Great efforts have been made over the years to assess the effectiveness of air pollution controls in place in the metropolitan area of São Paulo (MASP), Brazil. In this work, the community multiscale air quality (CMAQ) model was used to evaluate the efficacy of emission control strategies in MASP, considering the spatial and temporal variability of fine particle concentration. Seven different emission scenarios were modeled to assess the relationship between the emission of precursors and ambient aerosol concentration, including a baseline emission inventory, and six sensitivity scenarios with emission reductions in relation to the baseline inventory: a 50% reduction in SO₂ emissions; no SO₂ emissions; a 50% reduction in SO₂, NOₓ, and NH₃ emissions; no sulfate (PSO₄) particle emissions; no PSO₄ and nitrate (PNO₃) particle emissions; and no PNO₃ emissions. Results show that ambient PM₂.₅ behavior is not linearly dependent on the emission of precursors. Variation levels in PM₂.₅ concentrations did not correspond to the reduction ratios applied to precursor emissions, mainly due to the contribution of organic and elemental carbon, and other secondary organic aerosol species. Reductions in SO₂ emissions are less likely to be effective at reducing PM₂.₅ concentrations at the expected rate in many locations of the MASP. The largest reduction in ambient PM₂.₅ was obtained with the scenario that considered a reduction in 50% of SO₂, NOₓ, and NH₃ emissions (1 to 2 μg/m³ on average). It highlights the importance of considering the role of secondary organic aerosols and black carbon in the design of effective policies for ambient PM₂.₅ concentration control.

In this study the phytotoxic, cytotoxic, genotoxic and mutagenic effects of two commercial fungicide-active compounds, procymidone (PR) and iprodione (IP), were determined. The parameters evaluated were germination and root growth, mitotic index, chromosomal and nuclear aberrations, and molecular analyses were also performed in the model plant Allium cepa L. The results demonstrated that the active compounds PR and IP were phytotoxic, delaying germination and slowing the development of A. cepa seedlings. Moreover, PR and IP showed cytogenotoxicity towards A. cepa meristematic cells, inducing chromosomal changes and cell death. The mutagenic activity of the active compounds was demonstrated by the detection of DNA changes in simple sequence repeat (SSR) and inter-simple sequence repeat (ISSR) markers in the treated cells compared to the negative control. Together, these results contribute to a better understanding of the damage caused by these substances in living organisms and reveal a promising strategy for prospective studies of the toxic effects of environmental pollutants.

China is the biggest consumer of coal. Every year, half or more of China’s coal is used in the power industry. Most thermal power plants in China use electrostatic precipitators to treat solid particulate matter in flue gas. The efficiency of the electrostatic precipitator in removing dust has a considerable influence on atmospheric pollutants. However, the most important factor affecting the efficiency of the electrostatic precipitator in removing dust is the dielectric properties of the fly ash. Through the study of volt-ampere characteristics, electrical and capacitive properties, and electrical breakdown characteristics of coal-fired fly ash, it is found that the V–I characteristics of ash samples in thermal power plant do not strictly follow the formula ([Formula: see text]), the type of coal, and the chemistry of coal. Ingredients are related; disparate types of ash samples have disparate capacitances, and the measurement of capacitive contrast resistance has a certain influence.

Workers chronically exposed to respirable crystalline silica (CS) are susceptible to adverse health effects like silicosis and lung cancer. This study aimed to investigate potential early peripheral biomarkers of inflammation and oxidative stress in miners. The subjects enrolled in this study were occupationally unexposed workers (OUW, n = 29) and workers exposed to crystalline silica (WECS), composed by miners, which were divided into two subgroups: workers without silicosis (WECS I, n = 39) and workers diagnosed with silicosis, retired from work (WECS II, n = 42). The following biomarkers were evaluated: gene expression of L-selectin, CXCL2, CXCL8 (IL-8), HO-1, and p53; malondialdehyde (MDA) plasma levels and non-protein thiol levels in erythrocytes. Additionally, protein expression of L-selectin was evaluated to confirm our previous findings. The results demonstrated that gene expression of L-selectin was decreased in the WECS I group when compared to the OUW group (p < 0.05). Regarding gene expression of CXCL2, CXCL8 (IL-8), HO-1, and p53, significant fold change decreases were observed in workers exposed to CS in relation to unexposed workers (p < 0.05). The results of L-selectin protein expression in lymphocyte surface corroborated with our previous findings; thus, significant downregulation in the WECS groups was observed compared to OUW group (p < 0.05). The MDA was negatively associated with the gene expression of CXCL-2, CXCL8 (IL-8), and p53 (p < 0.05). The participants with silicosis (WECS II) presented significant increased non-protein thiol levels in relation to other groups (p < 0.05). Taken together, our findings may contribute to help the knowledge about the complex mechanisms involved in the silicosis pathogenesis and in the risk of lung cancer development in workers chronically exposed to respirable CS.

