultaneously above and below the canopy rather than by vertical transport. Such situations of ozone formation were supported by observation of two maximums in the ozone vertical profile, one immediately above the canopy and another in the trunk space. Another feature of the ozone profile was a deep minimum in the leaf layer, which indicated ozone deposition onto leaf surfaces. This study thus revealed concurrence of ozone formation and deposition, and left two potentially important implications worthy of further investigation: (1) a forest is not always a sink but can be a source of ozone in sunlit conditions, and (2) deposition of ozone to trees can take place not only from outside but also from inside of a forest. In the autumn observation, however, the ozone formation was barely recognizable above the canopy and no longer found in the trunk space; in addition, the ozone concentration minimum in the leaf layer disappeared, suggesting that the deposition or removal was dependent on temperature.

Changes in land-use or management practices may affect water outflow, sediment, nutrients and pesticides loads. Thus, there is an increasing demand for quantitative information at the watershed scale that would help decision makers or planners to take appropriate decisions. This paper evaluates by a modeling approach the impact of farming practices and land-use changes on water discharge, sediment and NO3-N loads at the outlet of a 51.29 km2 watershed of central Iowa (Walnut Creek watershed). This intensively farmed (corn-soybean rotation) watershed is characterized by a flat topography with tiles and potholes. Nine scenarios of management practices (nitrogen application rates: increase of current rate by 20, 40%, decrease of current rate by 20, 40 and 60%; no tillage) and land-use changes (from corn-soybean rotation to winter wheat and pasture) were tested over a 30 yr simulated period. The selected model (Soil and Water Assessment Tool, SWAT) was first validated using observed flow, sediment and nutrient loads from 1991 to 1998. Scenarios of N application rates did not affect water and sediment annual budgets but did so for NO3-N loads. Lessening the N rate by 20, 40 and 60% in corn-soybean fields decreased mean NO3-N annual loads by 22, 50 and 95%, respectively, with greatest differences during late spring. On the other hand, increasing input N by 20 and 40% enhanced NO3-N loads by 25 and 49%, respectively. When replacing corn-soybean rotation by winter wheat, NO3-N loads increased in early fall, immediately after harvest. Pasture installation with or without fertilization lessened flow discharge, NO3-N and sediment delivery by 58, 97 and 50%, respectively. No-tillage practices did not significantly affect the water resource and sediment loads. Finally, such realistic predictions of the impact of farming systems scenarios over a long period are discussed regarding environmental processes involved.

This work aims to identify the sources of nitrogencontamination in nitrate vulnerable zones (NVZs) of Spain by means of the nitrogen isotope method. Three categories of nitrogen sources (synthetic fertilisers, animal wastes, and sludges and effluents from waste-water treatment plants) from three NVZs were analysed for their nitrogen isotopic composition (δ¹⁵N) in order to assess the applicability of the method to the identification of these N sources. The mean δ¹⁵N values were: +1.48‰ for synthetic fertilisers, +15.98‰ for animal wastes and +11.52‰ for sludges and effluents. The synthetic fertiliser sources were significantly different from the organic sources and so, the method can be used for their identification. The highest variability was found within the animal waste category. The range of values found for the different kinds of animal wastes (+5.86 to +36.74) was very wide and overlappedthe range found for sludges and effluents from waste-water treatmentplants (+4.57 to +20.18). Accordingly, these two nitrogen sources areisotopically indistinguishable.

Precipitation samples were collected at two coastal sites on the Korean Peninsula, Kangwha on the western coast and Yangyang on the eastern coast, from September 1991 to February 1997. The samples were analyzed for concentrations of major ions, in addition to pH and electrical conductivity. The annual volume-weighted mean pH values were 4.89 and 5.05 at Kangwha and Yangyang, respectively. The pH was generally lower at Kangwha than that at Yangyang, especially during the winter, because of reduced neutralizing inputs and greater acid inputs in winter. Dominant ions were different with NH₄ ⁺ and SO₄ ²⁻ most important at Kangwha and Na⁺ and Cl⁻ at Yangyang. Neglecting sea salt components, nss-SO₄ ²⁻ and NO₃ ⁻ were important anions and nss-Ca²⁺ and NH₄ ⁺ were important cations at both sites. Concentrations of these ions were 1.2–1.6 times higher at Kangwha than at Yangyang. Annual mean concentrations of these ions varied little during the study, while larger seasonal variations were observed. Annual mean nss-SO₄ ²⁻/NO₃ ⁻ ratios at Kangwha and Yangyang were 2.8 and 2.6. The 5 yr annual mean values of nss-SO₄ ²⁻/NO₃ ⁻ showed no trend at Kangwha but a decreasing tendency at Yangyang. The decreasing trend is similar to the decreasing trend in emissions of SO₂/NOₓ in South Korea. Regional differences in chemical composition between Kangwha and Yangyang appear to be associated with long-range transport of acidic gases and alkaline dust originated from other regions.

Nitric acid (HNO₃) vapor is a significant component of air pollution. Dry deposition of HNO₃ is thought to be a major contributor to terrestrial loading of anthropogenically-derived nitrogen (N), but many questions remain regarding the physico-chemical process of deposition and the biological responses to accumulation of dry-deposited HNO₃ on surfaces. To examine these processes experimentally, a continuously stirred tank reactor (CSTR) fumigation system has been constructed. This system enables simultaneous fumigation at several concentrations in working volumes 1.3 m dia by 1.3 m ht, allowing for simultaneous fumigation of many experimental units. Evaluation of the system indicates that it is appropriate for long-term exposures of several months duration and capable of mimicking patterns of diurnal atmospheric HNO₃ concentrations representative of areas with different levels of pollution.

