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Zinc (Zn) mitigates copper (Cu) toxicity and retrieves yield and quality of lettuce irrigated with Cu and Zn-contaminated simulated wastewater / Full text
2023
Ullah, Sana, | Naeem, Asif, | Čalkaitė, Ieva, | Hosney, Ahmed, | Depar, Nizamuddin, | Barčauskaitė, Karolina,
Owing to a competitive interaction, zinc (Zn) contained in highly Cu-contained wastewater was hypothesized to mitigate Cu toxicity-induced negative effects on the growth and quality of lettuce. Thus, growth, metal accumulation and biochemical responses of lettuce irrigated with simulated wastewater (SW, control), Cu-contaminated SW (CuSW, 20 mg Cu L−1), Zn-contaminated SW (ZnSW, 100 mg Zn L−1) and both Cu- and Zn-contaminated SW (CuZnSW, 20 mg Cu and 100 mg Zn L−1) were evaluated. Results revealed that irrigation with CuSW negatively affected growth (dry matters, root length and plant height) and quality (low mineral concentrations) of lettuce, which were associated with higher Cu uptake. Irrigation with Zn + Cu-contaminated SW retrieved Cu toxicity and improved root and shoot dry matters and root length by 13.5%, 46% and 19%, respectively compared to that with alone Cu-contaminated SW. Moreover, CuZnSW improved lettuce leaf quality compared to CuSW and increased concentrations of Mg (30%), P (15%), Ca (41%), Mn (24%) and Fe (23%). Moreover, compared to CuSW, CuZnSW improved flavonoids (54%), total polyphenolic compounds (1.8-fold), polyphenolic acids (77%) and antiradical activities (16.6%). Most importantly, Zn addition boosted up lettuce Cu tolerance index by 18% under Cu-contaminated SW treatment. Pearson’s correlation analysis among various growth and mineral parameters demonstrated that shoot Zn concentration was positively related to elemental concentrations, phytochemical contents and antioxidant activity under Cu-contaminated environment. Thus, it is concluded that Zn supplementation retrieves negative effects of Cu toxicity to lettuce grown with Cu-contaminated wastewater.
Show more [+] Less [-]Biomarker responses in mussels (Mytilus trossulus) from the Baltic Sea exposed to water-accommodated fraction of crude oil and a dispersant at different salinities / Full text
2023
Turja, Raisa, | Benito, Denis, | Ahvo, Aino, | Izagirre, Urtzi, | Lekube, Xabier, | Stankevičiūtė, Milda, | Butrimavičienė, Laura, | Soto, Manu, | Lehtonen, Kari K.,
Oil spills pose significant environmental risks, particularly in cold seas. In the Baltic Sea, the low salinity (from 0 to 2 up to 18) affects the behaviour of the spilled oil as well as the efficiency and ecological impacts of oil spill response methods such as mechanical collection and the use of dispersants. In the present study, mussels (Mytilus trossulus) were exposed under winter conditions (5 °C) to the water-accommodated fraction (WAF) of Naphthenic North Atlantic crude oil prepared by mechanical dispersion or to the chemically enhanced fraction (CEWAF) obtained using the dispersant Finasol OSR 51 at salinities of 5.6 and 15.0. Especially at the lower salinity, high bioaccumulation of polycyclic aromatic hydrocarbons was recorded in mussels in the CEWAF treatments, accompanied by increased biomarker responses. In the WAF treatments these impacts were less evident. Thus, the use of dispersants in the Baltic Sea still needs to be carefully considered.
Show more [+] Less [-]Metals and metalloids in high-altitude Pyrenean lakes: sources and distribution in pre-industrial and modern sediments Full text
2023
Rodriguez-iruretagoiena, Azibar | Gredilla, Ainara | Fdez-ortiz De Vallejuelo, Silvia | Arana, Gorka | Meaurio, Maite | Madariaga, Juan Manuel | Auguet, Jean Christophe | González González, Aridane | Pokrovsky, Oleg S. | Camarero, Luis | De Diego, Alberto
High-altitude Pyrenean lakes are ecosystems far from local pollution sources, and thus they are particularly sensitive to the atmospheric deposition of metals and metalloids. This study aims to quantify the effect of human activity in 18 lakes located in both side of the France–Spain frontier. Sediment cores were collected in summer 2013, sampled at a 1cm resolution and the concentration of 24 elements was measured by ICP-MS. Statistic and chemometric analysis of the results highlights the influence of the geographical position and lithogenic features of each lake basin on trapping pollutants. More than the 80% of the lakes showed values of enrichment factor (EF) above 2 for at least one of the elements investigated in at least one core interval, which corroborates the existence of historical anthropogenic inputs of elements in the studied area. The results demonstrate the natural origin of As and Ti in Pyrenees, together with the significant anthropogenic inputs of Cd, Pb, Sb and Sn from ancient times. The data set points mining activities as the main historical source of pollution and illustrate the large impact of the industrial revolution. The regional variability could reflect also differential long-range transport, followed by dry or wet deposition.
