Global warming caused by CO₂ emissions will directly harm the health and quality of life of people. Accurate prediction of CO₂ emissions is highly important for policy-makers to formulate scientific and reasonable low-carbon environmental protection policies. To accurately predict the CO₂ emissions of the world’s major economies, this paper proposes a new fractional grey Bernoulli model (FGBM(1,1,[Formula: see text])). First, this paper introduces the modeling mechanism and characteristics of the FGBM(1,1,[Formula: see text]) model. The new model can be transformed into other grey prediction models through parameter adjustment, so the new model exhibits high adaptability. Second, this paper employs four carbon emission datasets to establish a grey prediction model, calculates model parameters with three optimization algorithms, adopts two evaluation criteria to evaluate the accuracy of the model results, and selects the optimization algorithm and model results that yield the highest model accuracy, which verifies that the FGBM(1,1,[Formula: see text]) model is more feasible and effective than the other six grey models. Finally, this paper applies the FGBM(1,1,[Formula: see text]) model to predict the CO₂ emissions of the USA, India, Asia Pacific, and the world over the next 5 years. The forecast results reveal that from 2020 to 2024, the CO₂ emissions of India, the Asia Pacific region, and the world will gradually rise, but that in USA will slowly decline over the next 5 years.

Increasing surface temperature has a significant effect on the electrical performance of photovoltaic (PV) panels. A closed-loop forced circulation serpentine tube design of cooling water system was used in this study for effectively management of the surface temperature of PV panels. A real-time experiment was first carried out with a PV panel with a cooling system at heat transfer fluid (HTF) flow rates of 60 kg h⁻¹, 120 kg h⁻¹, and 180 kg h⁻¹. Based on the experimentation, a correlation for a nominal operating cell temperature (NOCT) and thermal efficiency for collector was developed for experimental validation of useful energy gained, cell temperature, and electric power generation. The developed correlations were validated with the use of electric power electrical power and useful energy gained in photovoltaic serpentine thermal solar collector (PV/STSC) and fitting into the experimental results with a deviation of 1% and 2.5% respectively. Further, with the help of developed correlations, a system was developed in the TRNSYS tool through which an optimization study was performed based on electric and hot water demand. The findings indicated an optimal system with an 8-m² PV/STSC area, a HTF flow rate of 60 kg h⁻¹, and thermal energy storage (TES) system having a volume and height of 280 l and 0.8 m could meet 91% and 33% of the hot water demand for Ac loads and 78% or DC loads, respectively.

Exposure to air pollution during prenatal or neonatal periods is associated with autism spectrum disorder (ASD) according to epidemiology studies. Furthermore, prenatal exposure to valproic acid (VPA) has also been found to be associated with an increased prevalence of ASD. To assess the association between simultaneous exposure to VPA and air pollutants, seven exposure groups of rats were included in current study (PM₂.₅ and gaseous pollutants exposed — high dose of VPA (PGE-high); PM₂.₅ and gaseous pollutants exposed — low dose of VPA (PGE-low); gaseous pollutants only exposed — high dose of VPA (GE-high); gaseous pollutants only exposed — low dose of VPA (GE-low); clean air exposed — high dose of VPA (CAE-high); clean air exposed — low dose of VPA (CAE-low) and clean air exposed (CAE)). The pollution-exposed rats were exposed to air pollutants from embryonic day (E0) to postnatal day 42 (PND42). In all the induced groups, decreased oxidative stress biomarkers, decreased oxytocin receptor (OXTR) levels, and increased the expression of interleukin 6 (IL-6), interleukin 1β (IL-1β), and tumor necrosis factor alpha (TNF-α) were found. The volumes of the cerebellum, hippocampus, striatum, and prefrontal decreased in all induced groups in comparison to CAE. Additionally, increased numerical density of glial cells and decreased of numerical density of neurons were found in all induced groups. Results show that simultaneous exposure to air pollution and VPA can cause ASD-related behavioral deficits and air pollution reinforced the mechanism of inducing ASD ̉s in VPA-induced rat model of autism.

