The objective of this study was to demonstrate biochar’s effectiveness on Ni(II) removal from aqueous solutions by adsorption on three different biochars. Three different waste feedstocks, namely sewage sludge, exhausted olive pomace and the organic fraction of municipal solid waste, were used to produce biochar through pyrolysis at 300 °C, under inert conditions. The obtained biochars were characterized regarding their main properties and then evaluated as potential Ni(II) adsorbents. All investigated materials showed high adsorption efficiency in the range of 78–97%, with the biochar derived from SS exhibiting the best results, possibly because of its higher cation exchange capacity. Ni(II) removal rates were higher when the adsorption experiments were conducted at natural pH, while the removal efficiency under adjusted pH (acidic or alkaline) was slightly lower. The pseudo-second-order kinetic model adequately described the adsorption kinetics depicting high correlation coefficients, while the Freundlich adsorption isotherm model was successful in simulating equilibrium of adsorption.

The primary objective of this research is to ascertain the relationship between corporate social responsibility, environmental investments and financial performance in Nigerian manufacturing firms. The hypotheses are tested on internal environmental investments and external environmental investments on firm’s financial performance. It further determines if there is a significant difference between the profitability of environmentally conscious and environmentally non-conscious firms in Nigeria. Descriptive analysis is used to explain the variables applied and panel regression analysis is used to find out if there exists a relationship between internal environmental investments (employee benefits, staff training cost), external environmental investments (donations) and firm’s financial performance. The results indicate a positive and significant relationship exists between internal environmental investments and firm’s financial performance. It is also found a positive but insignificant relationship between external environmental investments and firm’s financial performance. Furthermore, paired sample t tests are used to reveal that there was a significant difference between the profitability of environmentally conscious and environmentally non-conscious firms. The finding of this study explains that firms with higher environmental investments have a higher profitability level than environmentally non-conscious firms.

The reuse of wastewater is one effective approach to solving the problem of water resource scarcity. However, deterioration in the quality of reused water, such as increased odor and bacterial growth, restricts its reuse. The objectives of this study were to characterize graywater (GW) treatment technology and to verify the suitability of the reclaimed water for toilet flushing. A membrane bioreactor (MBR) and biological aerated filter (BAF) were used to treat GW in a 1-year laboratory-scale experiment. The optimal operational conditions of the MBR and BAF were as follows: hydraulic retention time = 2–3 h, dissolved oxygen = 4–7 mg/L, mixed liquor suspended solids = 3500–4500 mg/L, and contact reaction time = 1.96–5.89 h, dissolved oxygen = 3–5 mg/L, backwash cycle time = 24–48 h, respectively. The MBR treatment resulted in reductions in COD, NH₃-N, and turbidity of 60–90%, 80–90%, and 95–99%, respectively, whereas those of BAF treatment were 50–90%, 50–90%, and 80–90%, respectively. The BOD₅ values of MBR and BAF effluent were 1.2–4.5 mg/L and 2.5–7 mg/L, respectively. GW treated by both MBR and BAF met the standard for reusing water for toilet flushing. The effluent from MBR, BAF, and BAF + ultrafiltration treatment and purified mixed wastewater was used to simulate toilet flushing at 28 °C, with the addition of 5 mg/L NaClO to the reused water. The residual chlorine levels were 1.5, 0.6, 0.9, and 0.5 mg/L, respectively, after 15 days. No bacteria were detected in any of the reclaimed water after 15 days. The water quality of the effluent of MBR-treated GW was better than that of the mixed wastewater. The results show that it is viable to use GW purified by MBR for toilet flushing. This study provides a scientific basis for the popularization and application of reclaimed water for toilet flushing.

