Plastic debris is one of the major environmental concerns for the coastal area of Brunei Darussalam. It reduces the aesthetic appeals of the beaches in the country. The current study investigates marine debris on six different beaches of Brunei Darussalam along the South China Sea. Plastic was found the most abundant among whole debris by number (90.02%) and by weight (39.12%). It was classified by size (micro (<5 mm), meso (5-20 mm), macro (21-100), and mega (>100 mm)), colour (transparent, coloured, white and black). Fourier Transform Infrared Spectroscopy (FT-IR) was used to investigate the types of plastics and additives present in it. Statistical analysis using Minitab 17 and Kruskal-Wallis test was performed for comparison of data at different study sites. All major types of plastics were found in different forms with varying quantities from which toxic chemicals may leach out during degradation. The highest abundance by the number of plastic debris was found on Muara beach with a mean value 74.428 n/m2 ± 34.33 n/m2, while the lowest abundance was found on Lumut beach 53 n/m2 ± 20.9 n/m2. The study shows beaches used for recreational facilities are likely to have more debris as compared to other beaches.

This study aimed to evaluate the concentration of heavy metals in liquid effluents and to quantify the mercury content in dental amalgam waste generated by dental clinics. Three neighbouring cities in Northeast Algeria were considered in this study (Constantine, Skikda, and Annaba). Heavy metals, such as Hg, Cu, Zn, Fe, Ni, Mn, Cr, Cd, and Pb, were analysed in wastewater and then compared with acceptable standard values. Special attention was given to mercurybecause of its dangerous effects. The results collected indicated the presence of heavy metal contamination in dental wastewater. Heavy metal concentrations were significantly high for all heavy metals and exceeded the allowed concentrations. However, Pb and Cr were shown to have acceptable concentrations. This study highlights the possible contamination of the environment by mercury and heavy metals generated by dental clinics. This study also demonstrates an order of magnitude of the concentration of these heavy metal in a large agglomeration with a population of 2.5 million people.

In order to investigate the accumulation and bio-absorption of lead and cadmium in radish and cress, the present study has been conducted in a completely randomized design in three replicates in a hydroponic growing medium. The first factor includes the plant type at two levels (radish and cress), and the second factor is consisted of lead (Pb) (first experiment) at two levels (50 and 100 mg/L), cadmium (Cd) (second experiment) at one level (10 mg/L), and a combination of lead and cadmium (third experiment) again at two levels. After 23 days, roots and aerial parts of both plants have been dried for 48 hours at 70°C in an oven. Then, half gram (0.5 g) of the dried templates has been used to measure the accumulation of Pb and Cd by means of an atomic absorption spectrometer. The highest amount of Pb in radish and crest roots belong to 100 mg/L concentration and the combined Cd (10) + Pb (100) mg/L treatment, respectively, and the highest amount of Cd occurs in Cd (10) + Pb (50) for radish roots and in Cd (10) + Pb (100) combination for cress. Moreover, the Translocation Factor (TF), with a value below 1 and higher bio-concentration factor (BCF) in roots, compared to the aerial part of both radish and cress, seem to be due to the low capability of these plants to transfer Pb and Cd from roots to aerial part. There is a high potentiality for lead accumulation in the roots that prevent its transfer to the aerial part.

Total Petroleum Hydrocarbons (TPHs) are one of the most dangerousorganic contaminants in the environment. Therefore, the remediation of the oilcontaminatedsoil is necessary. The growth of barley and oat plant was studied in thecontaminated soils (4, 6, 8% TPHs) during 5 months. Plant height, wet and dry weight ofshoots and roots of both plants were measured. Results showed that oat and barley height,wet and dry weight of shoots and roots decreased with increasing contamination levels.Regardless of the plants species, the highest rate of TPH reduction was observed in soilwith 4% contamination and decreased with increasing the contamination level. The TPHsconcentration in the rhizosphere of barley and oat decreased by 29.66 and 24.04% at the6% TPHs level and by 21.24 and 17.48% at the 8% TPHs level, respectively. Cultivationof barley and oat plants significantly accelerated the biodegradation of hydrocarbons andreduced TPHs content in soil as compared to unplanted soil.

The life cycle of diesel fuel in non-passenger vehicles was assessed for all registered vehicles in Qatar as of November 2017. The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model was used as a source of normalized data to evaluate diesel fuel emissions for all non-passenger vehicle categories. This work aims at estimating the emissions from all non-passenger diesel vehicles in Qatar and evaluating the impact of the fuel life cycle assessment. The emissions of CO2, NOx, CO, SO2, VOC, black carbon (BC), organic carbon, fine particulates PM2.5, and coarse particulates PM10 were evaluated. SO2 emissions were found to be dominant during the well to pump (WTP) stage of the life cycle assessment (LCA) process, while the pump to wheel (PTW) stage was found to be dominated by CO, VOC, PM10, PM2.5, and BC emissions. NOx and organic carbon emissions were virtually the same during both stages. Total greenhouse gas emissions amounted to 5367 kt of CO2 equivalent (CO2-eq) in 2017 as compared with that in 2014 (5277 kt), the only reported value in Qatar for transportation emissions. In addition, several mitigation strategies are proposed to ensure sustainability in the transport sector and to minimize the negative impact of diesel fuel emissions in the country.