Catalyst samples based on SiO₂-supported TiO₂ were prepared with the incorporation of Ag (metal), S (nonmetal), and ZnO@S (semiconductor and nonmetal). The materials were evaluated regarding their morphological, optical, and crystalline properties as well as their photoactivity under visible and ultraviolet light toward the degradation rate of a model emerging pollutant, acetaminophen (ACT). All modified materials exhibited improved performance over the undoped catalyst. The Ag-doped catalyst achieved the largest degradation under visible radiation (about 30% in 120 min), whereas under ultraviolet irradiation, the ZnO@S-doped sample exhibited the best performance (about 62% in 120 min). A Doehlert design was carried out to evaluate the influence of pH and temperature on the photoactivity of Ag-TiO₂/SiO₂. In addition, the role of each reactive species in the photodegradation reaction was investigated by radical scavenger experiments, and the superoxide radical anion O₂•⁻ was shown to be the predominant reactive species. The stability of the Ag-TiO₂/SiO₂ material under ultraviolet and visible light was confirmed after five successive operation cycles, showing a reasonable (about 50%) loss of activity under visible irradiation and a slight improvement (about 13%) under UV light, as a result of the photo-reduction of Ag⁺. Lastly, the effect of the initial pollutant concentration showed that ACT degradation using Ag-TiO₂/SiO₂ follows the Langmuir-Hinshelwood kinetics, with intrinsic reaction rate k = 2.71 × 10⁻⁴ mmol L⁻¹ min⁻¹ under visible-light radiation.

Description and morphological analysis of copepods inhabiting a water body with high arsenic concentrations (32.79 to 62.29 mg L⁻¹) were performed to identify some effect on the development of individuals due to the arsenic concentrations. Detailed morphology of prosomal and urosomal appendages along the development of the specimens was considered. The results showed that the freshwater copepod Paracyclops novenarius Reid, 1987 inhabits this water body, and previously, it was recorded as Paracyclops chiltoni (Thomson GM, 1882) on this site. Moreover, this becomes the first record of P. novenarius in Mexico. Morphological analysis showed a normal and stable development along the different instars, different arsenic concentrations in the media, and different sampled dates between the analyzed specimens, suggesting that the high arsenic concentrations do not affect the morphology of P. novenarius, including all its development and adult instars, which differs from other copepods and other groups such as Cladocera and Rotifera, where morphological changes due to metals and metalloids have been observed but in low concentrations of these elements. The results of this study contribute to the existing reports of the genus Paracyclops (Claus 1893) in Mexico and could provide information for environmental impact assessments on aquatic systems.

The vertical distribution pattern and concentrations of elements (Fe, Al, Ca, Mg, Mn, Cr, Cu, Ni, Co, Pb, Zn, and As) in the estuarine and lagoon region of Marquelia coast, Guerrero, Mexico, were studied to comprehend the origin and pollutant phases of geochemical elements. Henceforth, two sediment core samples [C1 (127 cm) and C2 (110 cm)] were collected to assess the pollution status using geochemical indices, namely anthropogenic factor (AF), enrichment factor (EF), and geoaccumulation index (Igₑₒ). Additionally, the elemental concentrations were compared with the sediment quality guidelines (SQGs) to examine the potential risks to biota. Among the two depositional environments, the sediments of lagoon Apozahualco exhibited higher concentrations of elements. The granulometry characteristics of sediment grains also attested that the concentration and mobilization of metals are largely governed by the fine-grained fractions. Major elemental concentration and grain size changes were identified at several depths (30–40, 60–70, and 90–100 cm) revealing the internal hydrodynamic condition. The overall assessment of geochemical indices revealed that the sediments were unpolluted to moderately polluted. The anthropogenic factor indicated that the upper portion of the sediments were affected by anthropogenic influences. The comparison of trace element concentration with SQGs denoted that Cr, Ni, and As could pose potential adverse effect to the organisms that live in and near the sedimentary environment. Factor analysis revealed the origin and behaviour of the studied elements during transportation and deposition processes in both the ecosystems (i.e. estuary and lagoon). The results of this study provided an in-depth understanding of variations in elemental concentration and pollution status of sediment profile in coastal transitional environments that would aid in sustainable management.

