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Abundance and properties of microplastics found in commercial fish meal and cultured common carp (Cyprinus carpio)
2019
Hanachi, Parichehr | Karbalaei, Samaneh | Walker, Tony R. | Cole, Matthew | Hosseini, Seyed V.
Microplastics (MPs) are environmental contaminants that are of increasing global concern. This study investigated the presence of MPs in four varieties of marine-derived commercial fish meal, followed by identification of their polymer composition using Fourier transform infrared (FTIR) spectroscopy. Exposure experiments were conducted on cultured common carp (Cyprinus carpio) by feeding four varieties of commercially available fish meal to determine relationships between abundance and properties of MPs found both in meal and in those transferred to cultured common carp. Mean particle sizes were 452 ± 161 μm (± SD). Fragments were the predominant shape of MP found in fish meal (67%) and C. carpio gastrointestinal tract and gills (65%), and polypropylene and polystyrene were the most present plastic polymers found in fish meal (45% and 24%, respectively) and C. carpio (37% and 33%, respectively). Positive relationships were found between MP levels in fish meal and C. carpio. This study highlights that marine-derived fish meal may be a source of MPs which can be transferred to cultured fish, thus posing a concern for aquaculture.
Show more [+] Less [-]Assessing impacts of climate change on habitat suitability of Coregonus ussuriensis and other coldwater fishes in northern China
2019
Xing, Baoxiu | Chen, He | Chen, Qingfeng | Zhang, Yan | Liu, Zifang | Yang, Zhao
Climate change seriously affects habitat suitability for coldwater fish. Amur whitefish (Coregonus ussuriensis) is a commercially important coldwater fish species found in northeast China that is particularly sensitive to water temperature. We use water temperature models for Songhua (Harbin to Yilan) and Mayi rivers to predict habitat suitability for Amur whitefish and other coldwater fish species during the months of July and August in 2014 and 2100—2 months during which river temperatures can reach extremes. The predict-results showed that fish habitat was to deteriorate over time, and to be less suitable for survival of coldwater fish species in 2100 than that in 2014. Under scenario RCP4.5 (Representative Concentration Pathway 4.5), the time period during which habitat for Amur whitefish was unsuitable increased continually; under scenario RCP8.5 (Representative Concentration Pathway 8.5), Amur whitefish might even disappear from the river basin. A significant increase in river water temperature will compromise coldwater fish survival and possibly lead to their disappearance. Practical measures to control greenhouse gas emissions and reduce the impact of global warming on aquatic ecosystems must be taken.
Show more [+] Less [-]Effect of coexisting components on phosphate adsorption using magnetite particles in water
2019
Lee, Won Hee | Kim, Jong-Oh
In this study, we focused on the rate of adsorption of phosphate on to the surface of magnetite in the presence of coexisting anions, organic matters and heavy metals. Magnetite particles were prepared using a co-precipitation method. Iron (II) sulfate heptahydrate and iron (III) chloride hexahydrate were mixed and then a sodium hydroxide solution was added drop-wise in the mixed iron solution. Coexisting anions were found to have no effect on the decrease in phosphate adsorption. However, phosphate adsorbed on to magnetite surface decreased with increasing total organic carbon (TOC) concentration of natural organic matter (NOM) such as citric, oxalic, and humic acid. The amount of phosphate adsorbed rapidly decreased with the increase of NOM concentration; therefore, it can be noted that NOM concentration considerably affects the adsorption of phosphate due to the negative charge exiting on the surface of NOMs. Glucose and ethanol, meanwhile, were found to have no effect on the phosphate adsorption. The amount of phosphate adsorbed did not change in the presence of heavy metals, namely, Pb and Cd, under acidic conditions. However, under alkaline conditions, the amount of phosphate adsorbed decreased with increasing concentrations of Pb and Cd. In the case of coexisting As(III), the amount of phosphate adsorbed decreased at all pH levels with increasing As(III) concentrations.