A total of 77 street dust samples were collected from Jinan City in East China and were analyzed for the concentrations, speciation, bioavailability, and influencing factors of ten heavy metals. The results showed that the average concentrations of Ba, Co, Cr, Cu, Cd, Mn, Ni, Pb, Zn, and V in the street dust were 642.77, 8.24, 114.09, 87.71, 1.08, 517.04, 30.29, 80.32, 497.84, and 51.76 mg/kg, and the concentrations of Ba, Cr, Cu, Cd, Ni, Pb, and Zn exceeded the local soil element background values. In the street dust, Ba, Co, Cr, Mn, Ni, and V were mainly in the residual; Cu and Pb were controlled by the oxidizable; Cd mainly existed in the acid extractable; and Zn was dominated by the reducible. According to the ratios of the acid extractable to the sum of four forms, Cd (39.85%) presented a high environmental risk; Mn and Zn (24.29% and 27.78%) exhibited a medium risk; and V, Cu, Pb, Ba, Co, Ni, and Cr had no environmental risk. The order of mobility or potential risk of heavy metals was Cd (85.8%) > Zn (77.1%) > Cu (64.3%) > Pb (62.0%) > Mn (51.7%) > Ba (38.9%) > Co (31.2%) > Ni (30.1%) > V (25.8%) > Cr (23.1%), suggesting that Cd, Zn, Cu, Pb, and Mn presented relatively high movability and risk. The bioavailability order of heavy metals was Cd (82.7%) > Zn (63.6%) > Mn (40.4%) > Ni (20.4%) > Pb (11.7%) > Cu (11.1%) > V (7.8%) > Cr (3.7%) in the gastric phase and Cu (24.6%) > Cd (19.9%) > Mn (16.2%) > Ni (6.6%) > Pb (5.7%) > Zn (4.4%) > Cr (3.0%) > V (2.3%) in intestinal phase, implying that Cd, Zn, Mn, and Cu were highly bioavailable in the gastrointestinal environment, which coincided with the risk of speciation. The speciation of heavy metals in street dust had certain correlations with their bioavailability. The physiochemical properties of street dust had significant effects on the concentrations, speciation, and bioavailability of heavy metals in street dust. The simple, fast, and nondestructive magnetic measurements could be used as indicators of the concentrations, speciation, and bioavailability of heavy metals in street dust.

In this study, the dispersion stability and reactivity of sulfide-modified nanoscale zerovalent iron (SNZVI) coated with different surface stabilizers (i.e., starch, sodium dodecylbenzene sulfonate (SDBS), or carboxymethyl cellulose (CMC)) were investigated. All the three types of surface stabilizers could enhance the dispersion stability of SNZVI but exerted differing influences on the reactivity toward trichloroethylene (TCE) removal. The coating of starch on SNZVI markedly improved TCE removal, which was positively correlated with the enhanced dispersion stability (i.e., more active surface sites). However, although the SDBS and CMC could enhance the dispersion stability of SNZVI, they resulted in an inhibition in TCE removal, especially for CMC. It was presumed that the coated SDBS/CMC on the surface of SNZVI occupied the active surface sites for TCE removal. Besides, the effect of groundwater geochemistry (i.e., pH, Ca²⁺, and humic acid (HA)) was examined. The increasing pH from 5 to 9 led to a slight decrease for all stabilized SNZVI particles. The presence of Ca²⁺ or HA exerted distinct influence on the TCE removal by the three stabilized SNZVI. The Ca²⁺/HA exerted an insignificant effect on the reactivity of CMC-SNZVI but markedly decreased the reactivity of starch-SNZVI and SDBS-SNZVI. The varying effects of Ca²⁺/HA should be due to their distinct interactions with different types of stabilizers on the surface of SNZVI.

Wetlands are recognized for the importance of their hydrological function and biodiversity, and there is now a consensus to protect and restore them as well as to complete the knowledge on their functioning. Here, we studied the dissolved organic matter (DOM) of a wetland composed of the Auzon cut-off meander, the Allier River, the alluvial fluvial flow, and watershed aquifer. Water was sampled at different locations, in spring, summer, and autumn. For each sample, DOM was characterized for its chemical and optical properties and its photooxidant capacity through its ability to generate DOM triplet excited states (³DOM*) and singlet oxygen upon simulated solar light exposure. UV-visible and fluorescence indices revealed that DOM was mainly microbial-derived whatever the sampling sites with spatial and temporal variations in terms of aromaticity (5.5–22%), specific UV absorbance at 254 nm (0.28–2.82 L m⁻¹mgC⁻¹), ratio of the absorbance at 254 and 365 nm (4.6–10.8), fluorescence index (1.35–166), and biological index (0.812–2.25). All the samples generated ³DOM* and singlet oxygen, rates of formation of which showed parallel variations. Using principal component analysis (PCA), we found positive correlations between the sensitizing properties of DOM samples and parameters associated to the abundance of low molecular weight and low absorbing chromophores. Moreover, the parameter variation across the wetland reinforced the hydrological movements observed in a previous study, suggesting that these parameters could be used as water connection tracers.