The present work investigated the potential of the green alga Chlorella vulgaris to produce high-quality biofuel under culture stress conditions. The cultivation was carried out in a 1000 l open plate tank system, which provides biomass yields comparable to open pond systems, but with less area needed. Algal biomass and lipid content were measured repeatedly. We compared the two solvent systems n-hexane and hexane/isopropanol (HIP) for extraction efficiency of lipids and applied three different extraction methods Soxhlet, soaking, and soaking followed by Soxhlet (soak-Sox). The combination of the HIP solvent and the soak-Sox provided the highest lipid yield (15.8 ± 0.174). Volumetric biomass and lipid productivity were 0.201 g l⁻¹ day⁻¹ and 31.71 mg l⁻¹ day⁻¹, respectively, whereas areal biomass and lipid productivity were 25.73 g m⁻² day⁻¹ and 4.066 g m⁻² day⁻¹, respectively. The fatty acid profile by means of gas chromatography resulted in seven fatty acids from C₁₂ to C₁₈. The most abundant fatty acid methyl esters (FAMES) were palmitic (C16:0), oleic (C18:1), and stearic (C18:0) acids. Lipid synthesis enhanced by optimizing the Kuhl growth medium with replacing nitrate by urea (50% N compared to the original recipe) increased salt content (10 g/l NaCl), ferrous sulfate (0.5 g/l), and sodium acetate addition (1 g/l). With regard to density, kinematic viscosity, gravity, pour point, flash point, and cetane number, the Chlorella-biodiesel comply with ASTM and EN standards thus pointing at the high potential of lipids synthesized by Chlorella as a feedstock for biodiesel production.

Urban water supply networks are susceptible to intentional, accidental chemical, and biological pollution, which pose a threat to the health of consumers. In recent years, drinking-water pollution incidents have occurred frequently, seriously endangering social stability and security. The real-time monitoring for water quality can be effectively implemented by placing sensors in the water supply network. However, locating the source of pollution through the data detection obtained by water quality sensors is a challenging problem. The difficulty lies in the limited number of sensors, large number of water supply network nodes, and dynamic user demand for water, which leads the pollution source localization problem to an uncertainty, large-scale, and dynamic optimization problem. In this paper, we mainly study the dynamics of the pollution source localization problem. Previous studies of pollution source localization assume that hydraulic inputs (e.g., water demand of consumers) are known. However, because of the inherent variability of urban water demand, the problem is essentially a fluctuating dynamic problem of consumer’s water demand. In this paper, the water demand is considered to be stochastic in nature and can be described using Gaussian model or autoregressive model. On this basis, an optimization algorithm is proposed based on these two dynamic water demand change models to locate the pollution source. The objective of the proposed algorithm is to find the locations and concentrations of pollution sources that meet the minimum between the analogue and detection values of the sensor. Simulation experiments were conducted using two different sizes of urban water supply network data, and the experimental results were compared with those of the standard genetic algorithm.

The pollution of the environment by potentially toxic elements (PTEs) is one of the most important raised concerns. Therefore, the current investigation was devoted to measuring the concentration of lead (Pb), cadmium (Cd), elemental mercury (Hg), nickel (Ni), iron (Fe), zinc (Zn), and copper (Cu) in muscle tissue of farmed rainbow trout (n = 30) as well as their feed (n = 15) and water (n = 15) samples collected from farms (Hamadan Province, Iran) by the aid of an inductively coupled plasma atomic emission spectrometer (ICP-OES). Also, the associated risk for human and biomagnification factor (BMF) and bioconcentration factor (BCF) for PTEs in the fish muscle through feed and water were calculated. The mean concentration of Pb, Cd, Hg, Ni, Fe, Zn, and Cu in rainbow trout muscle was reported as 0.056 ± 0.040 μg g⁻¹ wet weight, <LOD, 0.014 ± 0.016 μg g⁻¹ wet weight, 0.140 ± 0.188 μg g⁻¹ wet weight, 1.051 ± 0.909 μg g⁻¹ wet weight, 0.635 ± 0.725 μg g⁻¹ wet weight, and 0.275 ± 0.325 μg g⁻¹ wet weight, respectively, while all of the samples were contaminated in the concentrations below the permitted limits by regulatory bodies such as EC, Food and Agriculture Organization (FAO), and WHO/FAO. No significant difference between the amounts of PTEs among the collected feed and water samples was noted, while the corresponded values for PTE concentrations also were lower than the allowable limits. The values of BMF and BCF for all analyzed PTEs through water and feed were lower than 1000, demonstrating that the rainbow trout muscle could not be considered as a bioaccumulative tissue for PTEs. Additionally, no health risk due to ingestions of investigated PTEs via consumption of this rainbow trout fish was noted.

Fig. 1. was amended to reduce the size of the map and improve formatting of the manuscript. The authors claim this amendment does not affect the information being conveyed.

The western flower thrips (Frankliniella occidentalis Perg.) is one of the most economically important insect pests of greenhouse plants. Plant protection against this pest is based predominantly on synthetic insecticides; however, this form of protection poses problems in terms of thrip resistance to the active substances, along with health risks associated with insecticide residues on the treated plants. Therefore, new active substances need to be sought. Essential oils could be a new, appropriate, and safe alternative for greenhouse culture protection. As greenhouses are enclosed areas, fumigation application of EOs is possible. This paper presents acute toxicity results for 15 commercial EOs applied by fumigation, as well as the effect of sublethal concentrations on fertility of F. occidentalis females. The most efficient EOs were obtained from Mentha pulegium and Thymus mastichina, with LC₅₀₍₉₀₎ estimated as 3.1(3.8) and 3.6 (4.6) mg L⁻¹ air, respectively. As found for the very first time, sublethal concentrations of EOs could result in a significant reduction in the fertility of surviving T. occidentalis females. Among the tested EOs, the EO from Nepeta cataria provided the highest inhibition of fertility, with EC₅₀₍₉₀₎ estimated as 0.18 (0.36) mg L⁻¹ air. Chemical composition of the most efficient EOs and possible applications of the results in practice are discussed. In conclusion, in light of the newly determined facts, EOs can be recommended as active substances for botanical insecticides to be applied against Thysanopteran pests by fumigation.