Combustion engines bring a lot of pollution products to human living environment. This study introduced a green engine called free-piston linear engine (FPLE), and performed an evaluation on the pollutant emissions of a diesel FPLE by comparison with a corresponding conventional crankshaft engine (CCE). The combustion reaction and pollutant formation were described by a comprehensive model which considers the special operation mechanism of the FPLE. The effect of dynamic and fuel quantity on the unclean combustion products of the FPLE and the CCE was compared. Results indicate that in the case of the fuel quantity of 7.1 mg condition, the pollutant forming in the FPLE is generally later than that in CCE because of the higher speed of FPLE around the reverse point of stroke, and a significant advantage in nitric oxide (NO) emission is found for the FPLE, although it emits more carbon monoxide (CO) and soot. Moreover, compared with the CCE, the FPLE is cleaner in lean fuel conditions because the NO production of the FPLE is only half of that of the CCE, and that of other pollutants is almost at the same level. However, in heavy fuel conditions, the FPLE shows a disadvantage in CO and soot emission due to the serious afterburning effect and poor oxygen environment in some local areas, although its NO production is still lower than that of the CCE.

Pd-only three-way catalysts with improved catalytic activity for NO elimination were prepared. In order to explore the catalytic reaction rules of NO reduction under a three-way catalytic system, a series of single reactions related to NO reduction were evaluated. It was found that the reaction temperatures of NO + H₂ or NO + CO or NO + C₃H₆ reactions were below 250 °C, while that of NO + C₃H₈ was up to 350 °C. Thus, the reaction NO + C₃H₈ served as the key reaction in determining the purification efficiency of NO at the high-temperature stage. By in situ FTIR, we proposed that three possible steps were involved in NO + C₃H₈ reaction. The first step was the oxidation of C₃H₈ and NO to acetone and nitrate species by active oxygen species, respectively (C₃H₈ + O* → C₃H₆O, NO + O* → NO₃⁻). XPS results revealed that the amount of active oxygen species in Pd/CeO₂-ZrO₂-Al₂O₃ (Pd/CZA, 73.7%) was much higher than that in Pd/CeₓZr₁₋ₓO₂+Al₂O₃ (Pd/CZ+A, 64.1%). This was in line with the higher reaction efficiency of the first step over Pd/CZA. Then the NO + C₃H₈ reaction was accelerated by the first step, which consequently contributed to the higher NO elimination efficiency of Pd/CZA.

Bacteria-derived biochars from Bucillus sp. biomass under different pyrolysis temperature (250 °C, 350 °C, 450 °C, and 550 °C, respectively) were prepared, forming polyptychial, mesoporous graphite-like structure. The adsorption and sequestration efficiencies of Cd²⁺ by these biochars were evaluated, and the underlying mechanisms were then discussed. Cd²⁺ sorption data could be well described by Langmuir mode while the pseudo-second-order kinetic model and Elovich model best fitted the kinetic data. The functional groups complexation, cation-π interactions, and interaction with minerals (including surface precipitation with phosphorus and ion exchange) jointly contributed to Cd²⁺ sorption and sequestration on biochar, but the interaction with minerals played a dominant role by forming insoluble cadmium salt composed by polycrystalline and/or amorphous phosphate-bridged ternary complex. The maximum sorption capacity of BBC350 in simulated water phase of soil for Cd²⁺ was 34.6 mg/g. Furthermore, the addition of bacteria-derived biochars (1%, w/w) decreased the fractions easily absorbed by plants for Cd in the test paddy soils by 1.9–26% in a 10-day time. Results of this study suggest that bacteria-derived biochar would be a promising functional material in environmental and agricultural application.

Traffic accident may bring vehicle fire in the street canyons. With its high temperature and numerous hazardous materials, the smoke produced by the vehicle fire may cause serious damage to the human body and the properties nearby, such as the glass curtain walls of buildings. The influence of the ambient air flow speed and street aspect ratio on the dispersion of fire smoke in street canyon has been analyzed by FDS software and theoretical analysis in this study. The impact of different windward building heights and different ambient air flow speeds u₀ on the fire smoke were investigated. The results show that the fire smoke tilts towards the opposing direction of the ambient air flow within the street canyon, while the ambient air flow is perpendicular to the windward building. The results indicate that the critical re-entrainment velocity decreases at first, and then increases until it attains a constant with the building height ratio H₁/H₂. Finally, a predictive model of the critical re-entrainment velocity was developed under different building height ratios H₁/H₂.

Trace element distribution in the human body varies across regions and countries due to their different living environment and lifestyle. Thus, it is of great significance to investigate the reference level of trace element in a specific population. Wuhan is the largest metropolitan area in central China with highly developed heavy industries. This study aimed at determining the reference urinary distribution in general populations of Wuhan for nine trace elements (Cr, Mn, Cu, As, Se, Cd, Hg, Tl, Pb), and analyzed their associations with age, sex, and the kidney function. In total, 226 healthy adults not exposed to these trace elements were recruited, and the first-morning urine specimens were analyzed by using ICP-MS-based method. Our results showed higher urinary levels for As and Cd in Wuhan population when compared with other countries, while other element levels were almost equivalent. Sex difference existed for urinary Cu, Mn, As, Tl, and Pb. And urinary Cd, Tl, and Pb levels were associated with the glomerular filtration rate. Almost all these urinary elements showed significant inter-correlations, especially for Cu but except for Mn. This study provides systematic information regarding urinary trace element levels in residents of Wuhan in central China, and shall be of importance for future environmental and occupational biomonitoring.