Industrial activities compromise the ambient air quality at a local, regional and global level through gaseous and dust emissions. This study reviews uptake mechanisms and the associated phytotoxicity of pollutants in plants, focusing on heavy metals and SO2. It further describes detoxification mechanisms and the resultant biochemical and physiological changes in plants. Finally, the morpho-physiological and growth responses to stress-induced biochemical changes are discussed. Heavy metals and SO2 enter the plant tissue through the stomata, cuticular layers, lenticels and root hairs. In the plant cells, SO2 converts to SO32- or SO42- ions upon reacting with water molecules, which in excess are toxic to plants. However, the detoxification process of SO32- increases the production of reactive oxygen species (ROS). ROS are toxic to plants and damages biomolecules such as lipids, proteins, carbohydrates and DNA. On the other hand, heavy metals, such as Cu and Fe catalyse the Fenton/Haber-Weiss reactions, breaking down H2O2 into OH•. Additionally, Pb and Zn inhibit the activities of ROS-detoxifying enzymes, while other heavy metals bind to cellular layers making them rigid, thereby reducing cell division. Therefore, pollutant toxicity in plants affects biochemical parameters damaging organic molecules and limiting cambial activity. Damaged biomolecules inhibit the plant's capacity to carry out physiological functions, such as photosynthesis, stomatal functions, transpiration and respiration while impaired cambial activity reduces cell division and elongation resulting in reduced plant growth and productivity.

The aim of this study was to determine the levels of Cd, As, Hg, Pb, and Cr in the edible part of eleven most consumed fish species collected from the north-east coast of Persian Gulf, Iran, during 2017. An inductively coupled plasma atomic emission spectroscopy (ICP-AES) instrument was used to measure the concentration of heavy metals. The results were compared within acceptable limits for human consumption set by various health institutions. The order of heavy metals about total accumulation was Cr>As>Pb> Cd> Hg. The mean heavy metals concentrations of fish species muscle decreased in the order of Acanthopagrus latus> Planiliza subviridis> Lutjanus lemniscatus > Alectis indica> Epinephelus areolatus> Otolithes ruber> Epinephelus chlorostigma> Lethrinus crocineus> Euryglossa orientalis > Cynoglossus arel > Grammoplites suppositus. Probably the difference in the concentration of metals between samples depends on fish species, diet, and habitat. These species were declared to exhibit a low probability of causing non-cancerous diseases. The comparison of the accumulation and hazard risk of consuming the five heavy metals existing in the eleven species that were sampled from the coasts of Khuzestan, Maah-shar Harbour, with the WHO and USEPA guidelines showed that although consuming these fish species does not threaten the consumers' health, pregnant women and children should be cautious about consuming them. The HI was calculated for 70 kg body weight of adults and 14.5 kg body weight of children. The amount of optimal consumption is different for different weights of consumers.

Lead-acid battery recycling is one of the organized process which helps in overcoming the demand of lead for the production of the storage batteries. During recycling, a large amount of effluent is generated which contains lead beyond the permissible limit and harmful for the environment. This effluent was treated by adsorption as an alternative technique by using another waste (pressmud) as an adsorbent obtained from the sugar industry. Properties of the pressmud were determined through Fourier transform infrared spectroscopy, scanning electron microscope and X-ray diffraction analysis. Taguchi method L16 orthogonal array (4^3) was used for batch adsorption study for the parameters, initial pH, adsorbent dose and contact time. The optimum value for the adsorption of Pb(II) onto pressmud was found at effluent pH 4.5, adsorbent dose 1.0 g/50mL and time 240 min from the Signal-to-Noise ratio analysis. Kinetic and isotherm studies were also carried out to understand the mechanism of adsorption. Langmuir isotherm fitted best to the experimental data with R2=0.994 and kinetics of adsorption followed the pseudo-second-order model with R2=0.993.

This study on the heavy metal content of a local drinking water source in South-east Nigeria was carried out in 3 sampling stations between May 2019 and October 2019. Pollution indices and health risk assessment for non-carcinogenic were used to check the water’s suitability for human consumption. The indices were heavy metal pollution index (HPI) and Contamination Index (Cd). Eight metals were evaluated with standard methods and compared with Nigerian and WHO drinking water standards. Some metals like iron, lead and cadmium exceeded the recommended limits. The stations Heavy Metal Pollution Index ranged between 511.4 and 512.4 while the monthly values ranged between 279.8 and 547.6; all exceeding the threshold value of 100. Contamination Index ranged between 3.12 and 3.32 (stations) and -0.80 to 4.80 (month) indicating high contamination potential and low to high contamination potentials respectively. All the hazard indices also exceeded one (1). Stations 1 and 2 were higher in all the indices. All the indices were linked the high values of iron, lead and cadmium, influenced by sand mining activities. The pollution indices and Health Risk Assessment converged to show that the waters of Iyiakwu River are not fit for human consumption. The children are more vulnerable since it the main source of drinking water in the area.

Municipal solid waste landfills are significant parts of anthropogenic greenhouse gas emissions. The emission of significant amount of landfill gas has generated considerable interest in quantifying such emissions. The chemical composition of the organic constituents and potential amount of landfill gas that can be derived from the waste were determined. The chemical formulae for the rapidly biodegradable waste (RBW) and slowly biodegradable waste (SBW) were determined as C39H62O27N and C36H56O20N, respectively. The triangular method was used to calculate landfill gas obtainable from rapidly biodegradable waste over a 5-year period and for slowly biodegradable waste over a 15-year period. A plot was obtained for a landfill life span of 20 years. The volume of methane and carbon dioxide from RBW were 12.60 m3 and 11.76 m3 respectively while those from SBW were 6.60 m3 and 5.48 m3 respectively at STP. For the initial deposit of 2002 the highest landfill gas emission rate occurred in 2007 at 0.2829 Gg/yr with an average cumulative emission of 0.3142 Gg while for a landfill closed after five years the highest landfill gas emission rate was in 2010 at 1.2804 Gg/yr with an average cumulative emission of 1.5679 Gg while this cumulative emission will start declining by the year 2029.