The results of spatial and temporal distribution of acidic and basic air pollutants in ambient air around Hsinchu Science-Based Industrial Park (SBIP), Taiwan during August 2000 to October 2001 are presented. The sampling was performed on 13 different sites around the SBIP for 12 hrs each every month, and a total of 195 samples were collected. The effect of geographical and meteorologicalconditions, and production volume of the SBIP on the variation of pollutant's concentration was investigated. The spatial distribution shows that comparatively higher concentration of pollutants was found on the sites, which are either low in altitude such as the WS (west-southern) part of SBIP, in the downwind location or close to the factories. In case the wind velocity was low, i.e. below 2 m s⁻¹, the concentration of pollutant tended to increase and became uniformly distributed around the science park. The temporal distribution shows a decrease in ambient concentration of pollutants from February to June 2001, mainly due to the decline in the production volume of the SBIP in this period. During the whole period of investigation, the concentration of most of the species (except HF) was found to be lower than the factory-surrounding air quality standard of Taiwan, but in some cases it was higher than the AALG.

Bulk rainfalls were sampled during ten months in the Eastern Channel (Northern France). Chloride and sodium are the heavily loaded major ions in wet deposition, indicating a high influence of seasalt. However, the presence of heavy metals is independent of seasalt emissions and various anthropogenic sources should have an impact on their atmospheric concentrations.The comparison between heavy metals concentrations, always ranked as [Zn] ≫ [Pb] > [Cu] ≫ [Cd], with other values obtained during the same period on European coastal or on urban sites, confirms that ourwestern European station is in a semi-rural area where no local source strongly influences the abundance of atmospheric heavy metals. This semi-rural site could be disturbed by medium and/or long range transportepisodes.The observation of literature data confirms a decrease of Cd, Cu and Pb concentrations in rain waters from the beginning of the nineties. On the other hand, no sharp evolution has been observed for zinc concentrations.The structuring of data by clustering has permitted to extract five clusters, including four different types of origins. Two marine clusters, with relatively low levels of heavy metals, are opposite to three other clusters with higher heavy metal levels and a more important impact of continental polluted sources. In 47% of cases, the heavy metals collected at Cap Gris-Nez could originate from British Islands or north western Europe.Heavy metals fluxes show that this rural coastal European site has a level of contamination higher than those measured in remote area. The wet depositions of heavy metals to the English channel and the southern bight of the north sea are not negligible in the evaluation of global fluxes for this area, representing from 20 to 70% of the total input (riverine, direct and atmospheric inputs).

To date there have only been a few studies that measured mercury emissions from background substrate worldwide, and only a small amount of mercury flux data, from background substrate, exists for the Western United States. Because of this, the database of mercury emissions from background units < 0.1 mg kg⁻¹ mercury) is incomplete. This study focused on the collection of in-situ mercury flux data from representative lithologic units in Nevada. Measured mercury fluxes from substrate with background mercury concentration throughout Nevada were low (mean 2.0 ± 4.1 ng m⁻² hr⁻¹), and ranged from –3.7 to 9.3 ng m⁻² hr⁻¹. The mean measured mercury flux is slightly higher than those measured from background substrate from various locations throughout the world. The mean mercury flux from in-situ mercury measurements from substrate located near altered geologic units across Nevada was 15.5 ± 24.2 ng m⁻² hr⁻¹. These mercury fluxes are higher than the values applied in published global models for naturally enriched geologic units.

Chlorothalonil, a halogenated benzonitrile compound, is one of the most widely used fungicides in the world. Anaerobic microcosm assays were established to evaluate the combined effect of the initial content of carbon (6.3, 9.45 and 12.6 mg g⁻¹), nitrogen (0.6, 1.8 and 3 mg g⁻¹)and chlorothalonil (432, 865 and 1298 ηg g⁻¹) on the biodegradation of this fungicide by microbiota from an agricultural tropical soil. A Box-Behnken experimental design was used and chlorothalonil depletion was followed by HPLC with UV detection. The initial carbon content and fungicide dose were found to have a significant effect on removal efficiency. After 25 days of incubation, a high chlorothalonil depletion was observed in all biologically active microcosms (56–95%) although abiotic loss in a sterile blank was also notable (37%). The results suggest a high potential for chlorothalonil biodegradation under anaerobic conditions by indigenous microbial communities from soil that has been continuously exposed to high doses of the fungicide.

Nutrient-rich, highly acidic leachate draining from a coastalphosphogypsum storage site located at a phosphate fertilizer manufacturing company posed potentially harmful environmental effects to the coastal ecosystem. This study evaluated the chemical characteristics of the phosphogypsum and the hydrogeological characteristics of the surroundings. Hydraulic and chemical properties of the leachate draining from the site were also evaluated. The leachate is nutrient-rich and very acidic and discharges into the sea. The leachate and seawater are hydraulically connected through highly-permeable riprap placed at the toe of the stack. The chemical quality of the leachate and its drainage rate showed large variations depending on the location of the well, indicating heterogeneous hydraulic conditions. A vertical barrier system consisting of horizontal drainage wells and vertical leachate-collecting wells is suggested, in order to contain and collect the leachate. A back-up system of soil-bentonite cut-off walls is suggested to control leachate discharge to the sea.