Show more [+] Less [-]Effects of modified sediments from a eutrophic lake in removing phosphorus and inhibiting phosphatase activity
2019
Liu, Wenli | Zhang, Liangjie | Zhang, Jibiao | Liu, Xing | Huang, Wei | Huang, Deying | Zheng, Zheng
Phosphorus is one of the main limiting and strong influencing factors of eutrophication, and phosphorus controlling in lake is of great significance for eutrophication. To do this, sediment materials were taken from Dianchi Lake, a typically eutrophic lake, and modified by hexadecyltrimethylammonium bromide (CTAB) and ZnSO₄ to remove phosphorus and inhibit alkaline phosphatase activity (APA). Results indicated that phosphorus removal efficiencies of sediments modified by CTAB (S-CTAB), ZnSO₄ (S-Zn), and oxidized sediments (OS) were higher than that of the raw sediment (RS). Ability to absorb phosphorus varied, following the order S-Zn>S-CTAB>OS>RS. Sorption was influenced by ionic strength, with the former decreasing with the increase of the latter. Freundlich model well described the sorption isotherm, with an R² ranging from 0.9168 to 0.9958. Furthermore, compared with the raw sediments, the maximum phosphorus sorption capacities of S-Zn and S-CTAB increased by 12.2% and 124.5%, respectively. Results of desorption studies suggest that the desorption rate of S-Zn was from 3.88 to 13.76%, lower than that of other sediment materials. APA was inhibited by S-CTAB and S-Zn at the same time, with inhibition rates from 29.6% and 61.0% when the concentrations of S-CTAB and S-Zn were 10 nmol L⁻¹ and 0.2 nmol L⁻¹, respectively. This study provides new insights into phosphorus removal and phosphatase activity inhibition in water treatment.
Show more [+] Less [-]Urban environmental influences on the temperature–mortality relationship associated mental disorders and cardiorespiratory diseases during normal summer days in a subtropical city
2019
Ho, Hung Chak | Wong, Ernest Man-Sing
Temperature is associated with mortality risk across cities. However, there is lack of study investigating the summer effect on mortality associated with mental/behavioral disorders, especially in cities with subtropical climate. In addition, summer mortality in subtropical cities is different from tropical cities, and previous studies have not investigated the urban environmental inequality on heat mortality associated with mental/behavioral disorders. A register-based study was developed to estimate the temperature effects on decedents on days with 50ᵗʰ percentile of average daily temperature between 2007 and 2014 in Hong Kong (n = 133,359). Poisson regression was firstly applied to estimate the incidence rate ratio (IRR) from the summer temperature effects on all-cause mortality, cardiovascular mortality, respiratory mortality, and mortality associated with mental/behavioral disorders. For a 1 °C increase in average temperature on days with temperature ≥ 24.51 °C, IRRs of mortality associated with mental and behavioral disorders on lag 0 and lag 1 days were 1.033 [1.004, 1.062] and 1.030 [1.002, 1.060], while temperature effects on cardiovascular mortality and respiratory mortality during normal summer days (not extreme heat events) were not significant. A further investigation with linear regression has shown that decedents with mental/behavioral disorders on higher temperature days resided in areas with lower percentage of sky view, lower percentage of vegetation cover, higher level of neighborhood-level PM₂.₅, higher level of neighborhood-level NO, and higher level of neighborhood-level black carbon (BC). In order to develop protocols for community healthcare based on the “Leaving no one behind” scheme documented in the 2016 Sustainable Development Goals report of the United Nations, it is necessary to include heat effects on mental/behavioral disorders, especially people with dementia, for community planning and healthcare development.
Show more [+] Less [-]Are soils beneath coniferous tree stands more acidic than soils beneath deciduous tree stands?
2019
Burgess-Conforti, Jason R. | Moore, Philip A. Jr | Owens, Phillip R. | Miller, David M. | Ashworth, Amanda J. | Hays, Phillip D. | Evans-White, Michelle A. | Anderson, Kelsey R.