Sugar industry produces a variety of organic byproducts causing disposal as well as environmental issues. This study investigated the safe use of these byproducts in assessment of soil physicochemical properties and metal accumulation in rice. A field experiment was performed with following treatments: control only NPK (CF), NPK + sugarcane bagasse (SB), NPK + press mud (PM), NPK + sugarcane vinasse (SV), NPK + SB + PM (SB + PM), NPK + SB + SV (SB + SV), NPK + PM + SV (PM + SV), NPK + SB + PM + SV (SB + PM + SV). Total byproduct input was (1.25 t ha⁻¹) as recommended for organic inputs in the local area. The results indicated that integrated use of these amendments with chemical fertilization improved soil properties and rice yield. Organic matter was significantly improved in SB + SV (191.3%), SB + PM + SV (164.4%), and SB + PM (150.9%). Total N was significantly enhanced in SB + SV (193%), SB + PM + SV (166%), and SB + PM (152.5%); extractable P was high in SB (103%), PM + SV (89.7%), and SB + PM (51%); extractable K was significantly improved in PM (39.6%) and SB (33.4%); extractable Zn was significantly enhanced in SB (1172.8%), SV (829.2%) and PM (819.1%) in soil. Rice grain yield was significantly enhanced in SB (213.1%) and PM (208.8%) while combined application also improved the yield with reference to the CF. The application of SB + PM improved N (58.7%), P (27.4%), K (11.5%), and Zn (166.4%) concentration in grain, while metal accumulation was within the permissible limit. Zn concentration was significantly enhanced in SB + PM (166.4%) whereas the concentration of Cd and Pb was significantly reduced with the application of byproducts. Health assessment results showed no harmful effects for humans. Results conclude that these byproducts are good nutrients source and improve soil physicochemical properties without any health hazards.

In the present study, the oral bioavailability of cadmium (Cd) in earthworms and leeches was investigated through in vitro physiologically based extraction test (PBET) digestion/Caco2 and MDKC cell models. We are the first to create an innovative assessment strategy which has capacity to offer a more precise evaluation of Cd-associated health risks in traditional animal medicines (TAMs), by combinational usage of bioavailable Cd levels, the duration and frequency of the exposure to TAMs obtained by questionnaire data, as well as safety factor of TAMs. Our data showed that the percentage of bioavailability for Caco-2 cells in earthworms and leeches ranged from 3.29 to 14.17% and 4.32 to 12.61%, respectively. The percentage of bioavailability of MDCK cells in earthworms and leeches ranged from 4.83 to 15.74% and 6.53 to 15.04%, respectively. After adjusting by the bioavailability of Cd to target hazard quotient (THQ), excitingly, our findings manifested that the health risks induced by the ingestion of earthworms and leeches were acceptable in the clinic. Our key findings suggest that bioavailability characterization cannot be ruled out and health risks should be assessed on the basis of the bioavailable Cd levels rather than total levels. Our novel strategy provides insight into the bio-accumulation of Cd in organisms as well as a more realistic and accurate assessment of Cd-associated health risks in TAMs, with the main purpose of improving public health by scientifically using TAMs.

The effect of treated wastewater (TMWW) and biosolid (BSD) on the available soil metal levels was studied through a field experiment conducted in Amfissa, Greece (Geo. Coordinates X 360,030.956 and Y 4,265,145.376), using a randomized block design and applying the following treatments, in 4 replications: (i) TMWW, (ii) BSD, (iii) TMWW + BSD, and (iv) CONTROL. The perennial Ryegrass (Lolium perenne L.) was chosen as a test crop. Under these treatments, the differences in soil metal concentration between pre- and post-application were statistically significant. A considerable metal contribution to soil and plant was attained by the following interactions: (a) between “soil chemical and physical characteristics with metals” and with essential nutrients, (b) between “metals and essential nutrients” occurring in the soil, and (c) between “metals and essential nutrients” within the plant tissues. It is suggested that the interactions between metals and soil characteristics must be further studied to attain a more accurate knowledge in relation to soil fertility and productivity.