Show more [+] Less [-]Kinetics of metal and metalloid concentrations in holopelagic Sargassum reaching coastal environments Full text
2023
Cipolloni, Océanne-amaya | Baudrimont, Magalie | Simon-bouhet, Benoît | Dassié, Émilie Pauline | Gigault, Julien | Connan, Solène | Pascal, Pierre-yves
Since 2011, the Caribbean Islands have experienced unprecedented stranding of a pelagic brown macroalgae Sargassum inducing damages for coastal ecosystems and economy. This study measures the kinetics of metal trace elements (MTE) in Sargassum reaching different coastal environments. In July 2021, over a period of 25 days, fixed experimental floating cages containing the three Sargassum morphotypes (S. fluitans III and S. natans I and VIII) were placed in three different coastal habitats (coral reef, seagrass, and mangrove) in Guadeloupe (French West Indies). Evolution of biomasses and their total phenolic content of Sargassum reveals that environmental conditions of caging were stressful and end up to the death of algae. Concentrations of 19 metal(loid) trace elements were analyzed and three shapes of kinetics were identified with the MTE that either concentrate, depurate, or remains stable. In the mangrove, evolution of MTE was more rapid than the two other habitats a decrease of the As between 70 and 50 μg g−1 in the mangrove. Sargassum natans I presented a different metal composition than the two other morphotypes, with higher contents of As and Zn. All Sargassum morphotype are rapidly releasing the metal(oid)s arsenic (As) when they arrive in studied coastal habitats. In order to avoid the transfer of As from Sargassum to coastal environments, Sargassum stranding should be avoided and their valorization must take into account their As contents.
Show more [+] Less [-]Exposure of zebrafish to an environmental mixture of persistent organic pollutants triggers an increase in anxiety-like syndrome but does not affect boldness in unexposed offspring Full text
2023
Alfonso, Sebastien | Blanc, Melanie | Cousin, Xavier | Bégout, Marie-laure
Polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) are persistent organic pollutants (POPs) that are present as complex mixtures in all environmental compartments, including aquatic ecosystems. However, little is known about the effects of such complex mixtures on teleost behaviour. In this study, zebrafish (Danio rerio) were chronically exposed to an environmentally relevant mixture (MIX) containing 22 PCB and 7 PBDE congeners through diet from 5 days post fertilization onwards. MIX-exposed F0 fish produced offspring (F1 and F2 generations) that were fed using plain food and grown until adulthood. In each generation, five behavioural traits (i.e. boldness, activity, sociality, exploration and anxiety) were evaluated by the mean of different experimental set-ups. Two distinct behavioural syndromes were identified: boldness, positively correlated to activity and exploration; and anxiety, associated with low sociality. F0 fish did not display any behavioural disruption resulting from POP exposure whereas F1 MIX fish were bolder than fish from other generations but did not differ significantly from F1 controls. F2 MIX fish displayed a higher anxiety syndrome than F2 controls. This is of particular importance since such behavioural changes in offspring generations may have persistent ecological consequences, may affect fitness and hence cause detrimental effects on wild fish populations exposed to POP mixtures.
Show more [+] Less [-]Assessment of Particulate and Gaseous Fluoride in Phosphate Fertilizer Industry Full text
2023
S. Jawahar, K. Shridhar, V. Dhananjayan, K. Panjakumar, B. Ravichandran, A. Ravinder Nath and Nirmala Babu Rao
Fluorides are emitted in both gaseous and particle forms in the industrial sector. However, studies usually only report total fluoride content. Therefore, the study aimed to assess the particulate, gaseous fluoride and correlate it with the respirable dust particles in Single Super Phosphate (SSP), Granular Single Super Phosphate (GSSP), and administration divisions of the industry. Respirable dust particles, particulate fluoride, and hydrogen fluoride in the work environment were collected on a filter cassette containing an MCE filter paper (0.8 micron 37-mm) and Na2CO3 impregnated backup pad, respectively, using a personal sampler. The fluoride samples were analyzed using Ion Selective Electrode (ISE) and expressed as milligrams per meter cube (mg.m-3). The respirable dust, particulate, and gaseous fluoride content were found to have statistically significant differences (p<0.001) between the divisions (SSP, GSSP, and administration) in the static monitoring, whereas, in the case of personal monitoring, no significant differences were observed. Average airborne respirable, particulate, and gaseous fluoride levels in static monitoring were 1.37, 1.03, 0.20 mg.m-3, 0.018, 0.008, 0.001 mg.m-3, and 0.808, 0.403, 0.026 ppm in SSP, GSSP and administration respectively, whereas in personal monitoring the average respirable, particulate and gaseous fluoride concentrations were 1.18, 0.85, 0.30 mg.m-3, 0.0013, 0.007, 0.002 mg.m-3 and 0.356, 0.258, 0.011 ppm in SSP, GSSP and administration respectively. The present study observed that the levels of fluoride decreased with an increase in distance from SSP, followed by GSSP and administration. It indicates that the fluoride exposure was inversely proportional to the distance of the source. This study outcome will help to design a policy and intervention to mitigate fluoride exposure among workers.