In 2008, the Mulberry River, a National Wild and Scenic River, was listed as impaired due to low pH (below pH 6.0). Over the last 50 years, the volume of conifers in the Ozark region has increased 115% since 1978 which may result in the acidification of nearby aquatic ecosystems. The objective of this study was to determine if differences exist in soil and litter chemical properties between deciduous and coniferous tree stands. Aboveground litter (n = 200) and soil (n = 400) at 0- to 5- and 5- to 15-cm depths were collected at paired deciduous and coniferous stands at 10 locations within the Mulberry River watershed and analyzed for a suite of chemical parameters. There were no differences (P > 0.05) in several measures of soil acidity between deciduous and coniferous stands. Litter collected from the coniferous stands was more acidic than deciduous litter (4.4 vs 4.7; P < 0.05). Cation exchange capacity, exchangeable Ca and Mg, and water-soluble P and Mg contents differed (P < 0.05) by stand and depth. Cation exchange capacity and exchangeable Ca and Mg were greatest in the 0- to 5-cm depth interval of the coniferous stands. Water-soluble P and Mg contents were greatest within the 0- to 5-cm depth interval which did not differ (P > 0.05) between stand but were greater than the 5- to 15-cm depth interval. Although limited to the top 15-cm of soil, the similarity in soil acidity between stands suggests that conifer growth may not be a substantial source of acidity to the Mulberry River.
Show more [+] Less [-]How do fungal communities and their interaction with bacterial communities influence dissolved organic matter on the stability and safety of sludge compost?
2019
Zhao, Xinyu | Wei, Yuquan | Zhang, Fang | Tan, Wenbing | Fan, Yuying | Xi, Beidou
This study was conducted to assess the effect of fungal communities and their interaction with bacterial communities on the dissolved organic matter (DOM) transformation for the stability and safety of sludge composting. The results showed that fungal community had strong shifts in diverse stages of sludge composting along with the changes of temperature. Correlation analysis demonstrated that fungal communities had significant connections with bacterial communities during composting but were not directly related to the indicators of phytotoxicity and maturity. Variance partitioning analysis suggested that the interactions of fungal and bacterial communities had the biggest contribution (49.75%) to composting stability and safety. Based on structural equation modeling, the possible way of fungal community participated in the transformation of DOM components and the formation of humic-like substances of DOM by interacting with bacterial community was proposed, which will provide important information for understanding the biotic interaction in composting and improving composting fermentation process.
Show more [+] Less [-]A review of studies on urban energy performance evaluation
2019
Wang, Lei | Long, Ruyin | Chen, Hong | Li, Wenbo | Yang, Jiahui
Energy is a foundation for a city to create economic wealth, satisfy people’s desires, and achieve benefits. However, the increasing mismatch between energy supply and demand and the worsening of environmental pollution have highlighted the importance of improving urban energy performance, so the number of studies related to urban energy performance evaluation is increasing. Based on describing the authors, numbers, regional sources, and themes of these studies, this paper reviews and analyzes the conceptions, evaluation indicators, influencing factors, evaluation methods, and evaluation systems related to urban energy performance. Most countries have expressed concern about this topic. Researchers in China, Belgium, and the USA have had the most achievements and collaborations. The concept of urban energy performance further extends to a comprehensive performance. It is measured based on an input-output process. In addition to the original evaluation indicators, new desirable outputs and undesirable outputs are included. Industrial structure, energy price, population density, home car ownership, climate factors, Gini coefficient, health expenditure level, and unemployment rate are regarded as influencing factors. Therefore, a new framework of evaluation indicators and influencing factors is constructed. Stochastic frontier analysis (SFA) and data envelopment analysis (DEA) are commonly used to evaluate. With changes in conceptions, evaluation indicators, and influencing factors, the evaluation method should rather focus on measuring multiple input-output variables, determining the evaluation results and the impacts of factors at the same analysis stage, and highlighting policy orientations. As an important management tool, the evaluation system would continue to be studied and developed.