The role of a single water molecule on the atmospheric reaction of HONO + ClO is systematically investigated employing quantum chemical calculation combined with harmonic transition state theory. Two reaction pathways, cis-HONO + ClO and trans-HONO + ClO, are identified for the naked reaction, which depends on the configurations of HONO. When adding a single water molecule to this reaction, the rate constants of cis-HONO + ClO and trans-HONO + ClO pathways are 7.97 × 10⁻²¹ and 2.29 × 10⁻¹⁷ cm³ molecule⁻¹ s⁻¹, respectively, larger than the corresponding naked reaction. To further understand the role of water on the HONO + ClO reaction, it is necessary to calculate the effective rate constant by considering the concentration of water. It shows that the effective rate constants of water-assisted cis-HONO + ClO pathway are much smaller than those of the naked reaction, whereas the presence of water accelerates the trans-HONO + ClO at room temperature. This study demonstrates that water has a positive role in the pathway of trans-HONO + ClO by modifying the stabilities of reactant complexes and transition states through the hydrogen bond formation, which contributes to the sink of atmospheric HONO. In addition, the kinetic branching ratio indicates that the favorable reaction is the trans-HONO + ClO instead of the cis-HONO + ClO pathway, in contrast to the naked reaction. These results reveal the importance of water in the evaluation of the fate of active species in the atmosphere. Graphical Abstract

The shortage of drinking water is a major problem in the rural areas of the Mekong Delta, especially, when surface water, a main local direct drinking water source is being threatened by pesticide pollution and salinity intrusion. A hybrid process coupling electrodialysis (ED) and nanofiltration (NF) is proposed as an effective process easy to setup in a small plant to treat complex matrix with high salinity and pesticide concentration as is the Mekong Delta surface water. Performance of the ED–NF integration was evaluated with synthetic solutions based on the comparison with a single NF step generally used for pesticide removal. Both energy consumption and water product quality were considered to assess process efficiency. The ED stage was designed to ensure a 50% removal of salinity before applying NF. As expected, the NF rejection is better in the hybrid process than in a case of a single NF step, especially for pesticide rejection. The integration of a NF stage operated with NF270 membrane consumes less energy than that with NF90 membrane but its efficiency was observed not high enough to respect the Vietnamese guidelines. Using NF90, the optimal recovery rate of the NF stage varies from 30 to 50% depending on the salt content in the feed.

There has been a conflicting issue in rural China that whether or not encouraging the development of medium–large-scale biogas plants (MLBPs) to reduce household biogas digesters (HBDs) will be better for China in the long run. In this study, we investigate the difference between HBD users and MLBP users and the factors that affect the biogas use of these two user types on the basis of a survey of 1125 households in four provinces in China. The results indicate that compared to HBD users, MLBP users have a higher ratio (29%) of biogas use, obtain a higher subsidy-to-cost ratio (25%), and present a more positive evaluation of biogas service (3%). For HBD users, installation years and service evaluation are significant predictors of biogas use. For MLBP users, in addition to installation years and service, the subsidy-to-cost ratio affects biogas use negatively, and the biogas price is a key constraint for biogas use. These results provide valuable insights into the future development of biogas energy in rural China and guidance for the development of biogas in similar countries worldwide.

Employment of edible oils as alternative green fuel for vehicles had raised debates on the sustainability of food supply especially in the third-world countries. The non-edible oil obtained from the abundantly available rubber seeds could mitigate this issue and at the same time reduce the environmental impact. Therefore, this paper investigates the catalytic cracking reaction of a model compound named linoleic acid that is enormously present in the rubber seed oil. Batch-scale experiments were conducted using 8.8 mL Inconel batch reactor having a cyclic horizontal swing span of 2 cm with a frequency of 60 cycles per minute at 450 °C under atmospheric condition for 90 min. The performance of HZSM-5, HBeta, HFerrierite, HMordenite and HY catalysts was tested for their efficiency in favouring gasoline range hydrocarbons. The compounds present in the organic liquid product were then analysed using GC-MS and classified based on PIONA which stands for paraffin, isoparaffin, olefin, naphthenes and aromatics respectively. The results obtained show that HZSM-5 catalyst favoured gasoline range hydrocarbons that were rich in aromatics compounds and promoted the production of desired isoparaffin. It also gave a higher cracking activity; however, large gaseous as by-products were produced at the same time.

This study applied the logarithmic mean Divisia index (LMDI) model to identify and discuss the main drivers of Pakistan’s CO₂ emissions over the period 1990–2016. The study examined the effects of five factors based on Pakistan’s three main economic sectors while considering the 11 types of fuels consumed in that country. The results showed that the energy structure effect is the greatest driving force of CO₂ emissions in this country, followed by scale effect and economic structure effect. Energy intensity is the main contributor to reducing Pakistan’s carbon emissions throughout the study period. A comparative review at the sectoral level shows that the industrial sector for which coal is the main source of energy supply is the one that contributes the most to CO₂ emissions in Pakistan. Alongside this sector is the tertiary sector, where the transport sub-sector imposes rules of conduct based on a growing Pakistani population. Meanwhile, deforestation would be the main cause of CO₂ emissions from the agricultural sector in Pakistan, as energy consumption in this sector remains very low. Improving energy efficiency through the intensification of clean energy is urgently needed if Pakistan’s environmental goals are to be achieved.