Removal of arsenic from water is of utmost priorities on a global scenario due to its ill effects. Therefore, in the present study, aluminium oxide nano-particles (nano-alumina) were synthesised via solution combustion method, which is self-propagating and eco-friendly in nature. Synthesised nano-alumina was further employed for arsenate removal from water. Usually, pre-oxidation of arsenite is performed for better removal of arsenic in its pentavalent form. Thus, arsenate removal as a function of influencing parameters such as initial concentration, dose, pH, temperature, and competing anions was the prime objective of the present study. The speciation analysis showed that H₂AsO4– and HAsO₄²⁻ were co-existing anions between pH 6 and 8, as a result of which higher removal was observed. Freundlich isotherm model was well suited for data on adsorption. At optimal temperature of 298 K, maximum monolayer adsorption capacity was found as 1401.90 μg/g. The kinetic data showed film diffusion step was the controlling mechanism. In addition, competing anions like nitrate, bicarbonate, and chloride had no major effect on arsenate removal efficiency, while phosphate and sulphate significantly reduced the removal efficiency. The negative values of thermodynamic parameters ΔH° (− 23.15 kJ/mol) established the exothermic nature of adsorption, whereas the negative values of ΔG° (− 7.05, − 6.51, − 5.97, and − 5.43 kJ/mol at 298, 308, 318, and 328 K respectively) indicated the spontaneous nature of the process. The best-fitted isotherm was used to design a batch adsorber to estimate the required amount of aluminium oxide nano-particles for achieving the desired equilibrium arsenate concentration. Nano-alumina was also applied to treat the collected arsenic-contaminated groundwater from actual field. Experimental data were used to develop a neural network–based model for the effective prediction of removal efficiency without carrying out any extra experimentation.

Effects of surface modification by carboxyl group on Pb²⁺ adsorption performances and stability of peanut shell and its extracts (cellulose, lignin, and hemicellulose) were investigated. Stability of the biosorbents was measured by determining organic compound release amount (TOC). Results showed that adsorption capacity of peanut shell and the extract was poor and stability of them was not good enough. Amount of organic compound released from the unmodified sorbents followed the order: cellulose > lignin > peanut shell > hemicellulose. Hemicellulose was the main organic compound release resource for the raw peanut shell. Due to the poor stability of the raw materials, peanut and its extract could not be used directly in the practical waste water treatment. After modification, adsorption capacity of peanut shell, cellulose, lignin, and hemicellulose increased by 4- to 6-folds. Stability of the modified sorbents also increased significantly, and TOC determined for the modified peanut shell, cellulose, and hemicellulose was lower than 4.0 mg L⁻¹ in the optimum pH range from 4.0 to 6.0 even using for 30 days, which was lower than the drinking water standard in China. Modified peanut shell and its extract except for lignin could be used safely in pH ranged from 4.0 to 6.0. Surface modification could improve the adsorption performances and stability of the biosorbents.

Proton adsorption behavior on the surface of Al-substituted goethites as a function of pH and ionic strength was investigated and simulated with the multisite surface complexation (MUSIC) model. In addition, X-ray diffraction, X-ray photoelectron spectroscopy, and field emission scanning electron microscope were used to characterize the crystal structure, chemical composition, micromorphology, and surface properties of the Al-substituted goethite. Al substitution was found to affect the crystal structure and micromorphology of goethite. The morphological differences did not result in significant differences in PZC value but largely affected the surface charge values. Goethite surface charge capacity increased progressively with increasing amount of Al substitution, which was attributed to increases in the density of surface coordinated sites due to the increase in (021)/(110) face ratio. The optimization calculations enabled a satisfactory fitting of the titration data of both pure goethite and Al-substituted goethite, and the MUSIC model facilitated a more specific understanding of the charging behavior of Al-substituted goethite. The singly (≡FeOH⁻⁰.⁵ + ≡AlOH⁻⁰.⁵) and triply coordinated (≡Fe₃O⁻⁰.⁵ + ≡AlFe₂O⁻⁰.⁵) surface groups were most likely responsible for the basic charging behavior of goethite in the pH range of 4–10. All results indicate that the MUSIC model has excellent performance in characterizing Al-substituted goethite, and the model has promising application prospect in other substituted metal (hydr)oxides.

The uncontrolled discharge of organic and inorganic substances causes overenrichment of water bodies by nutrients resulting in eutrophication which disturbs the flora and fauna balance of the lake ecosystem affecting its water quality. Therefore, it is necessary to remove excess nutrients from contaminated lake water. The present investigation was attempted to reduce high organic content and excess nutrients from the sewage-contaminated lake water using microalgae and bacteria in the form of activated sludge. Comparative analyses in three different setups state that maximum efficient removal of nutrients and organic matter (chemical oxygen demand [COD]) was achieved by the symbiotic co-culture than stand-alone cultures of microalgae and activated sludge. The highest removal of nitrates (NO₃⁻) and phosphates (PO₄⁻) was 93% and 99% with maximum removal of COD by 73% in the case of co-culture. The maximum biomass obtained was 7.8 g/L in the co-culture system. Fourier transform infrared spectroscopy confirms the presence of fatty acids and lipids in the microalgae biomass. The effect of cultivation time and pH was studied in optimization for simultaneous biomass production, organic matter reduction and for removal of nutrients using central composite design (CCD) under response surface methodology (RSM). The optimized results were in good agreement with the experimental results. Graphical Abstract