Show more [+] Less [-]Aging as the main factor controlling PAH and polar-PAC (polycyclic aromatic compound) release mechanisms in historically coal-tar-contaminated soils
2019
Boulangé, Marine | Lorgeoux, Catherine | Biache, Coralie | Michel, Julien | Michels, Raymond | Faure, Pierre
In industrial sites, historically contaminated by coal tar (abandoned coking and manufactured gas plants), other families of organic pollutants than the 16 PAHs (polycyclic aromatic hydrocarbons) classified by the US-EPA can occur and induce potential risk for groundwater resources. Polar PACs (polycyclic aromatic compounds), especially oxygenated and nitrogenated PACs (O-PACs and N-PACs), are present in the initial pollution and can also be generated over time (i.e., O-PACs). Their aqueous solubilities are much greater than those of the PAHs. For these reasons, we need to increase our knowledge on polar PACs in order to better predict their behavior and the potential on-site risk. Batch leaching tests were carried out under various conditions of temperature, ionic strength, and availability of pollutants to determine the mechanisms and key parameters controlling their release. The results show a release of low-molecular-weight PAHs and polar PACs mainly by dissolution, while higher molecular weight PAHs are mainly released in association with colloids. Aging mainly controls the former mechanism, and ionic strength mainly controls the latter. Temperature increased both dissolution and colloidal mobilization. The Raoult law predicts the PAC equilibrium concentration for soils presenting high pollutant availability, but this law overestimates PAC concentration in aged soils (low pollutant availability). This is mainly due to limitation of PAC diffusion within coal-tar particles with aging. The most soluble PACs (especially polar PACs) are the most sensitive to aging. For better prediction of the PAC behavior in soils and water resources management, aging needs to be taken into account.
Show more [+] Less [-]Characteristics and processes of hydrogeochemical evolution induced by long-term mining activities in karst aquifers, southwestern China
2019
Huang, He | Chen, Zhihua | Wang, Tao | Zhang, Liang | Zhou, Gaoming | Sun, Bangtao | Wang, Yong
Long-term mining activities reshape the hydraulic and hydrochemical field, and threaten the safe use of groundwater and ecosystem balance. Here, we concluded the evolution characteristics and processes of karst groundwater system based on the water level and hydrochemistry data of the Carboniferous and Devonian aquifer in Maoping lead-zinc deposit, a representative in southwestern China. After concentrated mining lasting for nearly three decades, this mining area has generated a huge depression cone coupled with decreased level, changed flowpath, massive drainage, and direct hydraulic connection across the aquiclude. However, these two sets of karst aquifers exhibited distinct hydrochemical evolution patterns in particular with respect to sulfate. SO₄²⁻ and the total dissolved solids (TDS) increased slightly in the Carboniferous aquifer and maintained the hydrochemical type of HCO₃ and HCO₃·SO₄. While, SO₄²⁻ and TDS in the Devonian aquifer decreased drastically, and the hydrochemical type was converted from SO₄ and SO₄·HCO₃ to HCO₃ and HCO₃·SO₄. Before concentrated mining, pyrite oxidation and dissolution of carbonate minerals mutually promoted each other in sluggish groundwater flow, then generated abnormally high concentrations of SO₄²⁻, Ca²⁺, and Mg²⁺ in Devonian karst aquifer, causing an illusion of saturation state of gypsum dissolution. At present, SO₄²⁻ is mainly derived from pyrite oxidation indicated by sulfur isotope except deep groundwater contributed by gypsum dissolution. Groundwater quality in the Devonian aquifer was improved together by the dilution of northern shallow groundwater from the external Carboniferous aquifer and upward recharge of southern deep groundwater itself. Results of principal component analysis (PCA) verified the different recharge resources and mixing process resulted from continuous mining activities, which were the driving forces of hydrochemical evolution. Qualitatively speaking, the disturbing degree of the hydrodynamic field was consistent with the variation degree of hydrochemical filed. This research shed light upon the groundwater system and its evolution induced by intensive mining, which will benefit the future mining project.
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