Show more [+] Less [-]Removal of Brilliant Green Dye from Aqueous Solutions Using Multi-walled Carbon Nanotubes (MWCNTs): Linear and Nonlinear Isotherm Models and Error Analysis Full text
2023
N. I. Mahdi, M.S. Falih, R. F. Abbas, A. A. Waheb and A. A. Rahi
Current research explains the comparison of linear and nonlinear regression methods for finding the optimal isotherm study using experimental data for the adsorption of BG on multi-walled carbon nanotubes MWCNTs. BG dye maximum adsorption onto MWCNTs occurred at pH 2 and 35°C, with the apparent equilibrium reached after 15 min. In this study, five error functions were used: ERRS, Hybrid, Chi-square (χ2), ARE, and EABS. The values of error functions suggest that the Langmuir Linear type 3 is a suitable isotherm to describe the adsorption of BG on MWCNTs. The results showed that the Langmuir isotherm is a fit good isotherm to describe the adsorption process. The coefficient of non-determination (K2) showed Hybrid, and ERRS were the preferable error functions used to predict the fit of linear and nonlinear isotherm models. Compared with other studies, MWCNTs can be used as a low-cost adsorbent with low contact time for the removal of BG dye from an aqueous solution.
Show more [+] Less [-]Decarbonization of the Building Sector in Morocco – A Systematic Review Full text
2023
S. EL Majaty, A. Touzani and Y. Kasseh
This article is a systematic review of the decarbonization of the building sector in Morocco. It explores the different approaches and technologies used to reduce greenhouse gas emissions and achieve decarbonization targets in this sector. The article examines the policies and regulations in place in Morocco to encourage decarbonization of the building sector, as well as the initiatives taken by key actors to reduce carbon emissions in their buildings. It also reviews sustainable building technologies and renewable energy systems currently used in the country. The systematic review concludes that while Morocco has put in place policies and regulations to encourage the decarbonization of the building sector, there is still much to be done to achieve the ambitious decarbonization targets set by the country. The authors of the article recommend greater investment in sustainable building technologies and renewable energies, as well as increased collaboration between public and private sector actors to accelerate the transition to low-carbon buildings.
Show more [+] Less [-]The Impact of Climate Change on the City of Padang, Indonesia Full text
2023
Widya Prarikeslan, Nofi Yendri Sudiar, Gema Anugrah, Deski Beri, Dezi Handayani, Irma Leilani Eka Putri and Mohammad Isa Gautama
The impact of global warming is climate change which affects elements of society. This condition causes a decrease in the level of community welfare and increases the level of community vulnerability. Some climate change impacts are floods, droughts, landslides, and shoreline changes. In this study, we will focus on landslides. Landslides are among the most dangerous natural disasters that often occur in mountainous areas, especially during the rainy season. Various factors influence events involving landslides. This study aims to utilize GIS to identify landslide-prone areas in Padang. The method used in this study is the Zuidam and Concelado criteria overlay method for the level of landslide hazard and the broken method (jenks). The natural break (jenks) classification method reduces within-class variation and maximizes between-class variation. This study shows that the level of landslide vulnerability in Padang City is low, with a total area of 288854.38173 ha with a percentage of 42.21%. We need to consider more factors and experiment with training and validating data in more detail to gain insight into the physical contributions of the factors to landslide occurrences.
Show more [+] Less [-]Evaluation of Organic Pollution Using Algal Diversity in Rivers of Cotabato City, Bangsamoro Autonomous Region in Muslim Mindanao (BARMM), Mindanao Island, Philippines Full text
2023
Nancy C. Alombro, Raisah C. Guiamadil, Warda U. Datumama, John Paul A. Catipay
This study investigated the water quality and the organic pollution level of rivers in Cotabato City, specifically the Rio Grande de Mindanao, Matampay, Esteros, and Tamontaka rivers. The physicochemical characteristics of water in these rivers were determined in the laboratory, and the level of organic pollution was determined using Palmer’s algal pollution index. Water quality assessment showed that the dissolved oxygen (DO) in Matampay River and the biological oxygen demand (BOD) in Esteros River exceed the minimum standard set by the Department of Environment and Natural Resources (DENR) for water quality in class C rivers. Results also showed that there were thirty (30) algal genera belonging to twelve (12) classes were observed in Cotabato City rivers. Algal genera belonging to Chlorophyceae and Bacillariophyceae were found to be the most abundant in these rivers. Using Palmer’s algal pollution index, the Rio Grande de Mindanao showed a probability of high organic pollution, while the rest of the rivers indicated a lack of organic pollution. For a more thorough assessment of the Cotabato City rivers, it is advisable to consider more comprehensive measures, such as extending the sampling duration and expanding the number of sampling stations.
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